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A general synthesis of thiazoles. Part 6. Synthesis of 2-amino-5-heterylthiazoles

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Abstract

2-Chloromethyl pyridine, 2-chloromethyl quinoline and 2-chloromethyl benzimidazole have been reacted with amidino thioureas to provide the corresponding 2-amino-5-(2-heteroaryl) thiazoles. 4-Chloromethyl thiazole failed to undergo this reaction.

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References

  • Rajappa S and Sreenivasan R 1978Indian J. Chem. B16 749

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  • Rajappa S, Sudarsanam V, Advani B G and Rane A V 1982Proc. Indian Acad. Sci. (Chem. Sci.) 91

  • Ried W and Kaiser L 1976Liebigs Ann. Chem. 395

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Authors and Affiliations

  1. CIBA-GEIGY Research Centre, Goregaon, 400 063, Bombay, India

    S Rajappa & V G Yadav

  2. The Boots Company (India) Ltd., SION, 400 022, Bombay, India

    V Sudarsanam

Authors
  1. S Rajappa
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  2. V Sudarsanam
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  3. V G Yadav
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Additional information

Part 5. Preceding paper.

Contribution No. 675 from CIBA-GEIGY Research Centre.

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Rajappa, S., Sudarsanam, V. & Yadav, V.G. A general synthesis of thiazoles. Part 6. Synthesis of 2-amino-5-heterylthiazoles. Proc. Indian Acad. Sci. (Chem. Sci.) 91, 451–455 (1982). https://doi.org/10.1007/BF02864182

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  • DOI: https://doi.org/10.1007/BF02864182

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