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The Au-Zn (Gold-Zinc) system

  • Alloy Diagram Evaluations
  • Au-Zn
  • Published:
Bulletin of Alloy Phase Diagrams

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Cited References

  • 1897Hey: C.T. Heycock and F.H. Neville, “The Freezing Point of Alloys Containing Zinc and Another Metal,”J. Chem. Soc., 71, 383–422 (1897). (Equi Diagram; Experimental; Indicates the presence of a phase diagram)

    Google Scholar 

  • 06Pus: N.A. Puschin, “Potential and Nature of Metallic Alloys,”Zh. Russ. Fiz.-Khim. Obschchestaba, 39, 353–399 (1906) in Russian; TR:Z. Anorg. Chem., 56, 1–45 (1908) in German. (Equi Diagram; Experimental)

    Google Scholar 

  • Indicates key paper 06Vog R. Vogel, “Gold-Zinc Alloys,”Z. Anorg. Chem., 48, 319–332 (1906) in German. (Equi Diagram; Experimental; Indicates the presence of a phase diagram)

    Article  Google Scholar 

  • 19Tam: G. Tammann, “The Chemical and Galvanic Properties of Alloy States and Their Atomic Configurations,”Z. Anorg. Chem., 107, 158 (1919) in German. (Equi Diagram; Experimental)

    Google Scholar 

  • Indicates key paper 23Sol: P. Soldau, “Equilibrium in the System Gold-Zinc,”J. Inst. Met., 30, 351–400 (1923). (Equi Diagram; Experimental; Indicates the presence of a phase diagram)

    Google Scholar 

  • 25Pie: W.M. Pierce, E.A. Anderson, and P. van Dyck, “An Investigation of the Alleged Allotropy of Zinc by X-Ray Analysis and a Redetermination of the Zinc Lattice,”J. Franklin Inst., 200(3), 349–361 (1925). (Equi Diagram; Experimental)

    Article  Google Scholar 

  • 25Sol: P. Soldau, “Equilibrium in the System Gold-Zinc,”Z. Anorg. Chem., 141, 325–362 (1925) in German. (Equi Diagram; Experimental)

    Google Scholar 

  • Indicates key paper 25Wes: A. Westgren and G. Phragmen, “X-Ray Analysis of Copper-Zinc, Silver-Zinc and Gold-Zinc Alloys,”Philos. Mag., 50, 311–341 (1925). (Equi Diagram, Crys Structure; Experimental; Indicates the presence of a phase diagram)

    Google Scholar 

  • 26Bra: A.J. Bradley and J. Thewlis, “The Structure of γ-Brass,”Proc. R. Soc. (London), A, 112, 678–692 (1926). (Equi Diagram; Experimental)

    Article  ADS  Google Scholar 

  • 260Owe: E.A. Owen and G.D. Preston, “The Atomic Structure of AuMg and AuZn,”Philos. Mag., 2, 1266–1270 (1926). (Crys Structure; Experimental)

    Google Scholar 

  • 31Bra: A.J. Bradley and C.H. Gregory, “A Comparison of the Crystal Structures of Cu5Zn8 and Cu5Cd8,”Philos. Mag., 12, 143–162 (1931). (Equi Diagram; Experimental)

    Google Scholar 

  • 34Bil: W. Biltz, G. Rohltts, and H. von Vogel, “Systematic Doctrine of Affinity. LXI. Construction and Use of a High-Temperature Calorimeter with a Closed Reaction Chamber,”Z. Anorg. Chem., 220, 113–141 (1934) in German. (Thermo; Experimental)

    Article  Google Scholar 

  • 34Owe: E.A. Owen and E.L. Yates, “The Thermal Expansion of the Crystal Lattices of Silver, Platinum, and Zinc,”Philos. Mag., 17(110), 113–131 (1934). (Crys Structure; Experimental)

    Google Scholar 

  • 38Owe: E.A. Owen and I.G. Edmunds, “An X-Ray Study of the Superlattice in Certain Alloys,”Proc. Phys. Soc, (London), 50(3), 389–397 (1938). (Crys Structure; Experimental)

    Article  ADS  Google Scholar 

  • 40Age: N.V. Ageev and D.N. Shoykhet, “Structure of β Phase of Au−Zn Alloys,”Izv. Sekt. Fiz.-Khim. Anal., 13, 165–170 (1940) in Russian. (Equi Diagram, Crys Structure; Experimental; Indicates the presence of a phase diagram)

    Google Scholar 

  • 40Kos: W. Koster, “Modulus of Elasticity and Internal Friction of the Intermediary Phases in the Systems Copper-, Silver-, Gold-Zinc and Silver-Cadmium,”Z. Metallkd., 32(6), 151–156 (1940) in German. (Equi Diagram, Crys Structure; Experimental)

    Google Scholar 

  • 42Sch: A. Schneider and H. Schmid, “Metal Vapor Pressures. III. The Vapor Pressures of Zn and Cd over their Binary Alloys with Cu, Ag and Au,” “Metal Vapor Pressures. IV. Theory of Liquid Alloys,”Z. Elektrochem., 48, 627–646 (1942) in German. (Thermo; Experimental)

    Google Scholar 

  • 43Kub: O. Kubaschewski, “Thermochemistry of Alloys. XI. Heats and Entropies of Fusion and Degree of Order of Au and Ag Alloys,”Z. Phys. Chem., 192, 292–308 (1943) in German. (Equi Diagram, Crys Structure, Thermo; Experimental)

    Google Scholar 

  • 45Owe: E.A. Owen and E.A.O. Roberts, “The Solubility of Certain Metals in Gold,”J. Inst. Met., 71, 213–254 (1945). (Crys Structure; Experimental)

    Google Scholar 

  • 49Rau: E. Raub, P. Walter, and A. Engel, “The Structures of the Au3Zn-Phase in Absence and in Presence of Copper, Silver and Cadmium,”Z. Metallkd., 40(11), 401–405 (1949) in German. (Crys Structure; Experimental)

    Google Scholar 

  • 52Hum: W. Hume-Rothery, J.O. Betterton, and J. Reynolds, “The Factors Affecting the Formation of 21/13 Electron Compounds in Alloys of Copper and of Silver,”J. Inst. Met., 80, 609–616 (1952). (Equi Diagram; Experimental)

    Google Scholar 

  • 54Sch: K. Schubert, B. Kiefer, and M. Wilkens, “Ordered Phases with Long Period in Alloys,”Z. Naturforsch., 9a(11), 987–988 (1954) in German. (Crys Structure; Experimental)

    Google Scholar 

  • 55Sch: K. Schubert, B. Kiefer, M. Wilkens, and R. Haufler, “On Some Metallic Ordered Phases with Long Period,”Z. Metallkd., 46(9), 692–715 (1955) in German. (Crys Structure; Experimental)

    Google Scholar 

  • 57Sch: K. Schubert, H. Breimer, W. Burkhardt, E. Gunzel, R. Haufler, H.L. Lukas, H. Vetter, J. Wegst, and M. Wilkens, “Some Structural Results of Metallic Phases II,”Naturwissenschaften, 44(7), 229–230 (1957) in German. (Crys Structure; Experimental)

    Article  ADS  Google Scholar 

  • Indicates key paper 57Wil: M. Wilkens and K. Schubert, “On Some Metallic Ordered Phases with Long Period,”Z. Metallkd., 48(10), 550–557 (1957) in German. (Equi Diagram, Crys Structure; Experimental; Indicates the presence of a phase diagram)

    Google Scholar 

  • 58Gun: E. Gunzel and K. Schubert, “Crystal Structure of AuZn3(r),”Z. Metallkd., 49(5), 234–235 (1958) in German. (Crys Structure; Experimental)

    Google Scholar 

  • 58Mas: D.B. Masson and C.S. Barrett, “Effect of Deformation and Low Temperatures on the Structures of AgCd and AuZn,”Trans. AIME, 212(4), 260–265 (1958). (Equi Diagram; Experimental)

    Google Scholar 

  • 58Ter: J. Terpilowski,Zeszyty Nauk. Politech. Wroclaw., Chem., (4), 13–23 (1958); TR: Tech. Rep., Nat. Res. Council, Can., NRC-TT-1372, 13p, (1969). (Crys Structure, Thermo; Experimental)

    Google Scholar 

  • Indicates key paper 58Wil: M. Wilkens and K. Schubert, “On the Crystal Structure of Au3Zn(r), Au3Zn5 and Some Variants,”Z. Metallkd., 49(12), 633–646 (1958) in German. (Equi Diagram, Crys Structure; Experimental; Indicates the presence of a phase diagram)

    Google Scholar 

  • 59Car: R.W. Carpenter, R.L. Orr, and R. Hultgren, U.S. Dept. Commerce, Office Tech. Serv., PB Rept., 144, 478, 1499 (1959) as cited in [Elliott]. (Crys Structure; Experimental)

    Google Scholar 

  • 59Fei: E. Feingold, “Phase Transitions, Crystal Structures and Order-Disorder in the Alloy Au3Zn,” diss., Temple University (1959);Diss. Abstr., 20, 3349 (1960). (Equi Diagram, Crys Structure; Experimental)

  • 59Iwa: H. Iwasaki, “On the Structure of the Ordered Alloys Au3Zn[R],”J. Phys. Soc. Jpn., 14(10), 1456 (1959). (Equi Diagram, Crys Structure; Experimental)

    Article  ADS  Google Scholar 

  • 60Iwa: H. Iwasaki, M. Hirabayashi, K. Fujiwara, D. Watanabe, and S. Ogawa, “Study on the Ordered Phases with Long Period in the Gold-Zinc Alloy System,”J. Phys. Soc. Jpn., 15(10), 1771–1783 (1960). (Equi Diagram, Crys Structure, Thermo; Experimental; Indicates the presence of a phase diagram)

    Article  ADS  Google Scholar 

  • 62Iwa: H. Iwasaki, “Study on the Ordered Phases with Long Period in the Gold-Zinc Alloy System II. Structure Analysis of Au3Zn|R1|.Au3Zn|R2| and Au3+Zn, “J. Phys. Soc. Jpn., 17(10), 1620–1633 (1962); Errata,J. Phys. Soc. Jpn., 17(12), 1906 (1962). (Crys Structure; Experimental)

    Article  ADS  Google Scholar 

  • 62Mas: T.B. Massalski and H.W. King, “The Lattice Spacing Relationships in H.C.P.ε and Ψ Phases in the Systems Cu−Zn, Ag−Zn, Au−Zn and Ag−Cd,”Acta Metall., 10(12) 1171–1181 (1962). (Equi Diagram, Crys Structure; Experimental; Indicates the presence of a phase diagram)

    Article  Google Scholar 

  • 64Dav: D.A. Davies and E.A. Owen, “An X-Ray Investigation on the Solid Solution of Certain Elements in Zinc,”Brit. J. Appl. Phys., 15, 1309–1314 (1964). (Crys Structure; Experimental)

    Article  ADS  Google Scholar 

  • 64Jan: J.P. Jan and W.B. Pearson, “Martensitic Transformation in Ordered β′-AuZn,”Can. J. Phys., 42(1), 220 (1964). (Equi Diagram, Meta Phases; Experimental)

    Google Scholar 

  • 65Bal: A. Ball and R.E. Smallman, “A Note on the Martensitic Transformation in Thin Foils of AuZn,”Acta Metall., 13(9), 1011–1012 (1965). (Equi Diagram, Meta Phases; Experimental)

    Article  Google Scholar 

  • 65Iwa: H. Iwasaki, “The Crystal Structure and the Phase Transition of a Metastable Phase in the Au-37.8% Zn Alloy,”J. Phys. Soc. Jpn., 20(12), 2129–2140 (1965). (Equi Diagram, Meta Phases; Experimental)

    Article  ADS  Google Scholar 

  • Indicates key paper 65Pop: H. Pops and T.B. Massalski, “Transformation of β′-Phase Au−Zn Alloys at Low Temperatures,”Trans. AIME, 233, 728–730 (1965). (Equi Diagram, Meta Phases; Experimental)

    Google Scholar 

  • 66Oga: S. Ogawa and H. Iwasaki, “Study of Long Period Ordered Alloys by X-Ray Diffraction,”Sci. Rep. Res. Inst. Tohoku Univ., Ser. A, 18, Suppl., 194–206 (1966). (Equi Diagram; Experimental)

    Google Scholar 

  • 67Car: R.W. Carpenter, R.L. Orr, and R. Hultgren, “Heats of Formation of Au3Zn and AuZn,”Trans. AIME, 239(1), 107–109 (1967). (Crys Structure, Thermo; Experimental)

    Google Scholar 

  • 67Mac: R.B. Maciolek, J.A. Mullendore, and R.A. Dodd, “Vacancy-Defective Intermediate Phases,”Acta Metall., 15, 259–264 (1967). (Equi Diagram, Experimental)

    Article  Google Scholar 

  • Indicates key paper 68Iwa: H. Iwasaki and T. Uesugi, “X-Ray Measurement of Order in the Beta-Prime Phases of Noble Metal Alloys. I. β′ AuZn,”J. Phys. Soc. Jpn., 25(6), 1640–1646 (1968). (Crys Structure, Experimental)

    Article  ADS  Google Scholar 

  • 68Sac: G.A. Sacchetto, G.G. Bombi, and M. Fiorani, “Partial Molar Thermodynamic Quantities of Zinc in Liquid Zinc-Gold Alloys from emf Measurements,”Ber. Bunsenges Phys. Chem., 72(1), 80–84 (1968). (Thermo, Experimental)

    Google Scholar 

  • 70Bow: R.C. Bowe, L. Muldawer, and F. Chambers, “The Effect of Particle Size on the Martensitic Transformation of β′-AuZn (50%Zn),”Scr. Metall., 4(8), 581–582 (1970). (Equi Diagram; Experimental)

    Article  Google Scholar 

  • 70Kau: L. Kaufman and H. Bernstein,Computer Calculation of Phase Diagrams, Academic Press (1970). (Thermo; Theory)

  • Indicates key paper 70Yaz: A. Yazawa and A. Gubcova, “Thermodynamic Studies of Liquid Gold-Zinc and Silver-Zinc Systems,”Trans. Jpn. Inst. Met., 11(6), 419–423 (1970). (Equi Diagram, Thermo; Experimental; Indicates the presence of a phase diagram)

    Google Scholar 

  • 71Abd: M.A. Abdullin, A.A. Presnyakov, V.D. Melikhov, T.B. Begimov, and A.G. Malyavka, “Gold-Zinc System in the Region of γ-phases as a Function of Concentration,”Vestn. Akad. Nauk Kaz. SSR, 27(5), 43–49 (1971) in Russian. (Equi Diagram; Experimental)

    Google Scholar 

  • Indicates key paper 71Mas: D.B. Masson, “Thermodynamic Properties of Zinc in Alpha Au−Zn,”Metall. Trans., 2(3), 919–921 (1971). (Thermo; Experimental)

    Article  Google Scholar 

  • 71Pem: J.P. Pemsler and E.J. Rapperport, “Thermodynamic Properties of Solid Gold-Zinc Alloys by Atomic Absorption Spectroscopy,”Metall. Trans., 2(1), 79–84 (1971). (Equi Diagram, Thermo; Experimental; Indicates the presence of a phase diagram)

    Article  Google Scholar 

  • 71Pre: B. Predel and W. Schwermann, “AB 3 Superlattice Phases,”Z. Metallkd., 62(7), 517–524 (1971) in German. (Equi Diagram; Experimental)

    Google Scholar 

  • 72Ald: R. Alderdice and D.B. Downie, “Liquidus and Solidus Temperature of β′-Phase Au−Zn Alloys,”Scr. Metall., 6(9), 837–840 (1972). (Equi Diagram; Experimental; Indicates the presence of a phase diagram)

    Article  Google Scholar 

  • 73Ald: R. Alderdice, R.A. Connell and D.B. Downie, “Thermodynamic Properties of the Gold-Zinc System,”Acta Metall., 21(4), 485–488 (1973). (Equi Diagram, Thermo; Experimental)

    Article  Google Scholar 

  • 75Ana: R.P. Anantatmula, “Thermodynamic Properties of ε Phase Gold-Zinc Alloys,”Mater. Sci. Eng., 19(1), 123–127 (1975). (Thermo; Experimental)

    Article  Google Scholar 

  • 75Kou: S. Kou and Y.A. Chang, “Thermodynamics of the α-Gold-Zinc and β′-Gold-Zinc Phases,”Metall. Trans., 6(1), 39–44 (1975). (Thermo; Theory)

    Article  Google Scholar 

  • 76Kro: K. Krompholz and A. Weise, “X-Ray Study of the Quasibinary System AuZn−PdZn,”J. Less-Common Met., 50(2), 213–222 (1976). (Equi Diagram, Crys Structure; Experimental)

    Article  Google Scholar 

  • 77Ohs: K. Ohshima and D. Watanabe, “Electron Diffraction Study of Short-Range-Order Diffuse Scattering form Disordered Binary Alloys,”Acta Crystallogr. A, 33(5), 784–788 (1977). (Crys Structure; Experimental)

    Article  Google Scholar 

  • 77Ten: G. van Tendeloo and S. Amelinckx, “Long-Period Antiphase Boundary Structures in the Ordered Alloy Gold-Zinc (Au4Zn). I. One-Dimensional Long-Period Antiphase Boundary Structure,”Phys. Status Solidi (a), 43(2), 553–564 (1977). (Crys Structure; Experimental)

    Article  Google Scholar 

  • 78Ten: G. Van Tendeloo and S. Amelinckx, “Long-Period Antiphase Boundary Structures in the Ordered Alloy Gold-Zinc (Au4Zn). II. Growth Mechanism of theLPAPB Structure,”Phys. Status Solidi (a), 50(1), 53–66 (1978). (Crys Structure; Experimental)

    Article  Google Scholar 

  • 79Iwa: H. Iwasaki and Y. Watanabe, “Structure of Periodic Antiphase Domain Boundaries in Long-Range Ordered Alloys,” AIP Conf. Proc.,Modulated Struct., 53, 247–249 (1979). (Crys Structure; Experimental)

    Google Scholar 

  • 79Mak: K. Makinen and J. Teuho, “Long-Period Domains in Gold Compound with Zinc (Au3Zn(R2)),”Phys. Scr., 19(1), 51–53 (1979). (Crys Structure; Experimental)

    Article  ADS  Google Scholar 

  • Indicates key paper 79Pea: W.B. Pearson, “The Gold-Zine Equilibrium Diagram in the Region 55–88 at.% Zinc,”J. Less-Common Met., 68(1), P9-P15 (1979). (Equi Diagram, Crys Structure; Experimental; Indicates presence of a phase diagram)

    Article  Google Scholar 

  • Indicates key paper 80Ger: U. Gerling and B. Predel, “Thermodynamic Properties of Liquid Gold-Zinc Alloys,”Z. Metallkd., 71(2), 79–84 (1980) in German. (Thermo; Experimental)

    Google Scholar 

  • 80Kam: K. Kameda, Y. Yoshida, and S. Sakairi, “Activities of Molten Gold-Zinc and Silver-Zinc Alloys by E.M.F. Measurements Using Zirconia Solid Electrolytes,”Nippon Kinzoku Gakkai-shi, 44(6), 671–677 (1980) in Japanese. (Thermo; Experimental)

    Google Scholar 

  • 82Teu: J. Teuho and K. Makinen, “On the Out-of-Step Period in Au3Zn(H),”Phys. Status Solidi (a), 70(1), K1-K3, (1982). (Crys Structure; Experimental)

    Article  Google Scholar 

  • 83Cha: M.W. Chase, “Heats of Transition of the Elements,”Bull. Alloy Phase Diagrams, 4(1), 123–124 (1983). (Thermo; Compilation)

    Google Scholar 

  • 83Teu: J. Teuho and K. Makinen, “A Study of Nonperiodic Antiphase Boundaries in Long-Period Ordered Au3Zn(H). I. Antiphase Boundary Planes,”Phys. Status Solidi (a), 77(1), 263–268 (1983). (Crys Structure; Experimental)

    Article  Google Scholar 

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Work was supported by the International Gold Corporation Limited and ASM INTERNATIONAL. Literature searched through 1983. Part of the bibliographic search was provided by ASM. Professor T.B. Massalski is ASM/NIST Data Program Editor-in-Chief for the binary alloys, and also Category Editor for binary gold alloys, jointly with Dr. H. Okamoto.

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Okamoto, H., Massalski, T.B. The Au-Zn (Gold-Zinc) system. Bulletin of Alloy Phase Diagrams 10, 59–69 (1989). https://doi.org/10.1007/BF02882177

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