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Electronic structure of transition metal dicarbollide complexes

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This paper reports on the results of our electronic structure study of bisdicarbollide complexes of transition metals Fe, Co, Ni, and Cu (36 compounds) by X-ray photoelectron and X-ray emission spectroscopy.

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References

  1. R. N. Grimes,Carboranes [Russian translation], Mir, Moscow (1974).

    Google Scholar 

  2. L. I. Zakharkin and V. N. Kalinin,Usp. Khim.,43, No. 7, 1207–1240 (1974).

    CAS  Google Scholar 

  3. E. V. Leonova,ibid.,59, No. 2, 283–326 (1980).

    Google Scholar 

  4. A. I. Yanovskii,ibid.,64, No. 6, 881–902 (1985).

    Google Scholar 

  5. M. Razavi, L. Baker, and J. Hashmall,J. Electron. Spectrosc,36, No. 1, 29–35 (1985).

    Article  CAS  Google Scholar 

  6. E. A. Il’inchik and V. V. Volkov,29th Colloquium Spectroscopicum International. Abstracts, Leipzig (1995), p. 402.

  7. C. D. Wagner, in:Practical Surface Analysis by Auger and X-Ray Photoelectron Spectroscopy, D. Briggs and M. P. Seah (eds.), Wiley, New York (1983).

    Google Scholar 

  8. V. V. Volkov, E. A. Il’inchik, G. S. Voronina, et al.,Zh. Neorg. Khim.,40, No. 5, 800–806 (1995).

    CAS  Google Scholar 

  9. E. A. Il’inchik, V. V. Volkov, K. G. Myakishev, et al., in:Chemistry of Inorganic Hydrides [in Russian], N. T. Kuznetsov (ed.), Nauka, Moscow (1990), pp. 67–81.

    Google Scholar 

  10. V. I. Stanko, V. V. Khrapov, and T. A. Babushkina,Usp. Khim.,43, No. 8, 1359–1383 (1974).

    CAS  Google Scholar 

  11. V. I. Bregadze,Chem. Rev.,92, 209–223 (1992).

    Article  CAS  Google Scholar 

  12. D. A. Allison, G. Johansson, C. J. Allan, et al.,J. Electron. Spectrosc,1, 269–283 (1972/73).

    Article  Google Scholar 

  13. K. Siegbahn, K. Nordling, A. Fahlman, et al.,ESCA. Atomic, Molecular, and Solid State, Nova Acta Regiae Societatis Scientarium Upsaliensis, Ser. 4, Vol. 20,Structure Studied by Means of Electron Spectroscopy, Uppsala (1967).

  14. P. M. Garrett, F. N. Tebbe, and M. F. Hawthorne,J. Am. Chem. Soc,86, 5016–5017 (1964).

    Article  CAS  Google Scholar 

  15. L. N. Mazalov, V. V. Volkov, S. Ya. Dvurechenskaya, and L. I. Nasonova,Zh. Neorg. Khim.,23, No. 7, 1860–1864 (1978).

    CAS  Google Scholar 

  16. V. V. Volkov, E. A. Il’inchik, B. A. Kolesov, et al.,Zh. Strukt. Khim.,37, No. 6, 1060–1071 (1996).

    CAS  Google Scholar 

  17. E. A. Il’inchik and V. V. Volkov,IMEBORON VIII. Program and Abstracts, Knoxville, TN (1993), p. 160.

  18. D. A. Brown, M. O. Fanning, and N. J. Fitzpatrick,Inorg. Chem.,17, No. 6, 1620–1623 (1978).

    Article  CAS  Google Scholar 

  19. E. A. Il’inchik, V. V. Volkov, O. V. Volkov, et al., Preprint No. 90-05, Novosibirsk (1990).

  20. D. N. Hendrickson, J. M. Hollander, and W. L. Jolly,Inorg. Chem.,9, No. 3, 612–615 (1970).

    Article  CAS  Google Scholar 

  21. V. V. Volkov, O. V. Volkov, E. A. Il’inchik, and V. D. Yumatov,Abstracts of Papers from the 5th International Symposium Nonhomogeneous Electronic States, Novosibirsk (1995), pp. 152–153.

  22. H. Binder, E. Fluck, S. Hermanek, and J. Plesek,Z. Anorg. Allg. Chem.,433, 26–34 (1977).

    Article  CAS  Google Scholar 

  23. L. O. Pont, A. R. Siedle, M. S. Lazarus, and W. L. Jolly,Inorg. Chem.,13, No. 2, 483 (1974).

    Article  CAS  Google Scholar 

  24. E. A. Il’inchik, O. Volkov, and V. Volkov,IMEBORON IX. Program and Abstracts, Heidelberg (1996), p. 224.

  25. C. A. Ghilardi, C. Mealli, S. Midollini, et al.,Inorg. Chem.,19, No. 8, 2454–2462 (1980).

    Article  CAS  Google Scholar 

  26. E. L. Muetterties,Boron Hydride Chemistry, Academic Press, New York (1975), pp. 383–430.

    Google Scholar 

  27. V. I. Nefedov,X-Ray Photoelectron Spectroscopy of Chemical Compounds. Handbook [in Russian], Khimiya, Moscow (1984).

    Google Scholar 

  28. L. F. Warren, Jr. and M. F. Hawthorne,J. Am. Chem. Soc,92, 1157–1173 (1970).

    Article  CAS  Google Scholar 

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Translated fromZhurnal Struktumoi Khimii, Vol. 40, No. 2, pp. 358–371, March–April, 1999.

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Il’inchik, E.A., Volkov, V.V. & Volkov, O.V. Electronic structure of transition metal dicarbollide complexes. J Struct Chem 40, 299–309 (1999). https://doi.org/10.1007/BF02903660

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