Abstract
Using the Brock and Bird relation and the Flory statistical theory, the surface tension of five binary mixtures of 1,1,2,2-tetrachloroethane with benzene, toluene,p-xylene, acetone and cyclohexane have been evaluated at 298.15 K. The values of surface tension thus obtained have been utilized to compute ultrasonic velocity via the Auerbach relation. Theoretical values have been compared with experimental data and deviations in the ultrasonic velocity have been interpreted in terms of intermolecular interactions.
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Hildebrand J H and Scott R L 1950Solubility of non-electrolytes (New York: Reinhold)
Guggenheim E A 1950Thermodynamics (Amsterdam: North-Holland)
Brown R C and Marsh N H 1976Phys. Report-Rev. Sec. Phys. Lett. 24 77
Toxvaerd S 1975Statistical mechanics (London: Chem. Soc.) vol. 2 chap 4
Reid R C and Sherwood T K 1966The properties of gases and liquids 2nd edn. (New York: McGraw Hill) chap 8
Brock J R and Bird R B 1955Am. Inst. Chem. Eng. J. 1 174
Flory P J 1965J. Am. Chem. Soc. 87 1833
Flory P J and Abe A 1965J. Am. Chem. Soc. 87 1838
Patterson D and Rastogi A K 1970J. Phys. Chem. 74 1067
Mishra R L 1980J. Chem. Phys. 73 5301
Pandey J D 1980J. Chem. Soc., Faraday Trans. 176 1215
Pandey J D, Rai R D and Shukla R K 1989J. Chem. Soc., Faraday Trans. I 85 331.
Pandey J D, Upadhyay R K and Gupta U 1982Acoust. Lett. 5 7
Auerbach R 1948Experientia 4 473
Nath J and Tripathi A D 1989J. Chem. Eng. Data 28 283
CRC Handbook 1997–98Handbook of chemistry and physics 78th edn (New York, Boca Raton, FL: CRC Press)
Prigogine I and Saraga L 1952J. Chem. Phys. 49 399
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Pandey, J.D., Dubey, G.P. & Tripathi, N. Surface tension and ultrasonic velocity of binary liquid mixtures at 298.15 K. Proc. Indian Acad. Sci. (Chem. Sci.) 111, 361–367 (1999). https://doi.org/10.1007/BF02871916
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DOI: https://doi.org/10.1007/BF02871916