Abstract
Equimolar and bimolar reactions of zirconium isopropoxide with bibasic tridentate azomethine (AZH2) having the donor system ONO have been carried out and derivatives of the type Zr(OPr1)2(AZ) and Zr(AZ)2 [Where AZ2− is the anion of the azomethine molecule] have been isolated. The labile nature of the isopropoxy groups in 1∶1 derivatives has been shown by carrying out exchange reactions with equimolar amount of 2-methylpentane-2,4-diol. All the newly synthesized derivatives have been characterized on the basis of elemental analysis, conductance measurements, molecular weight determinations and infrared, ultraviolet, visible and proton magnetic resonance spectral studies.
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Sharma, R.K., Singh, R.V. & Tandon, J.P. Spectral studies of the newly synthesized azomethine derivatives of zirconium(IV). Proc. Indian Acad. Sci. (Chem. Sci.) 90, 461–465 (1981). https://doi.org/10.1007/BF02880859
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DOI: https://doi.org/10.1007/BF02880859