Abstract
The measurements of electric capacities and dielectric loss angles for nanocrystalline γ-Fe2O3, under air and vacuum atmospheres have been conducted by using ac LRC method, and the conductivity and the polarization relaxation time have also been calculated from the frequency spectra of real and imaginary parts of the dielectric constants. The anomalous dielectric behavior implies the existence of two kinds of polarization mechanisms with different relaxation times, which are caused by the defects and the dangling bonds in the interfaces, respectively. The experimental and calculated results indicated that the polarization loss and the conductance loss are dominant in air atmosphere and vacuum, respectively.
Similar content being viewed by others
References
Karch, J., Birringer, R., Gleiter, H., Ceramics ductile at low temperature,Nature, 1987, 330(6148): 556.
Gleiter, H., Nanocrystalline materials,Progress in Materials Science, 1989, 33(1): 223.
Lu, K., Zhou, F., Recent research progresses in nanocrystalline materials,Acta Metallugica Sinica (in Chinese), 1997, 33 (1): 99.
Zhu, X., Birringer, R., Herr, U.et al., X-ray diffraction studies of the structure of nanometer-sized crystalline materials,Phys. Rev. B, 1987, 35(17): 9085.
Sodheimer, E. H., The influence of a transverse magnetic field on the conductivity of thin films,Physics Review, 1950, 80 (3): 401.
Krick, D. T., Lenahan, P. M., Electrically active point defects in amorphous silicon nitride: an illumination and charge injection study,Journal of Applied Physics, 1988, 64(7): 3588.
Wang, T., Zhang, L. D., Mou, J. M., Anomalous dielectric behavior in nanometer-sized amorphous silicon nitride,Chinese Physics Letters, 1993, 10(11): 676.
Zhang, H. F., Wang, L. Z., Zhang, L. D.et al., Dielectric behavior in nanostructured solid of mtile TiO2,Acta Physica Sinica, 1996, 45(6): 1046.
Wang, T., Zhang, L. D., Interfacial polarization and its mechanism of nanostmctured amorphous silicon nitride,Chinese Science Bulletin, 1994, 39(18): 1511.
Clark, S. P. Jr.,Handbook of Physical Constants (revised edition), New York: the Geological Society of America, Inc. 1966. 565.
Ye, X. S., Sha, J., Fang, H.et al., Structural phase transition in nanostructured y-Fe2O3,Chinese Science Bulletin, 1997, 42(11): 894.
Debye, P.,Polar Molecules, Dover, Dover Publications, Inc. 1928, 92–107, Li, H. R.,Introduction to Dielectric Physics (in Chinese), Chengdu: Chengdu Science and Technology University Press, 1990, 129.
Author information
Authors and Affiliations
About this article
Cite this article
Ye, X., Sha, J., Chen, B. et al. Anomalous dielectric behavior in nanocrystalline γ-Fe2O3 . Chin. Sci. Bull. 44, 186–189 (1999). https://doi.org/10.1007/BF02884749
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF02884749