Abstract
SKβ spectra are studied for a series of nickel(II), zinc(II), and cadmium(II) dithiocarbamate complexes. Model quantum chemical calculations of the electronic structure of planar chelate rings are reported. It is shown that the metal-ligand interaction forming a coordination bond between the dithiocarbamate ligand and the metal mainly involves the nonbonding n-electrons and the weakly bonding π-electrons localized on the sulfur atoms.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
A. V. Nikolaev, L. N. Mazalov, É. A. Galtsova, et al.,Dokl. Akad. Nauk SSSR,190, No. 5, 1113–1116 (1970).
L. N. Mazalov, A. V. Nikolaev, É. A. Galtsova, et al.,Izv. Sib. Otd. Akad. Nauk SSSR, Ser. Khim. Nauk,14, No. 6, 3–14 (1971).
L. N. Mazalov and V. D. Yumatov,Electronic Structure of Extradants [in Russian], Nauka, Novosibirsk (1984).
V. M. Byr’ko,Dithiocarbamates [in Russian], Nauka, Moscow (1984).
N. A. Kostromina, V. N. Kumoke, and N. A. Skorik,Coordination Chemistry [in Russian], Vysshaya Shkola, Moscow (1990).
S. V. Larionov, A. A. Voityuk, L. N. Mazalov, et al.,Izv. Akad. Nauk SSSR, Ser. Khim., No. 5, 998–1002 (1981).
S. Luck, R. Forch, D. Sales, and D. Urch,J. Chem. Soc., Faraday Trans. 1,85, No. 12, 4129–4137 (1989).
L. N. Mazalov, A. P. Sadovskii, V. I. Baranovskii, et al.,Zh. Strukt. Khim.,15, No. 5, 805–810 (1974).
V. D. Khavryuchenko, A. F. Savost’yanova, A. D. Gorbalyuk, et al.,Zh. Neorg. Khim.,36, No. 2, 501–506 (1991).
B. N. Plakhutin, “SFKP-23, SPIN-HAMILTONIAN Program,”Information Materials of the Specialized Fund of Quantum Chemical Programs [in Russian], Institute of Chemical Kinetics and Combustion, Siberian Branch, Russian Academy of Sciences, Novosibirsk (1989), pp. 16–17.
E. A. Shugam and V. M. Agre,Kristallografiya,13, No. 2, 253–257 (1968).
S. F. Ruzankin,Zh. Strukt. Khim.,20, No. 5, 953–954 (1979).
K. Schwarz,Phys. Rev. D,5, No. 7, 2466–2475 (1972).
N. V. Bausk, L. N. Mazalov, and S. V. Larionov,Zh. Strukt. Khim.,27, No. 3, 162 (1986).
L. N. Mazalov,X-Ray Method in Structure Studies of Amorphous Solids [in Russian], Nauka, Novosibirsk (1988), pp. 6–24.
L. N. Mazalov, S. B. Érenburg, N. V. Bausk, et al.,Zh. Strukt. Khim.,38, No. 4, 723–731 (1997).
Author information
Authors and Affiliations
Additional information
Translated fromZhurnal Struktumoi Khimii, Vol. 39, No. 6, pp. 1121–1126, November–December, 1998.
Rights and permissions
About this article
Cite this article
Mazalov, L.N., Parygina, G.K., Fomin, É.S. et al. X-ray spectral study of the nature of electronic interactions in transition metal dithiocarbamates. J Struct Chem 39, 923–927 (1998). https://doi.org/10.1007/BF02903606
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF02903606