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Half-century history of clathrate chemistry

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Abstract

This paper is devoted to the history of a new field of knowledge — clathrate chemistry, whose 50th anniversary is being celebrated. The Historical Dates section contains data on clathrates from the first observations of these compounds (late 18th century) to the pioneering works (1947–1948) of the English crystallographer Herbert Marcus Powell explaining their nature. Major trends of research into clathrate chemistry since Powell’s works are discussed.

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References

  1. Gmelins Handbuch der Anorg. Chem.,B2, No. 9, Verlag Chemie, Weinheim (1960), p. 1102.

  2. J. W. Mellor,Comp. Treat. Inorg. Theor. Chem.,2, 51 (1922).

    Google Scholar 

  3. H. Davy,Phil. Trans. R. Soc. (London),101, 30(1811).

    Google Scholar 

  4. M. Faraday,Quart. J. Sci. Lit. Arts,15, 71 (1823).

    Google Scholar 

  5. A. de la Rive,Ann. Chim. Phys.,40, 401 (1829).

    Google Scholar 

  6. F. Wohler,Ann. Chem.,33, 125 (1840).

    Article  Google Scholar 

  7. F. Wohler,Ann. Chem. Liebigs,69, 297 (1849).

    Google Scholar 

  8. A. Clemm,ibid.,110, 357 (1859).

    Google Scholar 

  9. F. Mylius,Ber. Bunseng. Phys. Chem.,19, 999 (1886).

    Google Scholar 

  10. R. de Forcrand,Compt. Rend.,90, 1491–1493 (1880);95, 129 (1882);134, 835–838, 991–993 (1902);176, 355 (1923);181, 15 (1925).

    Google Scholar 

  11. R. de Forcrand and P. Villard,Compt. Rend.,106, 849–851, 1357–1359 (1888).

    Google Scholar 

  12. P. Villard,Compt. Rend.,107, 395–397 (1888);111, 302–305 (1890);118, 646–649 (1894);119, 368–371 (1894);123, 377–379 (1896);176, 1516 (1923).

    Google Scholar 

  13. H. le Chatelier,Compt. Rend.,99, 1074 (1884);101, 1474 (1885).

    Google Scholar 

  14. H. W. Roozeboom,Rec. Trav. Chim.,3, 29–58 (1884);4, 65–73 (1885).

    Google Scholar 

  15. K. A. Hofrnann and E. Küspert,Z. Anorg. AIIg. Chem.,15, 204 (1897).

    Google Scholar 

  16. K. A. Hofmann and H. Arnoldi,Ber.,39, 339 (1906).

    CAS  Google Scholar 

  17. A. P. Dianin,Zh. Ross. Fiz. Khim. Ova,43, 141 (1911);46, 1310 (1914).

    Google Scholar 

  18. K. Fredenhagen and G. Cadenbach,Z. Anorg. Allg. Chem.,158, 249 (1926).

    Article  CAS  Google Scholar 

  19. Y. Go and O. Kratky,Z. Phys. Chem.,B26. 439 (1934).

    CAS  Google Scholar 

  20. B. A. Nikitin,Selected Transactions. Noble Gas Chemistry [in Russian], USSR Academy of Sciences (1956), pp. 104–240.

  21. M. F. Bengen, Germ. Pat. OZ 123438 (1940); Germ. Pat. 869070 (1953);Techn. Oil Mission REEL,143, 135 (1946).

    Google Scholar 

  22. H. M. Powell and G. W. R. Bartindale,J. Chem. Soc, 799 (1945).

  23. D. E. Palin and H. M. Powell,ibid., 208 (1947).

  24. H. M. Powell,ibid., 61–73 (1948).

  25. J. H. Rayner and H. M. Powell,ibid., 319 (1952).

  26. D. Lawton and H. M. Powell,ibid., 2339 (1958).

  27. S. C. Wallwork and H. M. Powell,J. Chem. Soc, Perkin Trans.,2, 641 (1980).

    Google Scholar 

  28. H. M. Powell,Inclusion Compounds, Vol. 1, J. L. Atwood, J. E. D. Davies, and D. D. MacNicol (eds.), Academic Press, London (1984), pp. 1–28.

    Google Scholar 

  29. M. von Stackelberg,Naturwiss.,36, 327, 359 (1949).

    Article  CAS  Google Scholar 

  30. M. von Stackelberg and H. R. Muller,J. Chem. Phys.,19, 1319 (1951).

    Article  CAS  Google Scholar 

  31. M. von Stackelberg and H. R. Muller,Naturwiss.,38, 456 (1951).

    Article  Google Scholar 

  32. M. von Stackelberg and H. R. Muller,Angew. Chem.,64, 423 (1952).

    Google Scholar 

  33. M. von Stackelberg, A. Hoverath, and C. Scheringer,Z. Elektrochem.,62, 123 (1958).

    Google Scholar 

  34. W. F. Claussen,J. Chem. Phys.,19, 259–260, 1425–1426 (1951).

    Article  CAS  Google Scholar 

  35. L. Pauling and R. E. Marsh,Proc. Natl. Acad. Sci. US,38, 112 (1952).

    Article  CAS  Google Scholar 

  36. Obituary “Prof. H. M. ‘Tiny’ Powell,”J. Incl. Phenom.,10, 509 (1991).

    Google Scholar 

  37. J. E. D. Davies, W. Kemula, H. M. Powell, and N. O. Smith,ibid.,1, 3–44 (1983).

    Article  CAS  Google Scholar 

  38. E. Weber and H.-P. Josel,ibid.,1, 79–85 (1983).

    Article  CAS  Google Scholar 

  39. J. H. Van der Waals and J. C. Platteeuw,Adv. Chem. Phys.,2, 1–57 (1959).

    Article  Google Scholar 

  40. R.-M. Barrer and W. I. Stuart,Proc. R. Soc,A243, 172–189 (1957).

    CAS  Google Scholar 

  41. J.-M. Lehn,Supramolecular Chemistry. Concepts and Perspectives, VCH, Weinheim (1995).

    Google Scholar 

  42. C. J. Pedersen, J.-M. Lehn, and D. J. Cram,J. Incl. Phenom.,6, 337–350, 351–396, 397–413 (1988).

    Article  CAS  Google Scholar 

  43. G. A. Jeffrey and R. K. McMullan,Prog. Inorg. Chem.,8, 43–108 (1967).

    Article  CAS  Google Scholar 

  44. G. A. Jeffrey, in:Comprehensive Supramolecular Chemistry, Vol. 6. J. L. Atwood, J. E. D. Davies, D. D. MacNicol, and F. Vögtle (eds.), Pergamon, Oxford (1996), pp. 757–788.

    Google Scholar 

  45. G. A. Jeffrey, in:Inclusion Compounds, Vol. 1, J. L. Atwood, J. E. D. Davies, D. D. MacNicol, and F. Vögtle (eds.), Academic Press, London (1984), pp. 135–190.

    Google Scholar 

  46. D. W. Davidson, in:Water. A Comprehensive Treatise, Vol. 2, F. Franks (ed.), Plenum. New York (1973), pp. 115–234(1973).

    Google Scholar 

  47. J. A. Ripmeester and C. I. Ratcliffe, in:Inclusion Compounds, Vol. 5, J. L. Atwood, J. E. D. Davies, and D. D. MacNicol (eds.), Academic Press, London (1991), pp. 37–89.

    Google Scholar 

  48. H. Gies,ibid., pp. 1–36.

    Google Scholar 

  49. R. M. Barrer,ibid., Vol. 1, pp. 192–248 (1984).

    Google Scholar 

  50. M. D. Hollingsworth and K. D. M. Harris, in:Comprehensive Supramolecular Chemistry, Vol. 6, J. L. Atwood, J. E. D. Davies, D. D. MacNicol, and F. Vögtle (eds.), Pergamon, Oxford (1996), pp. 177–238.

    Google Scholar 

  51. F. H. Herbstein, —ibid., pp. 61–84.

    Google Scholar 

  52. R. Bishop, —ibid., pp. 85–116.

    Google Scholar 

  53. M. Miyata and K. Sada,ibid.ibid., pp. 147–176.

    Google Scholar 

  54. M. Gdaniec, B. T. Ibragimov, and S. A. Talipov, —ibid., pp. 117–146.

    Google Scholar 

  55. A. Collet, —ibid., pp. 281–304.

    Google Scholar 

  56. T. C. W. Mak and H. N. C. Wong, —ibid., pp. 351–370.

    Google Scholar 

  57. M. Farina, G. di Silvestro, and P. Sozzani, —ibid., pp. 371–398.

    Google Scholar 

  58. T. Kobayashi, S. Isoda, and K. Kubono, —ibid., pp. 399–420.

    Google Scholar 

  59. P. Dastidar and I. Goldberg, —ibid., pp. 305–350.

    Google Scholar 

  60. R. Gerdil, —ibid., pp. 239–280.

    Google Scholar 

  61. J. L. Flippen, J. Karle, and I. L. Karle,J. Am. Chem. Soc.,92, 3749 (1970).

    Article  CAS  Google Scholar 

  62. J. L. Flippen and J. Karle,J. Phys. Chem.,75, 3566 (1971).

    Article  CAS  Google Scholar 

  63. D. D. MacNicol, in:Inclusion Compounds, Vol. 2, J. L. Atwood, J. E. D. Davies, and D. D. MacNicol (eds.), Academic Press, London (1984), p. 124.

    Google Scholar 

  64. D. D. MacNicol and G. A. Downing, in:Comprehensive Supramolecular Chemistry, Vol. 6, J. L. Atwood, J. E. D. Davies, D. D. MacNicol, and F. Vögtle (eds.), Pergamon, Oxford (1996), pp. 421–464.

    Google Scholar 

  65. W. D. Schaeffer, W. S. Dorsey, D. A. Skinner, and C. D. Christian,J. Am. Chem. Soc,79, 5870–5876 (1957).

    Article  CAS  Google Scholar 

  66. J. Hanotier and P. Radzitzky, in:Inclusion Compounds, Vol. 1, J. L. Atwood, J. E. D. Davies, and D. D. MacNicol (eds.), Academic Press, London (1984), pp. 105–134.

    Google Scholar 

  67. S. A. Allison and R. M. Barrer,J. Chem. Soc,A, 1717–1723 (1969).

    Google Scholar 

  68. J. Lipkowski, in:Inclusion Compounds, Vol. 1, J. L. Atwood, J. E. D. Davies, and D. D. MacNicol (eds.), Academic Press, London (1984), pp. 59–103.

    Google Scholar 

  69. J. Lipkowski, in:Comprehensive Supramolecular Chemistry, Vol. 6, J. L. Atwood, J. E. D. Davies, D. D. MacNicol, and F. Vögtle (eds.), Pergamon, Oxford (1996), pp. 691–714.

    Google Scholar 

  70. T. Iwamoto, in:Inclusion Compounds, Vol. 1, J. L. Atwood, J. E. D. Davies, and D. D. MacNicol (eds.), Academic Press, London (1984), pp. 29–57.

    Google Scholar 

  71. T. Iwamoto,Inorg. Chim. Acta,2, 269–272 (1968).

    Article  CAS  Google Scholar 

  72. T. Iwamoto and Y. Ohtsu,Chem. Lett., 463–468 (1972).

  73. J. L. Atwood, J. E. D. Davies, and D. D. MacNicol (eds.),Comprehensive Supramolecular Chemistry. Solid State Supramolecular Chemistry. Crystal Engineering, Vol. 6, J. L. Atwood, J. E. D. Davies, and D. D. MacNicol (eds.), Pergamon, Oxford (1996).

    Google Scholar 

  74. M. P. Byrn, C. J. Curtis, Y. Hsiou, et al.,Comprehensive Supramolecular Chemistry, Vol. 6, Pergamon, Oxford (1996), pp. 715–732.

    Google Scholar 

  75. M. Fujita, Y. J. Kwon, S. Washizu, and K. Ogura,J. Am. Chem. Soc,116, 1151–1152 (and refs. 2, 3, and 4) (1994).

    Article  CAS  Google Scholar 

  76. M. J. Zaworotko,Chem. Soc. Rev.,23, 283–288 (1994).

    Article  CAS  Google Scholar 

  77. T. Kitazawa, S. Nishikiori, R. Kuroda, and T. Iwamoto,Chem. Lett., 1729–1732 (1988).

  78. T. Iwamoto, S. Nishikiori, T. Kitazawa, and H. Yuge,J. Chem. Soc, Dalton Trans., 4127–4136 (1997).

  79. F. Okino and H. Touhara, in:Comprehensive Supramolecular Chemistry, Vol. 7, J. L. Atwood, J. E. D. Davies, D. D. MacNicol and F. Vögtle (eds.), Pergamon, Oxford (1996), pp. 25–76.

    Google Scholar 

  80. J. Rouxel,ibid., pp. 77–106.

    Google Scholar 

  81. A. Clearfield and U. Constantino,ibid., pp. 107–150.

    Google Scholar 

  82. G. Alberti,ibid., pp. 151–188.

    Google Scholar 

  83. J. L. Atwood, J. E. D. Davies, D. D. MacNicol and F. Vögtle (eds.),Comprehensive Supramolecular Chemistry. Cyclodextrins, Vol. 3, Pergamon, Oxford (1996).

    Google Scholar 

  84. Topics in Inclusion Science. Calixarens: A Versatile Class of Macrocyclic Compounds, Vol. 3, Kluwer Academic, Dordrecht (1990).

  85. C. J. Pedersen,J. Am. Chem. Soc,89, 2495–2496, 7017–7036 (1967).

    Article  CAS  Google Scholar 

  86. M. Sitarski,Roczn. Chem.,49, 159 (1975).

    CAS  Google Scholar 

  87. V. R. Belosludov, Yu. A. Dyadin, and M. Yu. Lavrentiev,Theoretical Models of Clathration [in Russian], Nauka, Novosibirsk (1991).

    Google Scholar 

  88. J. Tse,International Conference on Natural Gas Hydrates, Ann. N. Y. Academy of Sciences,715, (1994), pp. 187–206.

    CAS  Google Scholar 

  89. V. P. Shpakov, J. S. Tse, C. A. Tulk, et al.,Chem. Phys. Lett.,282, 107–114 (1998).

    Article  CAS  Google Scholar 

  90. H. Tanaka and K. Kiyohara,J. Chem. Phys.,98, 4098–4109 (1993).

    Article  CAS  Google Scholar 

  91. B. Kvamme, G. Huseby, and O. K. Forrisdahl,Mol. Phys.,90, 979–991 (1997).

    Article  CAS  Google Scholar 

  92. V. G. Vasiliev, Yu. F. Makogon, F. A. Trebin, et al.,Inventions in the USSR. 1968-1969, TsNIIPI, Moscow (1970).

    Google Scholar 

  93. K. A. Kvenvolden,International Conference on Natural Gas Hydrates, Ann. N. Y. Academy of Sciences,715, 232 (1994).

    CAS  Google Scholar 

  94. D. W. Breck,Zeolite Molecular Sieves: Structure, Chemistry, and Use, Wiley, New York (1974).

    Google Scholar 

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Translated fromZhurnal Strukturnoi Khimii, Vol. 40, No. 5, pp. 797–808, September–October, 1999

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Dyadin, Y.A., Terekhova, I.S., Rodionova, T.V. et al. Half-century history of clathrate chemistry. J Struct Chem 40, 645–653 (1999). https://doi.org/10.1007/BF02903441

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