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The N−Pu (Nitrogen-Plutonium) system

  • Alloy Phase Diagram Evaluations
  • N−Pu
  • Published:
Bulletin of Alloy Phase Diagrams

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Cited References

  • 48Zac: W.H. Zachariasen, “The Crystal Structure of PuN and PuC,” USAEC, U. Chicago, Rep. AECD-2195 (1948);Met. Abst. (Sec. 2)19, 121 (1951). (Crystal Structure; Experimental)

  • 49Zac1: W.H. Zachariasen, “The Crystal Structure of Plutonium Nitride and Plutonium Carbide,”The Transuranium Elements, Nat. Nucl. Energy Ser., Div. 4, Vol 14B, No. 2, G.T. Seaborg, J.J. Katz, and W.M. Manning, Ed., McGraw-Hill, New York, 1448–1450 (1949). (Crys Structure; Experimental)

    Google Scholar 

  • 49Zac2: W.H. Zachariasen, “Crystal Chemical Studies of the 5f-Series of Elements. XII. New Compounds Representing Known Structure Types,”Acta Crystallogr., 2 388–390 (1949). (Crys Structure; Compilation)

    Article  Google Scholar 

  • 54Bal: J.G. Ball, P. Greenfield, P.G. Mardon, and J.A.L. Robertson, “The Crystal Structures of Plutonium. The δ and ε Phases,” United Kingdom At. Energy Authority, Harwell, Rep. AERE M/R 2416 (1954). (Crys Structure; Experimental)

  • 55Bro: F. Brown, H.M. Ockenden, and G.A. Welch, “The Preparation and properties of Some Plutonium. Compounds. Part II. Plutonium Nitride,”J. Chem. Soc. (London), 4196–4201 (1955). (Crys Structure; Experimental)

  • 55Zac: W.H. Zachariasen and F.H. Ellinger, “Crystal Chemical Studies of the 5f-Series of Elements. XXIV. The Crystal Structure and Thermal Expansion of γ-Plutonium,”Acta Crystallogr., 8, 431–433 (1955). (Crys Structure; Experimental)

    Article  Google Scholar 

  • 56Blo: J.M. Blocher, Jr., “Nitrides,”High-Temperature Technology, I.E. Campbell, Ed., John Wiley, New York, 171–187 (1956). (Meta Phases; Review)

    Google Scholar 

  • 56Ell: F.H. Ellinger, “Crystal Structure of Delta-Prime Plutonium and the Thermal Expansion Characteristics of Delta, Delta Prime, and Epsilon Plutonium,”J. Met., 8, 1256–1259 (1956). (Crys Structure; Experimental)

    Google Scholar 

  • 61Ell: F.H. Ellinger, “A Review of the Intermetallic Compounds of Plutonium,”The Metal Plutonium, A.S. Coffinberry and W.N. Miner, Ed., Univ. Chicago, Chicago, 281–308 (1961). (Crys Structure; Compilation)

    Google Scholar 

  • 62Car1: D.F. Carroll, “Thermal Expansion of Plutonium Nitride,” USAEC, Hanford Lab., Rep. HW-75125 (1962). (Crys Structure; Experimental)

  • 62Car2: D.F. Carroll, “Syntheses and Properties of Plutonium Mononitride,” USAEC, Hanford Lab., Rep. HWSA-2755 (1962). (Equi Diagram, Thermo; Experimental)

  • 62Ran1: M.H. Rand and R.S. Street, “High Temperature X-Ray Diffraction Studies—Part 3. Plutonium Nitride and Plutonium Sesquicarbide,” United Kingdom At. Energy Auth., Harwell, Rep. AERE-M-973(1962). (Equi Diagram, Crys Structure; Experimental)

  • 62Ran2: M.H. Rand, A.C. Fox, and R.S. Street, “Radiation Self-Damage in Plutonium Compounds,”Nature, 195, 567–568 (1962). (Crys Structure; Experimental)

    Article  ADS  Google Scholar 

  • 63Ans1: F. Anselin, “Simple Method of Preparation of the Nitrides of the Actinide and Rare Earth Metals,”C.R. Acad. Sci. Paris, 256, 2616–2619 (1963) in French. (Crys Structure; Experimental)

    Google Scholar 

  • 63Ans2: F. Anselin, “Study of the Nitrides of Uranium, of Plutonium, and of Their Solid Solutions,”J. Nucl. Mater., 10(4), 301–320 (1963) in French. (Equi Diagram, Crys Structure; Experimental)

    Article  ADS  Google Scholar 

  • 63Car: D.F. Carroll, “Thermal Expansion of Plutonium Nitride,”J. Am. Ceram. Soc., 46(8), 406 (1963). (Crys Structure; Experimental)

    Article  Google Scholar 

  • 63Ols: W.M. Olson, “Plutonium-Nitrogen System,” Quarterly Status Report on Solid Plutonium Fuels Program for Period up to June 30, 1963, J.A. Leary, W.J. Maraman, W.N. Miner, F.W. Schonfield, Ed., USAEC, Los Alamos Sci. Lab., Rep. LAMS-2949 (1963). (Equi Diagram, Crys Structure, Thermo; Experimental)

  • 63Zac1: W.H. Zachariasen and F.H. Ellinger, “The Crystal Structure of Alpha Plutonium Metal,”Acta Crystallogr., 16, 777–783 (1963). (Crys Structure; Experimental)

    Article  Google Scholar 

  • 63Zac2: W.H. Zachariasen and F.H. Ellinger, “The Crystal Structure of Beta Plutonium Metal,”Acta Crystallogr., 16, 369–375 (1963) (Crys Structure; Experimental)

    Article  Google Scholar 

  • 64Ans: F. Anselin, G. Dean, R. Lorenzelli, and R. Pascard, “On the System (UPu)(CNO) as Applied to Sintered Carbides, Carbonitrides, and Oxycarbides”Carbides in Nuclear Energy Vol. 1, L.E. Russell, B.T. Bradbury, J.D.L. Harrison, H.J. Hedger, and P.G. Mardon, Ed., Macmillan, London, 113–161 (1964) (Equi Diagram, Crys Structure; Experimental)

    Google Scholar 

  • 64Car: D.F. Carroll, “PuN and the Refractory Nitrides,” USAEC, Hanford Lab., Rep. HW-SA-3370 (1964). (Equi Diagram, Thermo; Experimental)

  • 64Cos: P. Costa, R. Lallement, F. Anselin, and D. Rossignol, “Magnetic Transitions in Uranium and Plutonium Mononitrides, Monocarbides, and Sesquicarbides,”Compounds of Interest in Nuclear Reactor Technology J.T. Waber, P. Chiotti, W.N. Miner, Ed., AIME, New York, 83–91 (1964). (Equi Diagram; Experimental)

    Google Scholar 

  • 64Ols: W.M. Olson and R.N.R. Mulford, “The Decomposition Pressure of Plutonium Nitride,”J. Phys. Chem., 68, 1048–1051 (1964). (Equi Diagram, Crys Structure, Thermo; Experimental)

    Article  Google Scholar 

  • 64Sto: E.K. Storms, “A Critical Review of Refractories,” USAEC, Los Alamos Sci. Lab., Rep. LA-2942 (1964). (Equi Diagram; Review)

  • 66Cam1: G.M. Campbell and J.A. Leary, “Thermodynamic Properties of Plutonium Mononitride from Electromotive Force Measurements,”Trans. Am. Nucl. Soc., 9, 43 (1966). (Thermo; Experimental)

    Google Scholar 

  • 66Cam2: G.M. Campbell and J.A. Leary, “Thermodynamic Properties of Plutonium Mononitride from Electromotive Force Measurements,”J. Phys. Chem., 70(8), 2703–2705 (1966). (Thermo; Experimental)

    Article  Google Scholar 

  • 66Liv: D.T. Livey, “Phase Diagrams,”At. Energy Review, 4 (Spec. Issue No. 1), 53–72 (1966). (Equi Diagram; Review)

    Google Scholar 

  • 66Mul: R.N.R. Mulford, “The Vapour Pressure of Plutonium,”Thermodynamics Vol. 1 IAEA, Vienna, 231–241 (1966). (Equi Diagram; Experimental)

    Google Scholar 

  • 66Ran: M.H. Rand, “Thermochemical Properties,”At. Energy Review, 4(Spec. Issue No. 1), 7–51 (1966). (Thermo; Review)

    Google Scholar 

  • 67Ale: C.A. Alexander, J.S. Ogden, and W.M. Pardue “Vaporization of PuN and Alloys of UN-PuN,” Annual Report. Progress Relating to Civilian Applications during July 1966 through June 1967, D.L. Keller, Ed., USAEC, Battelle Memorial Inst., Rep. BMI-1809 (1967). (Equi Diagram, Thermo; Experimental)

  • 67Bjo: C.W. Bjorklund, R.M. Douglass, and R.L. Nance, “X-Ray Powder Diffraction,” Quarterly Status Report on the Advanced Plutonium Fuels Program, April 1–June 30, 1967, USAEC, Los Alamos Sci. Lab., Rep. LA-3745-MS (1967). (Crys Structure; Experimental)

  • 67Bri: N.J. Bridger and R.M. Dell, “Research on Plutonium Nitride,” United Kingdom At. Energy Auth., Harwell, Rep. AERE-R-5441 (1967). (Equi Diagram, Crys Structure; Review)

  • 67Ell: F.H. Ellinger, C.C. Land, and K.A. Gschneidner, Jr., “Alloying Behavior of Plutonium,”Plutonium Handbook Vol. 1, O.J. Wick, Ed., Gordon and Breach, New York, 191–247 (1967). (Crys Structure; Experimental)

    Google Scholar 

  • 67Lap: R. Lapage and J.L. Bunce, “Heat of Combustion of Plutonium Nitride,”Trans. Faraday Soc., 63, 1889–1894 (1967). (Crys Structure, Thermo; Experimental)

    Article  Google Scholar 

  • 67Lea: J.A. Leary, W.C. Pritchard, R.L. Nance and M.W. Shupe, “Refractory Plutonium Fuel Materials,”Plutonium 1965, A.E. Kay and M.B. Waldron, Ed., Chapman and Hall, London, 639–653 (1967). (Equi Diagram, Crys Structure; Experimental)

    Google Scholar 

  • 67Lee: J.A. Lee, J.A.C. Marples, K. Mendelssohn, and P.W. Sutcliffe, “Some Physical Properties of Plutonium Metal at Low Temperatures,”Plutonium 1965, A.E. Kay and M.B. Waldron, Ed., Chapman and Hall, London, 176–188 (1967). (Equi Diagram; Experimental)

    Google Scholar 

  • 67Oet: F.L. Oetting, “The Chemical Thermodynamic Properties of Plutonium Compounds,”Chem. Rev, 67, 261–297 (1967). (Thermo; Review)

    Article  Google Scholar 

  • 67Par: W.M. Pardue, V.W. Storhok, and R.A. Smith, “Properties of Plutonium Mononitride and Its Alloys,”Plutonium 1965, A.E. Kay and M.B. Waldron, Ed., Chapman and Hall, London, 721–738 (1967). (Equi Diagram, Crys Structure, Thermo; Experimental)

    Google Scholar 

  • 67Rea: J.G. Reavis, “Differential Thermal Analysis,” Quarterly Status Report on the Advanced Plutonium Fuels Program, April 1–June 30, 1967, USAEC, Los Alamos Sci. Lab., Rep. LA-3745-MS (1967). (Equi Diagram, Thermo; Experimental)

  • 67Tay: J.C. Taylor and P.F.T. Linford, “Specific Heats of α-Plutonium and α-Manganese,”Cryogenics, 7, 305 (1967). (Equi Diagram; Experimental)

    ADS  Google Scholar 

  • 68Cam1: G.M. Campbell, L.J. Mullins, and J.A. Leary, “Thermodynamic Properties of Plutonium Compounds by EMF Techniques,”Thermodynamics of Nuclear Materials, 1967, IAEA, Vienna, 75–88 (1968). (Crys Structure, Thermo; Experimental)

    Google Scholar 

  • 68Cam2: G.M. Campbell, “Thermodynamic Properties of PuN by Galvanostatic Potential Determination,” USAEC, Los Alamos Sci. Lab., Rep. LA-3945 (1968). (Thermo; Experimental)

  • 68Ken: R.A. Kent and J.A. Leary, “Mass Spectrometric Studies of Plutonium Compounds at High Temperatures: I. Heats of Vaporization of Gold and Plutonium and the Heat of Decomposition of Plutonium Mononitride,” USAEC, Los Alamos Sci. Lab., Rep. LA-3902 (1968). (Thermo; Experimental)

  • 68Lor: R. Lorenzelli, “Contribution to the Study of the System (U,Pu) C,N,” Comm, Energie Atomique, Cent. Etudes Nucl. Fontenay-aux-Roses, France, Rep. CEA-R-3536 (1968) in French; TR: USAEC, Oak Ridge Nat. Lab. ORNL-tr-3019. (Crys Structure; Experimental)

  • 68Spe1: K.E. Spear and J.M. Leitnaker, “Review and Analysis of Phase Behavior and Thermodynamic Properties of the Plutonium-Nitrogen System,” USAEC Oak Ridge Nat. Lab., Rep. ORNL-TM-2106 (1968). (Equi Diagram, Thermo; Review)

  • 68Spe2: K.E. Spear and J.M. Leitnaker, “A Consistent Set of Thermodynamic Values for Plutonium Mononitride,”J. Am. Ceram. Soc., 51(12), 706–709 (1968). (Thermo; Review)

    Article  Google Scholar 

  • 69Ale: C.A.Alexander, J.S. Ogden, and W.M.Pardue, “Thermodynamics and Transport Characteristics of PuN and Alloys of UN-PuN,” Progress on Development of Materials and Technology for Advanced Reactors during July through September 1969, D.E.Keller,Ed., USAEC, Battelle Memorial Inst., Rep. BMI-1872 (1969). (Equi Diagram; Experimental)

  • 69Cam: G.M. Campbell, “Thermodynamic Properties of Plutonium Nitride by Galvanostatic Potential Determination,”J. Phys. Chem., 73(2), 350–355 (1969). (Crys Structure, Thermo; Experimental)

    Article  Google Scholar 

  • 69Har: D.R. Harbur, J.W. Anderson, and W.J. Maraman, “The Pre α → β Transformation in High Purity Plutonium,”J. Nucl. Mater., 30, 289–296 (1969). (Equi Diagram; Experimental)

    Article  ADS  Google Scholar 

  • 69Joh: G.K. Johnson, E.H. Van Deventer, O.L. Kruger, and W.N. Hubbard, “The Enthalpies of Formation of Plutonium Dioxides and Plutonium Mononitride,”J. Chem. Thermodyn. 1, 89–98 (1969). (Crys Structure, Thermo; Experimental)

    Article  Google Scholar 

  • 69Ken1: R.A. Kent, “Mass Spectrometric Studies of Plutonium Compounds at High Temperatures. III. The Vapor Pressure of Plutonium,”High Temp. Sci., 1, 169–175 (1969). (Equi Diagram; Experimental)

    Google Scholar 

  • 69Ken2: R.A. Kent and J.A. Leary, “Mass Spectrometric Studies of Plutonium Compounds at High Temperatures. IV. The Vaporization of PuN,”High Temp. Sci., 1 176–183 (1969). (Equi Diagram, Crys Structure, Thermo; Experimental)

    Google Scholar 

  • 69Ken3: R.A. Kent “Mass Spectrometric Studies of the Vaporization of Pu Compounds,” Quarterly Status Report on the Advanced Plutonium Fuels Program, April 1 to June 30, 1969, and Third Annual Report, FY 1969, USAEC, Los Alamos Sci. Lab., Rep. LA-4284-MS (1969). (Thermo; Experimental)

  • 69Rap: G. Raphael and C. de Novion, “Magnetic Susceptibilities of the Mononitrides and Sesquicarbides of Thorium, Uranium, and Plutonium,”Solid State Commun., 7, 791–793 (1969) in French. (Equi Diagram; Experimental)

    Article  ADS  Google Scholar 

  • 69Shu: M.W.Shupe, R.L. Nance, and D. Kelley, “Nitrides,” Quarterly Status Report on the Advanced Plutonium Fuels Program, April 1 to June 30, 1969, and Third Annual Report, FY 1969, USAEC, Los Alamos Sci. Lab., Rep. LA-4284-MS (1969). (Crys Structure; Experimental)

  • 70Ale1: C.A. Alexander, J.S. Ogden, W.M. Pardue, “Thermodynamics and Transport Characteristics of PuN and Alloys of UN-PuN,” Progress on Development of Materials and Technology for Advanced Reactors during October through December 1969, D.L. Keller, Ed., USAEC, Battelle Memorial Inst., Rep. BMI-1878 (1970). (Equi Diagram, Thermo; Experimental)

  • 70Ale2: C.A. Alexander, J.S.Ogden, and W.M.Pardue, “Thermodynamics and Transport Characteristics of PuN and Alloys of UN-PuN,” Progress on Development of Fuels and Technology for Advanced Reactors during July through September 1970 Progress Report, D.L. Keller, Ed., USAEC, Battelle Memorial Inst., Rep. BMI-1893 (1970). (Equi Diagram; Experimental)

  • 70Gol: A. Goldberg and T.B.Massalski, “Phase Transformations in the Actinides,” USAEC, Lawrence Radiation Lab., Rep. UCRL-72557 (1970). (Equi Diagram; Review)

  • 70Lee: J.A. Lee, K. Mendelssohn, and P.W. Sutcliffe, “Specific Heats of Plutonium and Neptunium,”Proc. R. Soc. (London), A, 317, 303–317 (1970). (Equi Diagram; Experimental)

    ADS  Google Scholar 

  • 70Mar: J.P. Marcon and J. Poitreau, “Vaporization of Plutonium Mononitride,”J. Inorg. Nucl. Chem., 32, 463–467 (1970) in French. (Equi Diagram, Thermo; Experimental)

    Article  Google Scholar 

  • 71Ten: V.J. Tennery and E.S. Bomar, “Lattice Parameters of (U, Pu)N Solid Solutions,”J. Am. Ceram. Soc., 54(5), 247–249 (1971). (Crys Structure; Experimental)

    Article  Google Scholar 

  • 72Fra: M. de Franco and J.-P. Marcon, “Study of the Reduction of Plutonium Mononitride by Carbon by Means of Measurements of Nitrogen Pressure,”Rev. Chim. Miner., 9, 437–448 (1972) in French. (Thermo; Experimental)

    Google Scholar 

  • 72Sut: P.W.Sutcliffe, “Low Temperature Properties of Transuranic Metals,” United Kingdom At. Energy Auth., Harwell, Rep. AERE-R7172. (Equi Diagram; Experimental)

  • 73Jac: J. Jacquemin, “Length Change in Plutonium and Several Compounds by Self-Irradiation at 4.2 °K,” Comm. Energ. Atomique, Cent. Etude Nucl. Fontenay-aux-Roses, France, Rep. CEA-R-4386 (1973) in French. (Equi Diagram; Experimental)

  • 73Pot: P.E. Potter, “Some Equilibria in the Uranium Plutonium-Nitrogen Ternary System. An Assessment,”J. Nucl. Mater., 47, 7–16 (1973). (Meta Phases; Theory)

    Article  ADS  Google Scholar 

  • 75Hol: H. Holleck, “Ternary Phase Equilibria in the Systems Actinide-Transition Metal-Carbon and Actinide-Transition Metal-Nitrogen,”Themodynamics of Nuclear Materials 1974, Vol. 2, IAEA, Vienna, 213–263 (1975). (Equi Diagram; Review)

    Google Scholar 

  • 75She: A. Sheth and L. Leibowitz, “Equation of State and Transport Properties of Uranium and Plutonium Nitrides in the Liquid Region,” U.S. Energy Res. Dev. Admin. Argonne Nat. Lab., Rep. ANL-AFP-12 (1975). (Equi Diagram, Thermo; Theory)

  • 76Ale: C.A. Alexander, R.B. Clark, O.L. Kruger and J. L. Robbins, “Fabrication and High-Temperature Thermodynamic and Transport Properties of PuN,”Plutonium 1975 and Other Actinides, H. Blank and R. Lindner, Ed., North-Holland, Amsterdam, 277–286 (1976). (Thermo; Experimental)

    Google Scholar 

  • 76Gor: J.E. Gordon, R.O.A. Hall, J.A. Lee, and M.J. Mortimer, “Heat Capacities of Plutonium and Neptunium,”Proc. R. Soc. (London) A, 351, 179–196 (1976). (Equi Diagram; Experimental)

    Article  ADS  Google Scholar 

  • 76Pot:, P.E. Potter, “Some Phase Relationships and Equilibria for the Uranium-Plutonium Monocarbonitrides Including the Effects of Oxygen on Some Equilibria,”Plutonium 1975 and Other Actinides, H. Blank and R. Lindner, Ed., North-Holland, Amsterdam, 211–232 (1976). (Equi Diagram, Thermo; Review)

    Google Scholar 

  • 78Gre: D.W. Green and G.T. Reedy, “Infrared Spectra of Matrix-Isolated Plutonium Nitrides,”,J. Chem. Phys., 69(2), 552–555 (1978). (Metal Phases; Experimental)

    Article  ADS  Google Scholar 

  • 78Hal: R.O.A. Hall, J.A. Lee, D.J. Martin, M.J. Mortimer, and P.W. Sutcliffe, “Heat Capacitiy of Plutonium Nitride at Low Temperatures,”J. Chem. Thermodyn., 10, 935–940, (1978). (Equi Diagram; Thermo; Experimental)

    Article  Google Scholar 

  • 78Oet: F.L. Oetting, “The Chemical Thermodynamic Properties of Nuclear Materials, III. Plutonium Mononitride,”J. Chem. Thermodyn., 10 941–948 (1978). (Equi Diagram, Thermo; Experimental)

    Article  Google Scholar 

  • 80Pot: P.E. Potter and K.E. Spear, “Advanced Fuels for Fast Breeder Reactors: A Critical Assessment of Some Phase Equilibria,” Thermodynamics of Nuclear Materials, 1979, Vol. 2, IAEA, Vienna, 195–226 (1980) (Equi Diagram, Thermo; Review)

    Google Scholar 

  • 82Mur: T., Muromura, “Effect of Oxygen and Carbon Impurities on Lattice Parameter of PuN,”J. Nucl. Sci. Technol., 19(10), 852–854 (1982). (Crys Structure; Experimental)

    Google Scholar 

  • 84Boe: A. Boeuf, R. Caciuffo, J.M. Fournier, L. Manes J. Rebizant, E. Roudaut, and F. Rustichelli, “239PnN Powder Neutron Diffraction Study”,Sol. State Commun. 52(4), 451–453 (1984). (Crys Structure; Experimental)

    Article  ADS  Google Scholar 

  • 84Pan: L.B. Pankratz, J.M. Stuve, and N.A. Gokcen, “Thermodynamic Data for Mineral Technology,” Bull. 677, U.S. Bur. of Mines (1984). (Thermo; Compilation)

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The work was supported by ASM INTERNATIONAL. Part of the literature search was provided by ASM INTERNATIONAL. Literature searched through 1985. Dr. Wriedt is the ASM/NIST Data Program Category Editor for binary nitrogen alloys.

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Wrledt, H.A. The N−Pu (Nitrogen-Plutonium) system. Bulletin of Alloy Phase Diagrams 10, 593–602 (1989). https://doi.org/10.1007/BF02882419

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