Skip to main content
SpringerLink
Log in

Structural mechanism of selective binding of lithium on a solid matrix of Al(OH)3 from aqueous solutions

  • Proceedings Of The 13th Seminar On Intermolecular Interactions And Conformations Of Molecules
  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

The structure of intercalation complexes of aluminum hydroxide with lithium salts is investigated by X-ray diffractometry and by21Al,7Li, and1H NMR. The lithium ions occupy vacant positions in the octahedral voids of aluminum hydroxide, and all atoms of gibbsite change localization. Parameters of the27Al and7Li quadrupole and1H dipole-dipole interaction tensors in anhydrous and aqueous intercalates of gibbsite with lithium salts are determined. A mechanism is suggested for the interaction of gibbsite with aqueous solutions of lithium salts.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. J. M. Lee and W. C. Bauman, “Recovery of lithium from brines,” US Patent No. 4116856,Ref. Zh., Khim., 10L41P (1979).

  2. A. P. Nemudry, V. P. Isupov, V. V. Boldyrev, and N. P. Kotsupalo,React. Sol.,1, 221–226 (1986).

    Article  CAS  Google Scholar 

  3. V. P. Isupov and L. E. Chupakhina,Chem. Sust. Devel.,2, Nos. 2–3, 535–539 (1994).

    CAS  Google Scholar 

  4. A. P. Nemudry, V. P. Isupov, N. P. Kotsupalo, and V. V. Boldyrev,Izv. Sib. Otd. Akad. Nauk SSSR, Ser. Khim. Nauk, No. 11, 28–32 (1984).

  5. A. P. Nemudry, V. P. Isupov, N. P. Kotsupalo, and V. V. Boldyrev,ibid., No. 5, 47–51.

  6. A. P. Nemudry, I. A. Poroshina, V. P. Isupov, et al.,ibid., No. 2, 48–52 (1987).

  7. A. P. Nemudry, V. P. Isupov, N. P. Kotsupalo, and V. V. Boldyrev,ibid., No. 19, 111–114.

  8. V. P. Isupov, L. É. Chupakhina, N. P. Kotsupalo, and V. V. Boldyrev,Dokl. Akad. Nauk SSSR,316, No. 5, 1144–1146 (1991).

    CAS  Google Scholar 

  9. A. P. Nemudry, I. A. Poroshina, G. N. Goldenberg, et al.,Izv. Sib. Otd. Akad. Nauk SSSR, Ser. Khim. Nauk, No. 5, 58–63 (1988).

  10. A. V. Besserguenev, A. M. Fogg, R. J. Francis, et al.,Chem. Mat.,9, 241–247 (1997).

    Article  CAS  Google Scholar 

  11. H. Saalfeld and M. Wedde,Z. Kristallogr.,139, 129–135 (1974).

    CAS  Google Scholar 

  12. N. V. Podberezskaya, S. A. Magarill, S. V. Borisov, et al.,Abstracts of Papers from the International Conference “Information Products, Processes, and Technologies,” Moscow (1996), pp. 187–188.

  13. V. A. Frank-Kamenetskii (ed.),X-Ray Diffraction Analysis of the Main Types of Rock-Forming Minerals [in Russian], Nedra, Leningrad (1983).

    Google Scholar 

Download references

Authors
  1. V. P. Isupov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S. P. Gabuda
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. S. G. Kozlova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. L. É. Chupakhina
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch, Russian Academy of Sciences (Novosibirsk). Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences (Novosibirsk). Translated fromZhurnal Strukturnoi Khimii, Vol. 39, No. 3, pp. 448–452, May–June, 1998.

This work was supported by RFFR grant No. 96-03-33069.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Isupov, V.P., Gabuda, S.P., Kozlova, S.G. et al. Structural mechanism of selective binding of lithium on a solid matrix of Al(OH)3 from aqueous solutions. J Struct Chem 39, 362–366 (1998). https://doi.org/10.1007/BF02873642

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02873642

Keywords

Search

Navigation