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Crystal structure of [Co(NH3)5NO2]C2O4. Analysis of specific contacts and structural effects hindering inner-spheric nitro-nitrito isomerization

  • Proceedings Of The 13th Seminar On Intermolecular Interactions And Conformations Of Molecules
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Abstract

The structure of [Co(NH3)5NO2]C2O4 is solved and refined (space group Immm, a=7.428(2), b=9.790(3), c=6.568(1) Å, V=477.6(2) Å3, Z=2; R1=0.0177, wR2=0.0279 for F2>4σ(F2); R1=0.1177, wR2=0.0643 for all data; residual electron density from 0.125 to −0.140 e/Å3). Specific contacts in the structure are analyzed. Crystal chemical interpretation is suggested to explain the occurrence of photodecomposition rather than photochemical bond isomerization under the action of light in cobalt(III) nitropentammoniate oxalate crystals, in contrast to all previously investigated cobalt(III) nitropentammoniates.

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Authors
  1. P. B. Novikov
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  2. D. Yu. Naumov
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  3. E. V. Boldyreva
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  4. N. V. Podberezskaya
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Additional information

Institute of Solid State Chemistry, Siberian Branch, Russian Academy of Sciences. Novosibirsk State University. Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences. Translated fromZhurnal Strukturnoi Khimii, Vol. 39, No. 3, pp. 412–423, May–June, 1998.

This work was supported by the “Universities of Russia” Program, project 3H-34-94. We are grateful to A.V. Virovets for his interest in this work and assistance.

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Novikov, P.B., Naumov, D.Y., Boldyreva, E.V. et al. Crystal structure of [Co(NH3)5NO2]C2O4. Analysis of specific contacts and structural effects hindering inner-spheric nitro-nitrito isomerization. J Struct Chem 39, 333–342 (1998). https://doi.org/10.1007/BF02873639

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  • DOI: https://doi.org/10.1007/BF02873639

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