Abstract
Using local mode description for methyl chloride, the infrared intensities for the first four CH3 stretching overtone bands are used to calculate the dipole function for the C-H bond. Detailed expressions for overtone transitions for diatomic molecules derived by Bouanich are employed for the calculation of dipole moment derivatives.
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Jayaraj, A.F., Singh, S. Dipole function for the C-H oscillator. Proc. Indian Acad. Sci. (Chem. Sci.) 109, 181–188 (1997). https://doi.org/10.1007/BF02883488
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DOI: https://doi.org/10.1007/BF02883488