Abstract
Microscopic expressions for the time dependence of solvation energies of newly created ions and dipoles in a dense dipolar liquid are presented. It is shown that: (i) the dynamics of solvation of an ion differ considerably from that of a dipole, especially that the long wavelength (k=0) component of solvent response is totally absent for dipoles, and (ii) the translational modes of the solvent molecules lead to a breakdown of Onsager’s conjecture on the distance dependence of solvent polarization relaxation.
This is a preview of subscription content, log in via an institution to check access.
References
Bagchi B and Chandra A 1988Proc. Indian Acad. Sci. (Chem. Sci.) 100 353
Bagchi B and Chandra A 1989aChem. Phys. Lett, (submitted)
Bagchi B and Chandra A 1989bJ. Chem. Phys. (in press)
Barbara P F and Jarzeba W 1988Acc. Chem. Res. 21 195
Calef D F and Wolynes P G 1983J. Chem. Phys. 78 4145
Castner E W Jr, Fleming G R and Bagchi B 1988aChem. Phys. Lett. 143 270
Castner E W Jr, Fleming G R, Bagchi B and Maroncelli M 1988bJ. Chem. Phys. 89 3519
Chandra A and Bagchi B 1988Chem. Phys. Lett. 151 47
Chandra A and Bagchi B 1989aJ. Chem. Phys. 90 (in press)
Chandra A and Bagchi B 1989bJ. Phys. Chem. (submitted)
Gray C G and Gubbins K E 1984Theory of molecular fluids (Oxford: Clarendon) vol. 1
Kahlow M A, Kang T-J and Barbara P F 1987J. Phys. Chem. 91 6452
Kahlow M A, Rang T-J and Barbara P F 1988J. Chem. Phys. 88 2372
Kahlow M A, Jarzeba W, Rang T-J and Barbara P F 1989J. Chem. Phys. (in press)
Loring R F and Mukamel S 1987J. Chem. Phys. 87 1272
Maroncelli M and Fleming G R 1987J. Chem. Phys. 86 6221
Maroncelli M, Castner E W Jr, Bagchi B and Fleming G R 1988Farad. Discuss. Chem. Soc. (Solvation)85 1
Onsager L 1977Can. J. Chem. 55 1819
Rips I, Klafter J and Jortner J 1988J. Chem. Phys. 88 6425
Simon J D 1988Acc. Chem. Phys. 21 128
Simon J D and Su S-G 1987aJ. Chem. Phys. 87 7016
Simon J D and Su S-G 1987bJ. Phys. Chem. 91 2693
Wolynes P G 1987J. Chem. Phys. 86 5133
Author information
Authors and Affiliations
Additional information
Contribution no. 598 from Solid State and Structural Chemistry Unit
Rights and permissions
About this article
Cite this article
Chandra, A., Bagchi, B. Microscopic expression for time-dependent solvation energy of ions and dipoles in dense polar liquids. Proc. Indian Acad. Sci. (Chem. Sci.) 101, 83–88 (1989). https://doi.org/10.1007/BF02869389
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF02869389