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The Ge-Mg (Germanium-Magnesium) system

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  • Ge-Mg
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Bulletin of Alloy Phase Diagrams

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Cited References

  • 33Zin: E. Zintl and H. Kaiser, “Uber die Fahigkeit der Elements Zur Bildungnegativerlonen (On the Capacity of Elements in Forming Negative Ions)”,Z. Anorg. Chem., 211, 125–131 (1933). (Crys Structure; Experimental)

    Google Scholar 

  • Indicates key paper40Ray: G.V. Raynor, “The Constitution of the Magnesium-Rich Alloys in the Systems Magnesium-Lead, Magnesium-Tin, Magnesium-Germanium, and Magnesium-Silicon”,J. Inst. Met., 66, 403–426 (1940). (Equi Diagram; Experimental; Indicates presence of a phase diagram)

    Google Scholar 

  • Indicates key paper41Kle: W. Klemm and H. Westlinning, “Untersuchungen Uber die Vergindungen des Magnesiums mit den Elementen der IVb-Gruppe (Investigation on the Formation of Compounds of Magnesium with Elements of Group IVB)”,Z. Anorg. Chem., 245, 365–380 (1941). (Equi Diagram; Experimental; Indicates presence of a phase diagram)

    Article  Google Scholar 

  • 50Bra: G. Brauer and J. Tiesler, “Uber Dichte and Gitterbau der Vergindungen Mg2Pb, Mg2Sn, und Mg2Ge (On the Structure and Lattice Parameters of Mg2Pb, Mg2Sn, and Mg2Ge Compounds)”,Z. Anorg. Chem., 262, 319–327 (1950). (Crys Structure; Experimental).

    Article  Google Scholar 

  • 53Bus: G. Busch and V. Winkler, “Elektrische Leitfahigkeit von Mischkristallen Intermetallischer Verbindungen”,Helv. Phys. Acta, 26, 578–583 (1953). (Crys Structure; Experimental)

    Google Scholar 

  • 55Blu: R.F. Blunt, H.P.R. Frederikse, and W.R. Hosler, “Electrical and Optical Properties of Intermetallic Compounds IV Magnesium Stannide”,Phys. Rev., 100(2), 663–666 (1955). (Crys Structure; Experimental)

    Article  ADS  Google Scholar 

  • 6eJam: J.C. Jamieson, “Crystal Structures at High Pressures of Metallic Modifications of Silicon and Germanium”,Science, 139, 762–764 (1963). (Pressure, Crys Structure; Experimental)

    Article  ADS  Google Scholar 

  • 64Kas: J.S. Kasper and S.M. Richards, “The Crystal Structures of New Forms of Silicon and Germanium”,Acta Crystallogr., 17, 752–755 (1964). (Crys Structure; Experimental)

    Article  Google Scholar 

  • 64Can: P. Cannon and E.T. Conlin, “Magnesium Compounds: New Dense Phases”,Science, 145, 487–489 (1964). (Pressure, Crys Structure; Experimental)

    Article  ADS  Google Scholar 

  • 65Ere: V.N. Eremenko and G.M. Lukashenko, “Thermodynamic Properties of Magnesium Germanide”,Neorg. Mater., 1(8), 1296–1297 (1965). (Thermo; Experimental)

    Google Scholar 

  • Indicates key paper66Bea: P. Beardmore, B.W. Howlett, B.D. Lichter, and M.B. Bever, “Thermodynamic Properties of Compounds of Magnesium and Group IVB Elements”,Trans. AIME, 236, 102–108 (1966); (Thermo; Experimental)

    Google Scholar 

  • 66Cau: H.J. Caulfield and D.E. Hudson, “Sublimation in the Intermetallic Series Mg2Si, Mg2Ge, Mg2Sn, Mg2Pb”,Solid State Commun., 4, 299–301 (1966). (Thermo; Experimental)

    Article  ADS  Google Scholar 

  • Indicates key paper66Eld: J.M. Eldridge, E. Miller, and K.L. Komarek, “Thermodynamic Properties of Liquid Magnesium Germanium Alloys”,Trans. AIME, 236, 1094–1098 (1966). (Thermo; Experimental; Indicates presence of a phase diagram)

    Google Scholar 

  • 66Ger: B.C. Gerstein, P.L. Chung, and G.C. Danielson, “Thermal Study of Group II–IV Semiconductors-I Heat Capacity of Mg2Ge in the Range 5–300 K”,J. Phys. Chem. Solids, 27, 1161–1165 (1966). (Thermo; Experimental)

    Article  ADS  Google Scholar 

  • 66Smi: J.F. Smith, as private communication quoted in [66Eld]. (Thermo; Experimental)

  • 67Eld: J.M. Eldridge, E. Miller, and K.L. Komarek, “Thermodynamic Properties of Liquid Magnesium-Silicon Alloys, Discussion of the Mg Group IVB Systems”,Trans. AIME, 239, 775–781 (1967). (Thermo; Experimental)

    Google Scholar 

  • Indicates key paper68Gef: R. Geffken and E. Miller, “Phase Diagrams and Thermodynamic Properties of the Mg−Si and Mg−Ge Systems”,Trans. AIME, 242, 2323–2328 (1968). (Thermo, Equi Diagram; Experimental; Indicates presence of a phase diagram)

    Google Scholar 

  • 70Nik: N. Nikitin and N. Rozyev, “Vapor Pressure and Thermal Dissociation of Mg2BIV Compounds”,Zh. Prikl. Khim., 43(9), 2093–2095 (1970) in Russian. (Thermo; Experimental)

    Google Scholar 

  • 71Bla: R. Blachnik, D. Kunze, and A. Schneider, “Uber eine Verbesserte Direktkalorimetrische Methode (On an Improved Direct Calorimetric Method; Enthalpy of Formation of Mg2Si and Mg2Ge)”,Metall., 25(2), 119–121 (1971). (Thermo; Experimental)

    Google Scholar 

  • 71Rao: Y. K. Rao and G. R. Belton, “Thermodynamic Properties of Mg−Ge Alloys,”Metall. Trans., 2, 2215–2219 (1971). (Thermo, Experimental; Indicates presence of a phase diagram)

    Google Scholar 

  • 73Eco: C. Ecolivet and R. Graf, “Solidification Unidirectionnelle des Alliages Eutectiques Mg−Mg2Ge et Mg−Mg2Si (Unidirectional Solidification of Mg−Mg2Ge and Mg−Mg2Si Alloys)”,Metaux, 572, 133–141 (1973) in French. (Crys Structure; Experimental; Indicates presence of a phase diagram)

    Google Scholar 

  • 74Fer: R. Ferro, R. Capelli, A. Borsese, and S. Delfino, “Heat of Formation of Magnesium-Germanium Alloys”,J. Less-Common Met., 37, 307–309 (1974). (Thermo; Experimental)

    Article  Google Scholar 

  • 75Ray: G. V. Raynor, “The Compounds of Magnesium with Silicon, Germanium, Tin, and Lead”,Met. Sci., 9, 430–431 (1975). (Crys Structure; Theory)

    Google Scholar 

  • 76Dyu: T. I. Dyuzheva, S. S. Kabalkina, and L. F. Vereshchagin, “High Pressure Polymorphism of the Intermetallic Compounds Magnesium Silicide and Magnesium Germanide”,Akad. Nauk SSSR, 218(5), 1073–1075 (1976) in Russian. (Pressure, Meta Phases; Experimental)

    Google Scholar 

  • 77Bar: I. Barin, O. Knacke, and O. Kubaschewski,Thermochemical Properties of Inorganic Substances (1973) andSupplement, Springer-Verlag, New York (1977) in German. (Thermo; Compilation)

    Google Scholar 

  • 79Kub: O. Kubaschewski and C. B. Alcock,Metallurgical Thermochemistry, Pergamon Press (1979). (Thermo; Compilation)

  • 81BAP: “Melting Points of the Elements”,Bull. Alloy Phase Diagrams,2(1), 145–146 (1981). (Thermo; Compilation) 0217 024

  • 81Kin: H. W. King, “Crystal Structures of the Elements at 25 °C”,Bull. Alloy Phase Diagrams, 2(3), 402–403 (1981). (Crys Structure; Compilation)

    Article  Google Scholar 

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Authors and Affiliations

  1. Department of Metallurgical Engineering, University of Missouri-Rolla, 65401, Rolla, MO, U.S.A.

    A. A. Nayeb-Hashemi & J. B. Clark

  2. Department of Materials Science and Engineering, University of Florida, 32611, Gainesville, FL, U.S.A.

    R. W. Olesinski & G. J. Abbaschian

Authors
  1. A. A. Nayeb-Hashemi
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  2. J. B. Clark
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  3. R. W. Olesinski
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  4. G. J. Abbaschian
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Additional information

Work was supported by American Society for Metals. Literature searched through 1983. Thermodynamic calculations were made using the F*A*C*T (Facility for the Analysis of Chemical Thermodynamics) computer program. Professor Abbaschian is the ASM/NBS Data Program Category Editor for binary germanium alloys, and Professor Clark is the ASM/NBS Data Program Category Editor for binary magnesium alloys.

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Nayeb-Hashemi, A.A., Clark, J.B., Olesinski, R.W. et al. The Ge-Mg (Germanium-Magnesium) system. Bulletin of Alloy Phase Diagrams 5, 359–365 (1984). https://doi.org/10.1007/BF02872950

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