Abstract
Thermal analysis of hydrazinium metal sulphates, (N2H5)2 M(SO4)-I, and their hydrazinates, (N2H5)2−M(SO4)23N2H4−II, whereM=Fe, Co and Ni have been investigated using thermogravimetry and differential thermal analysis. Type II compounds on heating decompose through an intermediate I and metal suphlate to the respective metal oxides.
Similar content being viewed by others
References
Bristoti A, Kunrath J I, Viccara P J and Bergter L 1975J. Inorg. Nucl. Chem. 37 1149
Cheng C, Wong H and Reiff W M 1977Inorg. Chem. 16 819
Drago R S 1971Physical methods in inorganic chemistry (East-West Edition) p. 370
Duncan J F and Wigley P W R 1963J. Chem. Soc. part I 1120
Frank E, Varriale M C and Bristoti A 1979J. Thermal Anal. 17 141
Klaaijsen, Den Adel H, Dokoupil Z and Huiskamp W J 1975Physics B (Amsterdam) 79 B+C 113
Kohler K and Franke W 1961Fortschr. Minerales 39 75; C.A. 55 21941h
Nieuwpoort A and Reedijk J 1973Inorg. Chim. Acta 7 323
Patil K C, Soundararajan R and Pai Verneker V R 1978Proc. Indian Acad. Sci. A87 281
Patil K C, Soundararajan R and Pai Verneker V R 1979Proc. Indian Acad. Sci. A 88 211
Reiff W M, Wong H, Frankel R B and Foner S 1977Inorg. Chem. 16 1039
Swamy M S R, Prasad T P and Sant B R 1973J. Thermal Anal. 23 711
Witteveen H T and Reedijk J 1973Solid State Commun.12 1121
Witteveen H T and Reedijk J 1974J. Solid State Chem 10 151
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Patil, K.C., Govindarajan, S., Soundararajan, R. et al. Thermal analysis of hydrazinium metal sulphates and their hydrazinates. Proc. Indian Acad. Sci. (Chem. Sci.) 90, 421–426 (1981). https://doi.org/10.1007/BF02880854
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF02880854