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Anisotropy of lattice distortion in [Co(NH3)5ONO]X2, X=Cl−, Br−, under hydrostatic pressure of up to 5.0 GPA

  • Proceedings Of The 13th Seminar On Intermolecular Interactions And Conformations Of Molecules
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Abstract

Variation of the unit cell parameters of [Co(NH3)5ONO]X2 (X=Cl−, Br−) as a function of hydrostatic pressure is studied by powder X-ray diffractometry in cooled diamond anvils. Pressures of up to 5.0 GPa lead to anisotropic lattice distortion but not to phase transitions. The anisotropy of lattice compression of the nitrito isomers is qualitatively distinct from that of the related structures of the corresponding nitro isomers, which differ mainly in the structure of complex cations. The following specific interactions are responsible for the anisotropy of compression for both nitrito and nitro isomers: hydrogen bonds between the NO2 and NH3 ligands of the neighboring cations and between the NH3 ligands and the halide anions; specific interactions of the NO2 ligands of the neighboring cations with each other and of the NO2 ligands with the halide anions.

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Authors
  1. E. V. Boldyreva
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  2. S. L. Kuzmina
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  3. H. Ahsbahs
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Additional information

Institute of Solid State Chemistry, Siberian Branch, Russian Academy of Sciences. Novosibirsk State University. Institute of Mineralogy and Materials Science and Technology Center, Marburg University (Germany). Translated fromZhurnal Strukturnoi Khimii, Vol. 39, No. 3, pp. 424–432, May–June, 1998.

This work was supported by the Humboldt Foundation (Germany) and the “Universities of Russia” Program (projects 3H-34-94, 3H-375-92).

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Boldyreva, E.V., Kuzmina, S.L. & Ahsbahs, H. Anisotropy of lattice distortion in [Co(NH3)5ONO]X2, X=Cl−, Br−, under hydrostatic pressure of up to 5.0 GPA. J Struct Chem 39, 343–349 (1998). https://doi.org/10.1007/BF02873640

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