Abstract
Complexes of Co(III) with 2-hydroxyacetophenone-thiosemicarbazone, 2-hydroxy-3-methylacetophenonethiosemicarbazone and 2-hydroxy-4-methyl-acetophenonethiosemicarbazone, and the addition complexes of 2-hydroxy-acetophenone thiosemicarbazone with ammonia, pyridine, aniline,o-toluidine,m-toluidine andp-toluidine have been synthesized and characterized on the basis of their conductivities, electronic and infrared spectral data. All complexes are low-spin octahedral in nature. Various parameters have been obtained using ligand field theory.
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References
Ballhausen C J and Maffitt W 1956J. Inorg. Nucl. Chem. 3 178
Batley G E and Gradon D P 1968Aust. J. Chem. 21 267
Campbell M J M and Grazeskowiak R 1967J. Chem. Soc. A396
Geary W J 1971Coord. Chem. Rev. 7 172
Legg J I and Cooke D W 1965Inorg. Chem. 4 1576
Legg J I and Cooke D W 1966Inorg. Chem. 5 594
Lever A B P 1968Inorganic electronic spectroscopy (London: Elsevier)
Patel M N and Patel R P 1971J. Indian Chem. Soc. 48 521, 1123
Patil M S and Shah J R 1980Proc. Indian Acad. Sci. (Chem. Sci.) 89 387
Patil M S and Shah J R 1981Proc. Indian Acad. Sci. 90 147
Vogel A I 1956Text-book of practical organic chemistry (London: Green and Co.) p. 344
Wentworth R A and Piper T S 1965Inorg. Chem. 4 709
Wiles D M and Suprunchuk T 1969Can. J. Chem. 47 1087
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Patil, M.S., Shah, J.R. Synthesis and physicochemical studies on Co(III) complexes. Proc. Indian Acad. Sci. (Chem. Sci.) 90, 427–431 (1981). https://doi.org/10.1007/BF02880855
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DOI: https://doi.org/10.1007/BF02880855