Abstract
Geochemical behavior of chemical elements is studied in a dolomitite weathering profile in upland of karst terrain in northern Guizhou. Two stages can be recognized during the process ofin situ weathering of dolomitite: the stage of sedentary accumulation of leaching residue of dolomitite and the stage of chemical weathering evolution of sedentary soil. Ni, Cr, Mo, W and Ti are the least mobile elements with reference to Al. The geochemical behavior of REE is similar to that observed in weathering of other types of rocks. Fractionation of REE is noticed during weathering, and the two layers of REE enrichments are thought to result from downward movement of the weathering front in response to changes in the environment. It is considered that the chemistry of the upper part of the profile, which was more intensively weathered, is representative of the mobile components of the upper curst at the time the dolomitite was formed, while the less weathered lower profile is chemically representative of the immobile constitution. Like glacial till and loess, the “insoluble” materials in carbonate rocks originating from chemical sedimentation may also provide valuable information about the average chemical composition of the upper continental crust.
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Nesbitt, H. W., Markovics, G., Weathering of granodioritic crust, long-term storage of elements in weatghering profiles and petrogenesis of siliciclastic sediments, Geochim. Cosmochim. Acta, 1997, 61(8): 1653.
Chen Yanjiang ed., New developing on sediment microelement tracer crust composition, environment and its evolution, Geology-Geochemistry (in Chinese), 1996, 223(3): 1.
Braun, J. J., Viers, J., Dupre, B. et al., Solid/liquid REE fractionation in the lateritic system of Goyoum, East Cameroon: The implication for the present dynamics of the soil covers of the humid tropical regions, Geochim. Cosmochim. Acta, 1998, 62(2): 273.
Chen Jun, Ji Junfeng, Qiu Gang, Geochemical study on the chemical weathering degree of loess, Luochu, Shanxi, Science in China (in Chinese), Ser. D, 1997, 27(6): 531.
Morey, G. B., Setterholm, D. R., Rare earth elements in weathering profiles and sediments of Minnesota: Implications for provenance studies, Journal of Sedimentary Research, 1997, 67(1): 105.
Banfield, J. F., Eogleton, R. A., Apatite replacement and rare earth mobilization fractionation, and fixation during weathering, Clays and Clay Minerals, 1989, 37(2): 113.
Wang Zhonggan, Yu Xueyuan, Zhao Zhenhua et al., eds., Rare Earth Element Geochemistry (in Chinese), Beijing: Science Press, 1989, 321–342.
Wang Shijie, Ji Hongbing, Ouyang Ziyuan et al., Preliminary study on weathering pedogenesis of carbonate rock, Science in China, Ser. D, 1999, supplement.
Martini, I. P., Chesworth, W., eds., Weathering, Soils & Palaeosols, Amsterdam: Elsevier Science Publishers, 1992, 127–181.
Nesbitt, H. W., Young, G. M., Early proterozoic climates and plate motions inferred from major element chemistry of lu-tites, Nature, 1982, 299: 715.
Nesbitt, H. W., Young, G. M., Formation and diagenesis of weathering profiles, The Journal of Geology, 1989, 97: 129.
Fedo, C. M., Nesbitt, H. W., Young, G. M., Unraveling the effects of potassium metasomatism in sedimentary rocks and paleosols with implications for paleoweathering condtions and provenance, Geology, 1995, 23: 921.
Young, G. M., Nesbitt, H. W., Processes controlling the distribution of Ti and Al in weathering profiles, siliciclastic sediments and sedimentary rocks, Journal of Sedimentary Research, 1998, 68(3): 448.
Maynard, J. B., Chemistry of modern soils as a guide to interpreting Precambrian paleosols, Journal of Geology, 1992, 100: 279.
Brimhall, G., Dietrich, W. E., Constitutive mass balance relations between chemical composition, volume, density, porosity, and strain in metasomatic hydrochemical systems: Results on weathering and pedogenesis, Geochim. Cosmochim. Acta, 1987, 51: 567.
White, A. F., Blum, A. E., Schulz, M. S. et al., Chemical weathering in a tropical watershed, Luquillo Mountains, Puert Rico: 1. Long-term versus short-term weathering fluxes, Geochim. Cosmochim. Acta, 1998, 62(2): 209.
Regional Geological Survey Team ed., Dictionary of Stratigraphic Terms of Guizhou (in Chinese), Guiyang: Guizhou Science and Technology Press, 1995, 12: 51–52.
White, A. F., Chemical weathering rates of silicate minerals in soils, in Chemical Weathering Rates of Silicate Minerals Rev. Mineral. ((eds. White, A. F., Brantly, S. L.), Vol. 31, 1995, 407–461.
Liu Yingjun, Cao Liming, Li Zhaolin, Element Geochemistry, Beijing: Science Press, 1984, 1–548.
Zhu, L. J., Lin, J. Y., The geochemical features and evolution of Laterite in the Karst areas of Guizhou Province, Chinese Journal of Geochemistry, 1996, 15(4): 1.
Middelburg, J. J., Weijden, C. V. D., Woittiez, J. R. W., Chemical processes affecting the mobility of major, minor and trace elements during weathering of granitic rocks, Chemical Geology, 1988, 68: 253.
Braun, J. J., Pagel, M., Muller, J. P. et al., Cerium anomalies in lateritic profiles, Geochim. Cosmochim. Acta, 1990, 54(2): 781.
Taylor, S. R., McLennan, S. M., McCulloch, M. T., Geochemistry of loess, continental crustal composition and crustal model ages, Geochim. Cosmochim. Acta, 1983, 47: 1897.
Taylor, S. R., McLennan, S. M., The Continental Crust: Its Composition and Evolution, Oxford: Blackwell Scientific Publications, 1985, 9–55.
Shaw, D. M., Cramer, J. J., Higgins, M. D. et al., Composition of the Canadian Precambrian Shield and the continental crust of the earth, in The Nature of Lower Continental Crust (eds. Dawson, J. B. et al.), Geol. Soc. Spec. Publ., 1986, 24: 275.
Condie, K. C., Chemical composition and evolution of the upper continental crust: Contrasting results from surface samples and shales, Chemical Geology, 1993, 104: 1.
Wedepohl, K. H., The composition of the continental crust, Geochim. Cosmochim. Acta, 1995, 59(7): 1217.
Gao, S., Luo, T. C., Zhang, B. R. et al., Chemical composition of the continental crust as revealed by studies in East China, Geochim. Cosmochim. Acta, 1998, 62(11): 1959.
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Ji, H., Ouyang, Z., Wang, S. et al. Element geochemistry of weathering profile of dolomitite and its implications for the average chemical composition of the upper-continental crust. Sci. China Ser. D-Earth Sci. 43, 23–35 (2000). https://doi.org/10.1007/BF02877828
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DOI: https://doi.org/10.1007/BF02877828