Skip to main content
SpringerLink
Log in

The As−Ge (Arsenic-Germanium) system

  • As−Ge
  • Published:
Bulletin of Alloy Phase Diagrams

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Cited References

  • 40Sto: H. Stöhr and W. Klemm, “Binary Systems Based on Germanium. II.,”Z. Anorg. Chem., 244, 205–223 (1940) in German. (Equi Diagram; Experimental; Indicates presence of a phase diagram)

    Article  Google Scholar 

  • 53Bur: J. A. Burton, E. D. Kolb, W. P. Slichter, and J. D. Struthers, “Distribution of Solute in Crystals Grown from the Melt. Part II,”J. Chem. Phys., 21, 1991–1996 (1953). (Equi Diagram; Experimental)

    Article  ADS  Google Scholar 

  • 53Hal: R. N. Hall, “Segregation of Impurities During the Growth of Germanium and Silicon Crystals,”J. Phys. Chem., 57, 836–839 (1953). (Equi Diagram; Experimental)

    Article  Google Scholar 

  • 53Thu: C. D. Thurmond, “Equilibrium Thermochemistry of Solid and Liquid Alloys of Germanium and of Silicon. I.,”J. Phys. Chem., 57, 827–830 (1953). (Thermo; Theory)

    Article  Google Scholar 

  • 54Bur: J. A. Burton, “Impurity Centers in Ge and Si,”Phys., 20, 845–854 (1954). (Equi Diagram; Theory)

    ADS  Google Scholar 

  • 54Sch: K. Schubert, E. Dörre, and E. Günzel, “Crystal Structure Data on Phases of the B-Elements,”Naturwissenschaften, 41, 448 (1954) in German (Crys Structure; Experimental)

    Article  ADS  Google Scholar 

  • 55Jil: D. C. Jillson and A. C. Sheckler, “The Segregation Coefficient of As in Germanium as a Function of Crystal Growth Variables,”Phys. Rev., 98, 229 (1955). (Equi Diagram; Experimental)

    Google Scholar 

  • 56Bar: M.-J. Barbier-Andrieux, “On the Preparation of Alloys of Germanium with Silicon and Several Other Metalloids by Igneous Electrolysis,”C. R. Acad. Sc. Paris, 242, 2352–2354 (1956) in French. (Equi Diagram; Experimental)

    Google Scholar 

  • 56Thu: C. D. Thurmond, F. A. Trumbore, and M. Kowalchik, “Germanium Solidus Curves,”J. Chem. Phys., 25, 799–800 (1956). (Equi Diagram; Experimental)

    Article  ADS  Google Scholar 

  • 57Hal: R. N. Hall, “Variation of the Distribution Coefficient and Solid Solubility with Temperature,”J. Phys. Chem. Solids, 3, 63–73 (1957). (Equi Diagram; Theory)

    Article  ADS  Google Scholar 

  • 58Wei: K. Weiser, “Theoretical Calculation of Distribution Coefficients of Impurities in Germanium and Silicon, Heats of Solid Solution,”J. Phys. Chem. Solids, 7, 118–126 (1958). (Thermo; Theory)

    Article  ADS  Google Scholar 

  • 60Thu: C. D. Thurmond and M. Kowalchik, “Germanium and Silicon Liquidus Curves,”Bell Sys. Tech. J., 39, 169–204 (1960). (Equi Diagram, Thermo; Experimental)

    Google Scholar 

  • 60Tru: F. A. Trumbore, “Solid Solubilities of Impurity Elements in Germanium and Silicon,”Bell Sys. Tech. J., 39, 205–233 (1960). (Equi Diagram; Experimental)

    Google Scholar 

  • 61Spi: W. G. Spitzer, F. A. Trumbore, and R. A. Logan, “Properties of Heavily Doped n-Type Germanium,”J. Appl. Phys., 32, 1822–1830 (1961). (Equi Diagram; Experimental)

    Article  ADS  Google Scholar 

  • 62Bry: J. H. Bryden, “The Crystal Structures of the Germanium-Arsenic Compounds. I.,”Acta Crystallogr., 15, 167–171 (1962). (Crys Structure; Experimental)

    Article  Google Scholar 

  • Indicates key paper62Tru: F. A. Trumbore, W. G. Spitzer, R. A. Logan, and C. L. Luke, “Solid Solubilities of Antimony, Arsenic, and Bismuth in Germanium from a Saturation Diffusion Experiment,”J. Electrochem. Soc., 109, 734–738 (1962). (Equi Diagram; Experimental)

    Article  Google Scholar 

  • 67She: E. G. Sheychet and V. Ya. Shkot, “X-Ray Investigation of the Structure of Heavily Doped Germanium,”Izv. Akad. Nauk SSSR Neorg. Mat., 3, 1967–1971 (1967) in Russian. (Equi Diagram; Experimental)

    Google Scholar 

  • 67Wad: T. Wadsten, “The Crystal Structures of SiP2, SiAs2, and GeP,”Acta Chem. Scand., 21, 593–594 (1967). (Crys Structure; Experimental)

    Article  Google Scholar 

  • 68Ars: I. P. Arsenteva, S. S. Gorelik, Yu. M. Litvinov, and V. N. Rozhanski, “The Mechanism of Decomposition of the Supersaturated Solid Solution of Arsenic in Germanium,”Sov. Phys. Solid State, 9, 2448–2452 (1968). (Crys Structure; Experimental)

    Google Scholar 

  • 69Bub: V. T. Bublik, S. S. Gorelik, and A. N. Dubrovina, “Precision Measurements of Lattice Periods of Strongly Doped Germanium and Silicon,”Sov. Phys. Solid State, 10, 2247–2249 (1969). (Crys Structure; Experimental)

    Google Scholar 

  • Indicates key paper70Bar: A. D. Barsukov, P. M. Grinshtein, G. M. Kuznetsov, V. V. Olenin, and V. I. Fistul, “Lattice Parameters of Solid Solutions of Arsenic in Germanium,”Sov. Phys. Solid State, 12, 989–990 (1970). (Crys Structure; Experimental)

    Google Scholar 

  • Indicates key paper70Don: P. C. Donohue and H. S. Young, “Synthesis, Structure, and Superconductivity of New High Pressure Phases in the Systems Ge−P and Ge−As,”J. Solid State Chem., 1, 143–149 (1970). (Crys Structure, Pressure; Experimental)

    Article  ADS  Google Scholar 

  • 70Rao: M. V. Rao and W. A. Tiller, “Excess Free Energies in the Ge, Si and Ga Binary Systems—the α-Parameter Approach,”J. Phys. Chem. Solids, 31, 191–198 (1970). (Thermo; Theory)

    Article  ADS  Google Scholar 

  • 71Bla: R. Blachnik and A. Schneider, “High-Temperature Enthalpies of As2Te3, Sb2Se3, Bi2Se3, GeAs, GeAs2, and SnAs,”J. Chem. Thermodyn., 3, 227–233 (1971). (Thermo; Experimental)

    Article  Google Scholar 

  • 73Rib: C.G. Ribbing, I. Lindau, and W.E. Spicer, “Phase Separation in the Ge: As System Studied by X-Ray Photoemission,”Phys. Lett., 43A, 407–408 (1973). (Meta Phases; Experimental)

    ADS  Google Scholar 

  • 75Uga: Ya.A. Ugay, L.N. Meshchaninova, E.G. Goncharov, V. Z. Anokhin, and V. R. Pshestanchik, “TheP-T-X Phase Diagram of the Ge−As System,”Izv. Akad. Nauk SSSR Neorg. Mat., 11, 602–606 (1975) in Russian. (Equi Diagram, Thermo; Experimental; Indicates presence of a phase diagram)

    Google Scholar 

  • 77Gon: E.G. Goncharov, N.F. Gladyshev, and Ya.A. Ugai, “Physicochemical Nature of the Intermediate Phases in the Arsenic-Germanium System,”Russ. J. Inorg. Chem., 22, 1059–1061 (1977). (Equi Diagram; Experimental)

    Google Scholar 

  • Indicates key paper78Uga: Ya.A. Ugai, N.F. Gladyshev, and E.G. Goncharov, “Tensimetric Investigation of the As−Ge System,”Russ. J. Inorg. Chem., 23, 589–591 (1978). (Equi Diagram, Thermo; Experimental)

    Google Scholar 

  • 81Rat: V.V. Ratnikov, L.M. Sorokin, and G.N. Mosina, “Precision Measurements of the Ge−As Solid Solution Lattice Constant with Allowance for the Inhomogeneous Distribution of Arsenic,”Sov. Phys. Solid State, 23, 32–35 (1981). (Crys Structure; Experimental)

    Google Scholar 

  • 82Mor: A.N. Morozov, V.T. Bublik, and A.V. Zaitsev, “Proof of the Formation of Frenkel Pairs in the Initial Stage of Precipitation of a Solid Solution of Arsenic in Germanium,”Sov. Phys. Solid State, 24, 1229–1232 (1982). (Crys Structure; Experimental)

    Google Scholar 

  • 82Uga: Ya.A. Ugay, A.E. Popov, E.G. Goncharov, and V.A. Pakharukov, “Homogeneity Range of Germanium Arsenide,”Zh. Neorg. Khim., 27, 1783–1787 (1982) in Russian. (Equi Diagram; Experimental)

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Materials Science and Engineering, University of Florida, 32611, Gainesville, FL

    R. W. Olesinski & G. J. Abbaschian

Authors
  1. R. W. Olesinski
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. G. J. Abbaschian
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

This program was supported by ASM, under grant No. FG 101-1 to the University of Florida. Literature was searched through 1983. Professor Abbaschian is ASM/NBS Data Program Category Editor for binary germanium alloys.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Olesinski, R.W., Abbaschian, G.J. The As−Ge (Arsenic-Germanium) system. Bulletin of Alloy Phase Diagrams 6, 250–254 (1985). https://doi.org/10.1007/BF02880409

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02880409

Keywords

Search

Navigation