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Photophysical and photochemical properties of dithiolate-diimine zinc complexes: Complexes with 3,4-toluenedithiolate ligand: (tdt)Zn(bpy), (tdt)Zn(phen), (tdt)Zn(biqu)

  • “Applied Photochemistry”, Proceedings Of The 3rd Int. Conf. On Solar Energy Storage And Applied Photochemistry, Cairo, Eygpt, January 1995
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Abstract

Photochemistry and photophysics of dithiolate-diimine zinc complexes with the lowest ligand-to-ligand charge transfer (LLCT) excited state were studied. Investigated complexes were found to be nonluminescent because LLCT transition is symmetry-forbidden. Steady-state and flash photolysis experiments indicate that LLCT* state of these complexes can reduce methylviologen and oxygen.

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Authors and Affiliations

  1. Department of Chemistry, Moscow State University, 119899, Moscow, Russia

    A Z Noy, A M Galin, Yu V Razskazovskii & M Ya Mel’nikov

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  1. A Z Noy
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  2. A M Galin
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  3. Yu V Razskazovskii
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  4. M Ya Mel’nikov
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Noy, A.Z., Galin, A.M., Razskazovskii, Y.V. et al. Photophysical and photochemical properties of dithiolate-diimine zinc complexes: Complexes with 3,4-toluenedithiolate ligand: (tdt)Zn(bpy), (tdt)Zn(phen), (tdt)Zn(biqu). Proc. Indian Acad. Sci. (Chem. Sci.) 107, 789–794 (1995). https://doi.org/10.1007/BF02869970

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  • DOI: https://doi.org/10.1007/BF02869970

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