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The role of sulfur in the pyrolysis of kerogen

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Chinese Science Bulletin

Abstract

Sulfur plays an important role in the generation and evolution of hydrocarbon from organic matter. Here, a pyrolysis experiment in closed system was performed on Maoming oil shales kerogen (Type I), Maoming oil shales kerogen added with sulfur ether and Maoming oil shales kerogen added with sulphur. The results suggest that the existence of sulfur can result in: (i) higher yield of hydrocarbons generated from the kerogen; (ii) decrease of the temperature for the maximum generation of heavy hydrocarbons (the C15+ fraction) by 20°C; (iii) decrease of the temperature for the maximum generation of the aromatics fraction by 40°C, and (iv) acceleration of the aromatization process. The pyrolysates from kerogen added with sulfur are similar to the heating products of the sulfur-rich kerogen as reported in the literatures. It seems that the sulfur catalysis is also an important factor that can make the sulfur-rich kerogen generate low-mature oil at the earlier diagenesis stage, except for the weakness of the C-S and S-S bonds.

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References

  1. Damste, J. S. S., De Leeuw, J. W., Analysis structure and geochemical significance of organically-bound sulphur in the geosphere: State of the art and future research, in Advances in Organic Geochemistry 1989 (eds. Durand, B., Behar, F.), Organic Geochemistry, 1990, 16: 1077–1101.

  2. Damste, J. S. S., Eglinton, T. I., De Leeuw, J. W. et al., Organic sulphur in macromolecular sedimentary organic matter: I. Structure and origin of sulphur-containing moieties in kerogen, asphaltene and coal as revealed by flash pyrolysis, Geochimica et Cosmochimica Acta, 1989, 53: 873–889.

    Article  Google Scholar 

  3. van Dongen, B. E., Schouten, S., Baas, M. et al., An experimental study of the low-temperature sulfurization of carbohydrates, Organic Geochemistry, 2003, 34(8): 1129–1144.

    Article  Google Scholar 

  4. Marika, D. K., Schouten, S., Sinninghe Damsté, J. S., Formation of insoluble, nonhydrolyzable, sulfur-rich macromolecules via incorporation of inorganic sulfur species into algal carbohydrates, Geochimica et Cosmochimica Acta, 2000, 64(15): 2689–2699.

    Article  Google Scholar 

  5. Gelin, F., Marika, D. K., de Leeuw, J. W. et al., Laboratory sulfurisation of the marine microalgaNannochloropsis salina, Organic Geochemistry, 1998, 29(8): 1837–1848.

    Article  CAS  Google Scholar 

  6. Xia Yanqing, Meng Qianxiang, Wang Hongyong et al., The simulation of the formation of benzothiophene series compounds and their significance, Acta Sedimentologica Sinica (in Chinese), 1999, 17(1): 127–129.

    Google Scholar 

  7. Xia Yanqing, Wang Chunjiang, Meng Qianxiang et al., Investigation of mechanisms of formation of biphenyls and benzonaph-thothiophenes by simulation experiment, Sciences in China (in Chinese), 1999, 29(3): 257–262.

    Google Scholar 

  8. Xia Yanqing, Wang Chunjiang, Meng Qianxiang et al., The simulation on the mechanism of formation of thiophene series compounds, Geochimica (in Chinese), 1999, 28(4): 393–396.

    CAS  Google Scholar 

  9. Fu Jiamo, Sheng Guoying, Jiang Jigang, Immature crude oil from hypersaline environmental deposition, Oil & Gases (in Chinese), 1986, 6(2): 150–158.

    Google Scholar 

  10. Jiang Jigang, Sheng Guoying, Fu Jiamo, The discovery of high sulfur immature crude oil in salt lake basin, Experiments for Oil and Gas (in Chinese), 1988, 10(4): 337–342.

    Google Scholar 

  11. Peng Pingan, Fu Jiamo, Sheng Guoying et al., Geochemical characteristics of supergene organic matter in hypersaline environment, Sciences in China (in Chinese), Ser. B, 1989(1): 84–92.

  12. Peng Pingan, Sheng Guoying, Fu Jiamo et al., Origin of immature sulfur-rich oil in Jianghan oil field, Chinese Science Bulletin (in Chinese), 1998, 43(6): 636–638.

    Google Scholar 

  13. Peng Ping’an, Sheng Guoying, Fu Jiamo et al., Immature crude oils in the salt lake depositional environment are related to organic matter precipitated at stage of carbonate in salt lake sedimentation sequences, Chinese Science Bulletin (in Chinese), 2000, 45 (Supplement): 2689–2694.

    Article  Google Scholar 

  14. Wang Tieguan, Zhong Ningning, Hou Dujie et al., Genetic mechanism and occurrence of immature oil and gas (in Chinese), Beijing: Petroleum Industry Press, 1995.

    Google Scholar 

  15. Wang Tieguan, Zhong Ningning, Hou Dujie et al., Several genetic mechanisms of immature crude oils in China, Acta Sedimentologica Sinica, 1997, 15(2): 75–83.

    Google Scholar 

  16. Zhang Linye, Zhang Shouchun, Huang Kaiquan et al., Simulation experiment of immature oil genetic mechanism in lake facies of semi-salt water, Chinese Science Bulletin (in Chinese), 1999, 44(4): 361–368.

    Google Scholar 

  17. Qin Kuangzong, Guo Shaohui, Lishuyuan, Structure of organic geological macromolecules and generation of immature oil, Petroleum Exploration and Development, 1997, 24(5): 1–6.

    CAS  Google Scholar 

  18. Hold, I. M., Brussee, N. J., Schouten, S. et al., Changes in the molecular structure of a Type II-S kerogen (Monterey Formation, U.S.A.) during sequential chemical degradation, Organic Geochemistry, 1998, 29: 1403–1417.

    Article  CAS  Google Scholar 

  19. Lewan, M. D., Ruble, T. E., Comparison of petroleum generation kinetics by isothermal hydrous and nonisothermal open-system pyrolysis, Organic Geochemistry, 2002, 33(12): 1457–1475.

    Article  CAS  Google Scholar 

  20. Putschew, A., Schaeffer-Reiss, C., Schaeffer, P. et al., Release of sulfur- and oxygen-bound components from a sulfur-rich kerogen during simulated maturation by hydrous pyrolysis, Organic Geochemistry, 1998, 29(8): 1875–1890.

    Article  CAS  Google Scholar 

  21. Tannenbaum, E., Aizenshtat, Z., Formation of immature asphalt from organic-rich carbonate rocks-I. Geochemical correlation, Organic Geochemistry, 1985, 8: 181–192.

    Article  CAS  Google Scholar 

  22. Baskin, D. K., Peters, K. E., Early generation characteristics of a sulfur-rich Monterey Kerogen, The American Association of Petroleum Geologists Bulletin, 1992, 76(1): 1–13.

    CAS  Google Scholar 

  23. Orr, W. L., Kerogen/asphaltene/sulfur relationships in sulfur-rich Monterey oils, Organic Geochemistry, 1986, 10: 499–516.

    Article  CAS  Google Scholar 

  24. Bazhenova, O. K., Arefiev, O. A., Immature oils as the products of early catagenetic transformation of bacterial-algal organic matter, Organic Geochemistry, 1990, 16(1-3): 307–311.

    Article  CAS  Google Scholar 

  25. Lewan, M. D., Sulphur-radical control on petroleum formation rates, Nature, 1998, 391: 164–166.

    Article  CAS  Google Scholar 

  26. Fu Jiamo, Xu Yufen, Chen Deyu et al., Biomarker compounds of biological inputs in Maoming oil shale, Geochemistry (in Chinese), 1985, (2): 99–114.

  27. Radke, M., Welte, D. H., Willsch, H., Geochemical study on a well in the Western Canada Basin: relation of the aromatic distribution pattern to maturity of organic matter, Geochimica et Cosmochimica Acta, 1982, 46(1): 1–10.

    Article  CAS  Google Scholar 

  28. Ronald, J. H., Tang, Y. C., Kaplan, I. R., Insights into oil cracking based on laboratory experiments, Organic Geochemistry, 2003, 34(12): 1651–1672.

    Article  Google Scholar 

  29. Tomic, J., Behar, F., Vandenbroucke, M. et al., Artificial maturation of Monterey kerogen (Type II-S) in a closed system and comparison with Type II kerogen: Implications on the fate of sulfur, Organic Geochemistry, 1995, 23(7): 647–660.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. State Key Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, 510640, Guangzhou, China

    Qin Yan, Ping’an Peng, Chiling Yu & Jinzhong Liu

  2. Graduate School of the Chinese Academy of Sciences, 100039, Beijing, China

    Qin Yan

Authors
  1. Qin Yan
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  2. Ping’an Peng
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  3. Chiling Yu
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  4. Jinzhong Liu
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Correspondence to Ping’an Peng.

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Yan, Q., Peng, P., Yu, C. et al. The role of sulfur in the pyrolysis of kerogen. Chin. Sci. Bull. 49 (Suppl 1), 10–18 (2004). https://doi.org/10.1007/BF02890448

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  • DOI: https://doi.org/10.1007/BF02890448

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