Skip to main content
SpringerLink
Log in

Thermal decomposition of some nitroanilinoacetic acids

  • Physical and Theoretical
  • Published:
Proceedings of the Indian Academy of Sciences - Chemical Sciences Aims and scope Submit manuscript

An Erratum to this article was published on 01 December 1985

Abstract

Thermal decomposition characteristics of 2,4 dinitroanilino acetic acid, 2,4,6 trinitro anilino acetic acid and their methyl and ethyl esters have been investigated by DTA. It is concluded from a study of the kinetic parameters of their decomposition, intramolecular hydrogen bonds existing in these compounds and mass spectral fragmentation characteristics of ethyl esters that these compounds decompose by the loss of OH through a cyclic intermediate formed by the intramolecular hydrogen bonding between the amino hydrogen atom and ortho nitro group.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  • Abderhalden E and Blumberg P 1910J. Chem. Soc. 98 I 371

    Google Scholar 

  • Bellamy L J, Hallam H E and William R L 1958Trans. Faraday. Soc. 54 1120

    Article  CAS  Google Scholar 

  • Fedoroff B T (ed.) 1960Encyclopedia of explosives and related items (New Jersey: Picatinny arsenal, Dover) Vol. 1, p.A420

    Google Scholar 

  • Fields E K and Meyerson S 1968J. Org. Chem. 33 4487

    Article  CAS  Google Scholar 

  • Fields E K and Meyerson S 1975 inAdvances in free radical chemistry (ed.) G H Williams (London: Elek Science) Vol. 5, p. 101

    Google Scholar 

  • Hellberg L H, Prodanovich M J and Stults F 1972J. Heterocycl. Chem. 9 401

    Article  CAS  Google Scholar 

  • Kissinger H E 1957Anal. Chem. 29 1702

    Article  CAS  Google Scholar 

  • Kwart H and Taagepara M R 1964Tetrahedron Lett. 18 1099

    Article  Google Scholar 

  • Maksimov Yu Ya 1969Zh. Fiz. Khim. 43 725 (Chem. Abstr. 196971 49032 s)

    CAS  Google Scholar 

  • Maksimov Yu Ya 1971Zh. Fiz. Khim. 45 793 (Chem. Abstr. 197175 34938 a)

    CAS  Google Scholar 

  • Maksimov Yu Ya and Kogut E N 1978Zh. Fiz. Khim. 52 1400 (Chem. Abstr. 197889 107565 c)

    CAS  Google Scholar 

  • Matveev V G, Dubikhin V V and Nazin G M 1976Kinet. Catal. 17 280 andChem. Abstr. 197685 93554 b

    CAS  Google Scholar 

  • Matveev V G, Dubikhin V V and Nazin G M 1978aIzv. Akad. Nauk. SSSR, Ser. Khim. 783 andChem. Abstr. 197889 23513 w

  • Matveev V G, Dubikhin V V and Nazin G M 1978bIzv. Akad. Nauk. SSSR, Ser Khim. 474 andChem. Abstr. 197888 151 803 g

  • Musso R C 1967 quoted by Meyerson S, Vender Haar R W and Fields E K 1972J. Org. Chem. 37 4114

    Google Scholar 

  • Ozawa T 1965Bull. Chem. Soc. Jpn. 38 1881

    Article  CAS  Google Scholar 

  • Rao K U B 1982Studies on nitro anilino acetic acids Ph.D. thesis, University of Poona, Pune

    Google Scholar 

  • Roberts J D and Caeserio M L 1965Principles of organic chemistry (New York: Benjamin Inc.) p. 77

    Google Scholar 

  • Studier M H, Moore L P, Hayat R and Matsuoka S 1970Biochem. Biophys. Res. Commun. 40 894

    Article  CAS  Google Scholar 

  • Torssel K and Ryhage R 1965 quoted by Meyerson S, Vender Haar R W and Fields E K 1972J. Org. Chem. 37 4114

    Google Scholar 

  • Zeman S 1980Thermochim. Acta 39 117

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Explosives Research & Development Laboratory, Armament Post, 411021, Pune, India

    K U B Rao

  2. IDL Chemicals Ltd, Sanathnagar (IE) P.O, 500 018, Hyderabad, India

    S R Yoganarasimhan

Authors
  1. K U B Rao
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S R Yoganarasimhan
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

An erratum to this article is available at http://dx.doi.org/10.1007/BF02840460.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Rao, K.U.B., Yoganarasimhan, S.R. Thermal decomposition of some nitroanilinoacetic acids. Proc. Indian Acad. Sci. (Chem. Sci.) 95, 309–314 (1985). https://doi.org/10.1007/BF02864195

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02864195

Keywords

Search

Navigation