Abstract
Electron diffraction and spectral data for hafnium and zirconium tetrakis(acetylacetonates) Hf(C5H7O2)4 and Zr(C5H7O2)4 are analyzed in terms of D2 symmetry of the geometrical configuration. Structural parameters and rms amplitudes of vibrations are determined. It is found that rg(Zr-O)=227.1(5) pm and rg(Hf-O)=226.5(5) pm.
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United Institute of High Temperatures, Russian Academy of Sciences. Translated fromZhurnal Strukturnoi Khimii, Vol. 39, No. 1, pp. 46–54, January–February, 1998.
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Ezhov, Y.S., Komarov, S.A. & Sevast’yanov, V.G. Molecular structure of hafnium and zirconium acetylacetonates M(C5H7O2)4 . J Struct Chem 39, 36–43 (1998). https://doi.org/10.1007/BF02873822
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DOI: https://doi.org/10.1007/BF02873822