Skip to main content
SpringerLink
Log in

Synthesis and structure of layered fluorine-containing crystal hydrates based on aquacomplexes of noble metals

  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

Crystal hydrates were synthesized based on aquaions of noble metals [M(H2O)6]F3·nH2O, where n = 3–8 and M = Ir, Rh. The structure of the resulting crystal hydrates with three aqueous molecules is characterized by the space group P3, Z = 1 and has a layered form. The positively charged layers [M(H2O)6F +2 which alter with negatively charged layers of the composition ∼-·3H2O, are located perpendicular to the c axis. According to X-ray structural and nuclear magnetic resonance data, the water molecules and the F- ions in the negatively charged layers are disordered.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. L. J. Elding,Inorg. Chem. Acta,20, No. 1, 65–69 (1976).

    Article  CAS  Google Scholar 

  2. P. Bentler and H. Gamsjager,J. Chem. Soc. Commun., No. 14, 554–555 (1976).

  3. R. S. Armstrong, J. K. Beattie, and S. P. Best,School of Chemistry of Sydney, New South Wales (1983), pp. 1973–1975; W. Brian and H. White Skelton, Department of Physical and Inorganic Chemistry, University of Western Australia (1983), pp. 1973–1975.

  4. S. V. Zemskov, V. A. Nadolinnyi, V. A. Shipachev, and L. M. Levchenko,Koordinats. Khim.,12, No. 9, 1255–1262 (1986).

    Google Scholar 

  5. S. V. Zemskov, V. G. Isakova, and S. V. Tkachev,ibid.,7, No. 3, 424–427 (1981).

    Google Scholar 

  6. S. P. Gabuda and A. F. Rzhavin,NMR in Crystal Hydrates and Hydrated Proteins [in Russian], Nauka, Novosibirsk (1978).

    Google Scholar 

  7. G. E. Pake,J. Chem. Phys.,16, 327–337 (1948).

    Article  CAS  Google Scholar 

  8. A. Abragam,The Principles of Nuclear Magnetism, Oxford, Clarendon Press (1961).

    Google Scholar 

  9. J. Wo and E. I. Fedin,Fiz. Tverd. Tela,4, No. 8, 2233–2237 (1962).

    Google Scholar 

  10. S. P. Gabuda and S. G. Kozlova,Zh. Strukt. Khim.,38, No. 1, 173–195 (1997).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Russia

    V. A. Shipachev, V. G. Isakova, S. G. Kozlova, I. A. Baidina & S. A. Gromilov

Authors
  1. V. A. Shipachev
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. G. Isakova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. S. G. Kozlova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. I. A. Baidina
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. S. A. Gromilov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated fromZhurnal Strukturnoi Khimii, Vol.40, No. 2, pp. 259–264, March–April, 1999.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Shipachev, V.A., Isakova, V.G., Kozlova, S.G. et al. Synthesis and structure of layered fluorine-containing crystal hydrates based on aquacomplexes of noble metals. J Struct Chem 40, 214–219 (1999). https://doi.org/10.1007/BF02903649

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02903649

Keywords

Search

Navigation