Abstract
Decomposition of 2-propanol has been studied on vanadium pentoxide with MoO3 and WO3 additives. It has been observed that a small amount of the additives increases the dehydration activity of the catalysts, but at 5% or higher concentration, dehydration of 2-propanol decreases. The initial increase followed by a decrease in the dehydration activity with increased amount of additives is due to the change in the rate-determining step. Addition of MoO3, WO3, and alkali metal oxides to vanadium pentoxide has similar effects on the V4+ concentration and catalytic activity. Based on the results of the kinetic and ESR spectral studies, a scheme for the reaction has been proposed. It is concluded that the concentration of V4+ ion plays the crucial role in these catalysts.
Similar content being viewed by others
References
Chakrabarty D K, Guha D, Bhatnagar I K and Biswas A B 1976J. Catal. 45 305
Chakrabarty D K, Guha D and Biswas A B 1976J. Mat. Sci. 11 1347
Chakrabarty D K and Guha D 1977React. Kinet. Catal. Lett. 6 307
Chakrabarty D K, Guha D and Biswas A B 1977J. Solid State Chem. 22 263
Ioffe V A and Patrina I B 1970Phys. Status Solidi 40 389
Mars P and Maessen J G H 1968J. Catal. 10 1
Nakamura M, Kawai K and Jujiwara Y 1974J. Catal. 34 345
Tarama K, Teranishi S, Yoshida S and Tamura N 1964Proc. Int. Cong. Catal. (Amsterdam: North Holland)1 282
Vorontyntsev V M, Shevts V A and Kazansky V B 1971Kinet. Katal. 12 678
Author information
Authors and Affiliations
Additional information
Deceased October 1979
Rights and permissions
About this article
Cite this article
Chakrabarty, D.K., Rajyalakshmi, M. & Biswas, A.B. The role of V4+ ions in vanadium oxide catalysts I. Decomposition of 2-propanol. Formerly: Proceedings (Chemical Sciences) 89, 131–137 (1980). https://doi.org/10.1007/BF02892997
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF02892997