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1H NMR in CaCl2·xH2O nanocrystals and water sorption isobars in a CaCl2-silica gel system

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Abstract

Mobility of water molecules in nanocrystals and other phases of CaCl2·xH2O (x=0–12) formed in the nanopores of silica gel during sorption of water vapor is studied by1H NMR. The sorption properties of calcium chloride impregnated in the pores of micro- and mesoporous silica gels were measured.

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Authors
  1. M. M. Tokarev
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  2. S. G. Kozlova
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  3. S. P. Gabuda
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  4. Yu. I. Aristov
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Additional information

Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences. G. K. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences. Translated fromZhurnal Strukturnoi Khimii, Vol. 39, No. 2, pp. 261–266, March–April, 1998.

This work was supported by RFFR grants No. 96-03-33069 and 97-03-33533 and NATO grant HTECH LG N 970330.

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Tokarev, M.M., Kozlova, S.G., Gabuda, S.P. et al. 1H NMR in CaCl2·xH2O nanocrystals and water sorption isobars in a CaCl2-silica gel system. J Struct Chem 39, 212–216 (1998). https://doi.org/10.1007/BF02873620

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  • DOI: https://doi.org/10.1007/BF02873620

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