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The Au−Bi (Gold-Bismuth) system

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  • Au−Bi
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Journal of Phase Equilibria

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Cited References

  • 92Hey: C. T. Heycock, and F. H. Neville, J. Chem. Soc., 61, p 897 (1892).

    Google Scholar 

  • 94Hey: C. T. Heycock, and F. H. Neville, J. Chem. Soc., 65, p 65–76 (1894).

    Article  Google Scholar 

  • 95Roe: F. Roessler, Z. Anorg. Allg. Chem., 9, p 70–72 (1895).

    Google Scholar 

  • 06Vog: R. Vogel, Z. Anorg. Allg. Chem., 50, p 145–151 (1906).

    Article  Google Scholar 

  • 31Haa: W. J. de Haas, and F. Jurriaanse, Naturwissenschaften, 19, p 706 (1931).

    Article  ADS  Google Scholar 

  • 32Haa: W. J. de Haas and F. Jurriaanse Proc. Kon. Ned. Akad. Wetensch., 35, p 748–750 (1932).

    Google Scholar 

  • 35Jur: F. Jurriaanse, Z. Kristallogr., 90, p 322–329 (1935).

    Google Scholar 

  • 45Owe: E. A. Owen, and E. A. O'Donnell Roberts, J. Inst. Met., 71, p 213–254 (1945).

    Google Scholar 

  • 46Rau: E. Raub, and A. Engel, Z. Metallkunde, 37, p 76–81 (1946).

    Google Scholar 

  • 48Haj: O. Hajiček, Hutn. Listy, 3, p 265–270 (1948).

    Google Scholar 

  • 53Ale: N. E. Alekseevskii, G. G. Zhdanov, and N. N. Zhuravlev, Zh. Eksp. Teor. Fiz., 25, p 123–126 (1953); Chem. Abstr., 49, Abst. No. 5050 (1955).

    Google Scholar 

  • 62Nat: M. W. Nathans, and M. Leider, J. Phys. Chem., 66, p 2012–2015 (1962). (Note: The reader is cautioned that the values for the Au−Bi peritectic and eutectic as reported in the abstract are not the same as reported in Table III of [62Nat]. The Table III values were used in this evaluation)

    Article  Google Scholar 

Additional References

  • 51Kle: O. J. Kleppa, A Thermodynamic Study of Liquid Metallic Solutions. III. The Systems Bismuth-Gold and Thallium-Gold, J. Amer. Chem. Soc., 73, p 385–390 (1951). (emf measurements between 600 and 800°C for 21 to 95 at.% Bi)

    Article  Google Scholar 

  • 56Kle: O. J. Kleppa, The Thermodynamic Properties of the Moderately Dilute Liquid Solutions of Copper, Silver and Gold in Thallium, Lead and Bismuth, J. Phys. Chem., 60, p 446–452 (1956). (Liquid solution calorimetry. Δ H for liquid alloys with 68 to 99 at.% Bi, and for solid Au2Bi)

    Article  Google Scholar 

  • 68Fid: R. S. Fidler, J.A. Spittle, M. R. Taylor, and R. W. Smith, Structures of Bismuth-Silver, Bismuth-Gold, and Tin-Zinc Eutectics Solidification of Metals, published by Iron and Steel Institute, London, p 173–176 (1968). (The Bi−Au2Bi eutectic crystallized with the Au-rich phase, forming a broken lamellar morphology. No phase diagram data presented)

    Google Scholar 

  • 73Pre: B. Predel, and A. Emam, Contribution to the under-standing of Thermodynamic Properties of Some Liquid Binary Alloys of Copper, Silver and Gold with Bismuth and Antimony, Z. Metallkunde, 64, p 496–501 (1973). in German. (Thermodynamic activities and enthalpies of mixing were determined over the entire range of composition in liquid Au−Bi alloys at 1100°C)

    Google Scholar 

  • 75Gat: B. Gather, and R. Blachnik, Ternary Chalcogenide System. The Gold-Bismuth-Selenium System, Z. Metallkunde, 66, p 356–359 (1975), in German. (The phase diagram for the Au−Bi system was determined by X-ray, metallographic and DTA measurements, as shown in Fig. 2. The peritectic and eutectic points differ only slightly from the diagram proposed by [Elliott] in Fig. 1) See Fig. 2.

    Google Scholar 

  • 76Kam: K. Kameda and T. Azakami, Activities of Gallium and Bismuth in Liquid Gold Base Binary Alloy Systems, J. Jpn. Inst. Met., 40, p 1087–1092 (1976) in Japanese. (Activities, free energies of mixing, and heats of mixing were determined from emf measurements in the temperature range 670 to 850°C)

    Article  Google Scholar 

  • 79Pou: G. Pouillard, M.-C. Trinel-Dufour, Z. Derriche and P. Perrot, Reduction of Bi2O3 in Contact with a Gold Electrode in a Solid Electrolyte Cell. Activity of Au−Bi Alloys between 800 and 1100 K, Rev. Chim. Miner., 16(1), p 30–38 (1979) in French. (Activities of Au−Bi (20 to 52 at.% Bi) alloys were determined from emf measurements, as shown in the following table:

    Google Scholar 

  • 81Wal: P.C. Wallbrecht, R. Blachnik and K.C. Mills, The Heat Capacity and Enthalpy of Some Hume-Rothery Phases Formed by Copper, Silver and Gold. Part I. Cu+Sb, Ag+Sb, Au+Sb, Au+Bi Systems, Thermochimica Acta, 45, p 189–198 (1981). (Claims differential scanning calorimetry (DSC) measurements on a Au0.67Bi0.33 sample show that Au2Bi occurs at a composition with more than 67 at.% Au, but it is not indicated that the composition used was checked after preparation)

    Article  Google Scholar 

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Work done at IIT Research Institute, Chicago, Illinois, under contract to the Office of Standard Reference Data, National Bureau of Standards. From [Elliott; IITRI]; literature searched through 1968.

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Elliott, R.P., Shunk, F.A. The Au−Bi (Gold-Bismuth) system. Bulletin of Alloy Phase Diagrams 2, 479–481 (1982). https://doi.org/10.1007/BF02876169

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