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Additional References
K.H.J. Buschow and J.H.N. van Vucht, Systematic Arrangement of the Binary Rare-Earth-Aluminium Systems,Philips Res. Rept., 22, p 233–245 (1967). (A detailed X-ray investigation of Al2La did not reveal any significant homogeneity range)
M.E. Drits, E.S. Kadaner and N.D. Shoa, Solid Solubility of Rare Earth Metals in Aluminium,Izv. Akad. Nauk SSSR Met., 1, p 219 (1969). in Russian; translated asRuss. Met., 1, p 113–117 (1969). (Maximum solubility of La in Al extrapolated to 0.01 at.% La at the eutectic temperature 640°C) See Fig. 2.
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V.I. Kober, I.F. Nichkov, S.P. Raspopin and V.A. Nauman, Phase Composition and Thermodynamic Properties of Lanthanum-Aluminum Alloys,Izv. Vyssh. Uchebn. Zaved. Tsvetn. Metall., No. 5, p 83–86 (1997) in Russian; translated asSov. Non-Ferrous Met. Res., 5(5), p 184–186 (1977). (An emf study showed formation of AlLa3, AlLa, Al2La, Al3La and Al4La—the last probably being the Al11La3 shown in Fig. 1. In contrast to Fig. 1, AlLa3 was observed at 603°C. The activity of Al showed large negative deviation from Raoult’s law)
V.I. Kononenko, V.G. Shevchenko and A.L. Sukhman, Thermodynamics of the Interaction Between Aluminium and Lanthanum in the Liquid Phase,Izv. Akad. Nauk SSSR Met., No. 1, p 67–68 (1978) in Russian; translated asRuss. Met., No. 1, p 59–60 (1978). (Enthalpies, free energies, and entropies of mixing for entire composition range were determined at 1573 and 1693 K)
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Work done at IIT Research Institute, Chicago, Illinois, under contract to the Office of Standard Reference Data, National Bureau of Standards. From [Elliott; IITRI]; bibliography through 1968.
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Elliott, R.P., Shunk, F.A. The Al−La (Aluminum-Lanthanum) system. Bulletin of Alloy Phase Diagrams 2, 219–221 (1981). https://doi.org/10.1007/BF02881485
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DOI: https://doi.org/10.1007/BF02881485