Abstract
Complexes of lithium, sodium, potassium, magnesium and calcium were isolated by diethylene glycol dibenzoate in different organic solvents. Picrate, dinitrophenolate and orthonitrophenolate were used as anions. Stoichiometries of isolated complexes are 1:1 for alkali metal and 1:2 for alkaline earth metal complexes. Shifts in the characteristic frequencies of ligand molecule were observed in IR and1H NMR spectra of complexes
Similar content being viewed by others
References
Ackman R H, Brown W H, Wright F 1955J. Org. Chem. 20 1147
Dobler M, Dunitz J D, Krajewsk J 1969J. Mol. Biol. 42 603
Hiratani K, Taguchi T, Sugihara H and Okada T 1986Chem. Lett. 97
Poonia N S, Bhagwat V W and a Sarad K 1971Inorg. Nucl. Chem. Lett. 13 227
Qureshi R, Sharma U and Bhagwat V W 1992Natl. Acad. Sci. Lett. 15 17
Vogtle F and Weber E 1977Kontakte 1 11
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Mishra, D., Sharma, U. Isolation of alkali and alkaline earth metal complexes by diethylene glycol dibenzoate. Proc. Indian Acad. Sci. (Chem. Sci.) 108, 65–68 (1996). https://doi.org/10.1007/BF02872519
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF02872519