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Spectrophotometric study of the formation of adducts between U(TTA)4 and some neutral donors

  • Inorganic and Analytical
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Abstract

Adduct formation between U(TTA)4 and neutral donors triphenyl phosphine oxide (TPPO), tri-n-butyl phosphate (TBP) and methyl-isobutyl ketone (MIBK) in benzene was studied by absorption spectra. All the three donors form 1∶1 adduct with U(TTA)4. The adduct formation constants calculated from the spectral changes were 5·2×104, 1·1×103 and ∼0·8 for the adducts with TPPO, TBP and MIBK respectively. The adduct formation apparently increases the coordination number of U(IV) from 8, in the U(TTA)4 to 9 in the adduct formed.

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References

  • Alcock K, Grimley S S, Healy T V, Kennedy J and McKay H A C 1956Trans. Faraday Soc. 52 39

    Article  CAS  Google Scholar 

  • Baskin Y and Prasad N S K 1963J. Inorg. Nucl. Chem. 25 1011

    Article  CAS  Google Scholar 

  • Betts R H and Leigh R H 1950Can. J. Res. 828 514

    Google Scholar 

  • Day R A Jr., Wilhite R H and Hamilton F D 1955J. Am. Chem. Soc. 77 3180

    Article  CAS  Google Scholar 

  • Drew M G B 1977Coord. Chem. Rev. 24 179 (and references therein)

    Article  CAS  Google Scholar 

  • Ferraro J R and Healy T V 1962J. Inorg. Nucl. Chem. 24 1463

    Article  CAS  Google Scholar 

  • Graddon D P and Watton C C 1961J. Inorg. Nucl. Chem. 21 49

    Article  CAS  Google Scholar 

  • Healy T V 1961J. Inorg. Nucl. Chem. 19 314, 328

    Article  CAS  Google Scholar 

  • Healy T V 1969 inSolvent extraction research, eds A S Kertes and Y Marcus (Wiley-Interscience) pp. 257

  • Irving H and Edgington D N 1960J. Inorg. Nucl. Chem. 15 150

    Article  Google Scholar 

  • Irving H and Edgington D N 1961aJ. Inorg. Nucl. Chem. 20 314, 321

    Article  CAS  Google Scholar 

  • Irving H and Edgington D N 1961bJ. Inorg. Nucl. Chem. 21 169

    Article  Google Scholar 

  • Leipoldt J G, Wessels G F S and Bok L D C 1975J. Inorg. Nucl. Chem. 37 2487

    Article  CAS  Google Scholar 

  • Lippard S J 1967 inProgress in inorganic chemistry ed. F A Cotton8 109 (and references therein)

  • Marcus Y and Kertes A S 1969Ion exchange and solvent extraction metal complexes (Wiley-Interscience) pp. 815 (and references therein)

  • Ramakrishna V V, Patil S K and Hara Prakas B 1979aSep. Sci. Tech. 14 571

    Article  CAS  Google Scholar 

  • Ramakrishna V V, Patil S K and Ramanujam A 1979bJ. Inorg. Nucl. Chem. (accepted)

  • Ramanujam A, Ramakrishna V V and Patil S R 1979Sep. Sci. Tech. 14 13

    Article  CAS  Google Scholar 

  • Ramanujam A, Nadkarni M N, Ramakrishna V V and Patil S K 1978J. Radioanal. Chem. 42 349

    Article  CAS  Google Scholar 

  • Selbin J and Ortego J D 1967J. Inorg. Nucl. Chem. 29 1449

    Article  CAS  Google Scholar 

Download references

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Authors and Affiliations

  1. Radiochemistry Division, Bhabha Atomic Research Centre, 400 085, Bombay

    S K Patil, V V Ramakrishna & A Ramanujam

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  1. S K Patil
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  2. V V Ramakrishna
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  3. A Ramanujam
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Patil, S.K., Ramakrishna, V.V. & Ramanujam, A. Spectrophotometric study of the formation of adducts between U(TTA)4 and some neutral donors. Proc. Indian Acad. Sci. (Chem. Sci.) 88, 303–312 (1979). https://doi.org/10.1007/BF02880938

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  • DOI: https://doi.org/10.1007/BF02880938

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