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Copolymerization of 4′-vinylbenzo-15-crown-5 with Di(ethylene glycol) ethyl ether acrylate

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Abstract

Radical copolymerization behavior of 4′-vinylbenzo-15-crown-5, a vinyl monomer having apendant 15-membered crown ether unit (VCE) with di(ethylene glycol) ethyl ether acrylate (DEGEEA) was carried out in toluene solution using 2,2-azobisisobutyronitrile (AIBN) as an initiator. The copolymers were characterized by means of FT-IR,1H-NMR, and13C-NMR. The reactivity ratio of VCE and DEGEEA, determined by Fineman-Ross and Kelen-Tudos method, gave values 0.55 for VCE, and 0.11 for DEGEEA respectively.

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Authors and Affiliations

  1. Department of Textile Engineering, Inha University, Yonghyun-dong 253, Nam-ku, 402-751, Incheon, Korea

    Long Yi Jin & Soukil Mah

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  1. Long Yi Jin
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  2. Soukil Mah
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Correspondence to Soukil Mah.

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Jin, L.Y., Mah, S. Copolymerization of 4′-vinylbenzo-15-crown-5 with Di(ethylene glycol) ethyl ether acrylate. Fibers Polym 3, 49–54 (2002). https://doi.org/10.1007/BF02875399

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  • DOI: https://doi.org/10.1007/BF02875399

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