Abstract
Molecular association greathy affects the physicochemical properties of mesogenic cyanophenyls, which are currently widely used as molecular materials for optoelectronics. This paper reports on a polythermal IR spectroscopic study of molecular association for mesogenic alkyl/alkoxycyanobiphenyls and their hydrated and heteroaromatic analogs in nonpolar solutions, low-temperature inert matrices, and molecular condensate layers in the temperature ranges of 5–10 and 80–330 K. Correlation of the thermodynamic parameters of association with molecular structure of cyanophenyls is established.
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M. V. Lomonosov Moscow State University. Translated fromZhurnal Strukturnoi Khimii, Vol. 39, No. 3, pp. 395–400, May–June, 1998.
This work was carried out in the framework of the Federal Program “Universities of Russia” and the International Scientific Collaboration Program OMMEL.
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Shabatina, T.I., Vovk, E.V., Andreev, G.N. et al. IR spectroscopic study of molecular associates of mesogenic cyanophenyls. J Struct Chem 39, 318–322 (1998). https://doi.org/10.1007/BF02873637
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DOI: https://doi.org/10.1007/BF02873637