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Polymeric dyes based on thiadiazole derivatives

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Abstract

A series of polymeric dyes were synthesized by free radical addition polymerization of monomeric dyes. The 2-amino-5-mercapto-1,3,4-thiadiazole was diazotized and coupled with various N-arylmaleimides to give monomeric dyes. All the polymeric dyes were characterized by elemental analysis, infrared spectroscopy, visible absorption spectroscopy, viscometry, and thermogravimetric analysis. Color and dyeing properties of the polymeric dyes were discussed by comparing them with those of the corresponding monomeric dyes. The dyeing performance of these dyes was assessed on nylon fiber. These dyes were found to give various color shades with good to very good depth and levelness on the fiber. The dyeing of the monomeric dyes showed moderate fastness to light and good to excellent fastness to washing, perspiration and sublimation and their corresponding polymeric dyes showed excellent fastness properties. The dyebath exhaustion and fixation on nylon fiber has been found to be good.

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Authors and Affiliations

  1. V.P. and R.P.T.P. Science College, 388120, Vallabh Vidyanagar, Gujarat State, India

    Hari Raghav Maradiya & Vithal Soma Patel

  2. Department of Chemistry, Sardar Patel University, 388120, Vallabh Vidyanagar, Gujarat State, India

    Vithal Soma Patel

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  1. Hari Raghav Maradiya
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  2. Vithal Soma Patel
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Correspondence to Hari Raghav Maradiya.

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Maradiya, H.R., Patel, V.S. Polymeric dyes based on thiadiazole derivatives. Fibers Polym 2, 212–220 (2001). https://doi.org/10.1007/BF02875347

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  • DOI: https://doi.org/10.1007/BF02875347

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