Abstract
Raman spectrum of allyl acetate molecule has been photographed in liquid phase using 4358 Å line of mercury arc as the exciting line. Infrared absorption spectrum of the molecule has been recorded in liquid phase in the frequency range 200–4000 cm−1. Both the spectra have been analysed to identify the fundamental frequencies. AssumingC s symmetry, the observed fundamental frequencies have been assigned to various modes of vibration and compared with the frequencies of allyl halides and acetic acid. On the basis of present assignments of fundamental vibrational frequencies and assumed approximate structural parameters of the molecule, thermodynamic functions have been computed.
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Abbreviations
- X:
-
OCOCH3
- s:
-
strong
- vs:
-
very strong
- vvs:
-
very very strong
- m:
-
medium
- mw:
-
medium weak
- w:
-
weak
- vw:
-
very weak
- vvw:
-
very very weak
- b:
-
broad
- v :
-
stretching
- a :
-
angle deformation
- β:
-
in-plane bending
- γ:
-
out-of-plane bending
- φ:
-
torsional deformation
References
Bothner-By A A and Naar-Colin C 1961J. Am. Chem. Soc. 83 231
Bothner-By A A, Naar-Colin C and Gunter H 1962J. Am. Chem. Soc. 84 2748
Bothner-By A A and Gunter 1962Disc. Faraday Soc. 34 127
Chao J and Zwolinski B J 1978J. Phys. Chem. 7 363
Colthup N B 1964Introduction to infrared and Raman spectroscopy (New York: Academic Press)
David R L and Mann D E 1967J. Chem. Phys. 27 868
Fateley W G and Miller F A 1961Spectrochim. Acta 17 857
Fateley W G and Miller F A 1963Spectrochim. Acta 19 611
Fukushima K and Zwolinski B J 1969J. Chem. Phys. 50 737
Gunde R and Azman A 1975J. Mol. Struct. 27 212
Herzberg G 1945Molecular spectra and molecular structure. Infrared and Raman spectra of polyatomic molecules (New York: Van Nostrand)
Herschbach D R 1962Symposium on molecular structure and spectroscopy (Science Council of Japan, Tokyo) C 401
Herschbach D R and Krisher L C 1958J. Chem. Phys. 28 728
Hirota E 1965J. Chem. Phys. 42 2071
Lin C C and Swalen J D 1959Rev. Mod. Phys. 31 841
McLachlan R D and Nyquist R A 1968Spectrochim. Acta A24 103
Miller F A, Fateley W G and Witkowski R E 1967Spectrochim. Acta A23 891
Millikan R C and Pitzer K S 1957J. Chem. Phys. 27 1305
Nakanishi K 1966Infrared absorption spectroscopy practical (San Francisco: Holden Day and Tokyo: Naukodo Co.)
Pitzer K S and Gwinn W D 1942J. Chem. Phys. 10 428
Shimanouchi 1972Recommendation tables of molecular vibrational frequencies consolidated NSRDS-NBS 39, U.S. Govt. Printing Press, Washington D.C., Vol. 1
Siegel S 1957J. Chem. Phys. 27 989
Silvi B, Labarbe P and Perchard J P 1973Spectrochim. Acta A29 263
Tabor W J 1957J. Chem. Phys. 25 1171
Torgrimsen T and Klaboe P 1974J. Mol. Struct. 20 213, 229
Wilmshurst J K 1956J. Chem. Phys. 25 1171
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Singh, B., Prasad, R. & Jaiswal, R.M.P. Vibrational spectra and thermodynamic functions of allyl acetate. Formerly: Proceedings (Chemical Sciences) 89, 201–207 (1980). https://doi.org/10.1007/BF02893005
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DOI: https://doi.org/10.1007/BF02893005