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Synthesis, structure and ring-opening polymerization of macrocyclic arylates containing phthalic unit

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Abstract

A series of macrocyclic arylate dimers have been selectively synthesized by an interfacial polycondensation of o-phthaloyldichloride with bisphenols. A combination of GPC, FAB-MS,1H and13C NMR unambiguously confirmed the cyclic nature. Although single-crystal X-ray analysis of two such macrocycles reveals no severe strain on the cyclic structures, these macrocycles can undergo facile melt polymerization to give high molecular weight polyarylates.

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Authors and Affiliations

  1. Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 130022, Changchun, China

    Hongyan Jiang, Tianlu Chen, Yan Xing, Yonghua Lin & Jiping Xu

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  1. Hongyan Jiang
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  2. Tianlu Chen
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  3. Yan Xing
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  4. Yonghua Lin
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  5. Jiping Xu
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Project supported by the National Natural Science Foundation of China.

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Jiang, H., Chen, T., Xing, Y. et al. Synthesis, structure and ring-opening polymerization of macrocyclic arylates containing phthalic unit. Sc. China Ser. B-Chem. 40, 495–502 (1997). https://doi.org/10.1007/BF02875418

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  • DOI: https://doi.org/10.1007/BF02875418

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