Skip to main content
Log in

The planimetric unfold method of fullerene cage structure

  • Notes
  • Published:
Chinese Science Bulletin

Abstract

Two kinds of planimetric diagrams, which consist of the boat form F6 and F5, the storm petrel form F6 and F5, respectively, were proposed to express the geometric structure of fullerene cage in this study. There are two chief advantages using the diagrams: (i) the spatial symmetrical characteristic of fullerene cage is not destroyed; (ii) the coordination forms of F5 and F6 in the structure can be clearly expressed. This work has laid the foundation for studying the structural geometry of fullerene cage and its quantum chemistry and property.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Kroto, H. W., Heath, J. R., O’Brien, S. C. et al., C60: Buckminsterfullerene, Nature, 1985, 318: 162.

    Article  CAS  Google Scholar 

  2. Kratschmer, K., Lamb, L. D., Fostiropoulos, K. et al., Solid C60: a new form of carbon, Nature, 1990, 347: 354.

    Article  Google Scholar 

  3. Kroto, H. W., C60: Buckminsterfullerene, the celestial sphere that fell to earth, Angewante Chemic (International ed.), 1992, 31:111.

  4. Kroto, H. W., Space, stars, C60 and soot, Science, 1988, 242: 1139.

    Article  PubMed  CAS  Google Scholar 

  5. Zheng Zhe, Ye Danian, He Wei, The research survey of carbon and fullerene, Reviews and Prospects of Mineralogy, Petrology and Geochemistry at the Boundary of Two Centuries (ed. Ouyang Ziyuan) (in Chinese), Beijing: Atomic Energy Press, 1998, 25–29.

    Google Scholar 

  6. Manolopoulos, D. E., May, J. C., Down, S. E., Theoretical studies of the fullerenes: C34 to C70, Chem. Phys. Letters, 1991, 181: 105.

    Article  CAS  Google Scholar 

  7. Yannoni, C. S., Johnson, R. D., Meijer, G. et al.,11CNMR study of the C60 cluster in the solid state: molecular motion and carbon chemical shift anisotropy, Journal of Physical Chemistry, 1991, 95: 9.

    Article  CAS  Google Scholar 

  8. Iijima, S., The 60-carbon cluster has been revealed! Journal of Physical Chemistry, 1987, 91: 3466.

    Article  CAS  Google Scholar 

  9. Ebbesen, T. W., Making bucks, Nature, 1993, 361: 218.

    Article  Google Scholar 

  10. Heinney, P. A., Fischer, J. E., McGhie, A. R. et al., Orientational ordering transition in solid C60, Phys Rev. Lett., 1991. 66: 2911.

    Article  Google Scholar 

  11. Mistutaka, F., Geometrical study for fullerence structures and construction of new carbon forms, Tanso, 1994, 162: 100.

    Google Scholar 

  12. Hawkins, J. M., Meyer, A., Lewis, T. A. et al., Crystal structure of osmylated C60: confirmation of the soccer ball framework, Science, 1991, 252: 312.

    Article  PubMed  CAS  Google Scholar 

  13. Fowler, P. W., Steer, J. I., The leapfrog principle: A rule for electron counts of carbon clusters, Chemical Communications, 1987, 1403.

  14. Fowler, P. W., Three candidates for the structure of C84, Journal of the Chemical Society, Faraday Transactions, 1991, 87: 1945.

    Article  CAS  Google Scholar 

  15. Fowler, P. W., Batten, R. C., Manolopoulos, D. E., The higher fullerenes: a candidate for the structure of C78, Journal of the Chemical Societv. Faradav Transactions, 1991, 87: 3103.

    Article  CAS  Google Scholar 

  16. He Wei, Zheng Zhe, Ye Danian, Structural representative of fullerence cages Cn, Scientia Geologica Sinica (in Chinese), 1997, 32(3): 313.

    CAS  Google Scholar 

  17. Zheng Zhe, Zheng Weixing, Ye Danian et al., Solution and significance of structural representative of fullerene cages, Acta Petrologica Sinica (in Chinese), 2000, 16(2): 288.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

About this article

Cite this article

Ye, D., Ai, D., He, W. et al. The planimetric unfold method of fullerene cage structure. Chin.Sci.Bull. 45, 1893–1896 (2000). https://doi.org/10.1007/BF02886301

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02886301

Keywords

Navigation