Abstract
Electron bond energies are calculated for the negative ions of complex heavy elements Ge, Sn, Pb using the polarization potential formalism and relativistic perturbation theory of Rayleigh-Schrödinger type with a model potential of zero-order approximation. Basic correlation effects: polarizing interactions of outermost particles via the polarized core and mutual screening of outermost particles are taken into account to provide an acceptable accuracy of calculations. The paper gives refined values for the negative ions involved.
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Additional information
Hydrometeorological Institute, Odessa. Translated fromZhurnal Strukturnoi Khimii, Vol. 39, No. 2, pp. 217–221, March–April, 1998.
This work was supported by ISSEP grant No. SPU 071013-1997 (A.V.G.).
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Glushkov, A.V., Efimov, V.A., Polevoy, A.N. et al. Bond energy calculation for the negative ions of heavy elements. J Struct Chem 39, 175–178 (1998). https://doi.org/10.1007/BF02873614
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DOI: https://doi.org/10.1007/BF02873614