Skip to main content
Log in

Natural mineral-marine manganese nodule as a novel catalyst for the synthesis of carbon nanotubes

  • Published:
Journal of Wuhan University of Technology-Mater. Sci. Ed. Aims and scope Submit manuscript

Abstract

Multi-walled carbon nanotubes were fabricated by the pyrolysis of acetylene with naturally occurring marine manganese nodules as a novel catalyst at an elevated temperature. The nanotube product was examined by transmission electron microscopy. The method is expected to be the simplest one to synthesize carbon nanotubes due to unnecessary synthesis of catalyst.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. S Iijima. Helical Microtubules of Graphitic Carbon.Nature, 1991, 354: 56–58

    Article  CAS  Google Scholar 

  2. A Thess, R Lee, P Nikolaev,et al. Crystalline Ropes of Metallic Carbon Nanotubes.Science, 1996, 273: 483–487

    Article  CAS  Google Scholar 

  3. P Gu, J H Zhao, G H Li,et al. Highly Ordered Carbon Nanotubes Arrays with Open Ends Grown in Anodic Alumina Nanoholes.J. Wuhan University of Technology-Mater. Sci. Ed., 2003, 18(1): 7–8

    Article  CAS  Google Scholar 

  4. S G Wang, J H Wang, J J Han. Effect of Particle Density on the Aligned Growth of Carbon Nanotubes.J. Wuhan University of Technology-Mater. Sci. Ed., 2004, 19(2): 4–6

    Article  Google Scholar 

  5. J M C Moreno, M Yoshimura. Hydrothermal Processing of High-quality Multiwall Nanotubes from Amorphous Carbon.J. Am. Chem. Soc., 2001, 123: 741–742

    Article  CAS  Google Scholar 

  6. S Turner, M D Siegel, P R Buseck. Structural Features of Todorokite Intergrowths in Manganese Nodules.Nature, 1982, 296: 841–842

    Article  CAS  Google Scholar 

  7. S Ching, K S Krukowska, S L Suib. A New Synthetic Route to Todorokite-type Manganese Oxides.Inorg. Chim. Acta., 1999, 294: 123–132

    Article  CAS  Google Scholar 

  8. S Amelinckx, X B Zhang, D Bernacrts,et al. A Formation Mechanism for Catalytically Grown Helix-shaped Graphite Nanotubes.Science, 1994, 265: 635–63

    Article  CAS  Google Scholar 

  9. K Hernadi, A Fonseca, J B Nagy,et al. Catalytic Synthesis of Carbon Nanotubes Using Zeolite Support.Zeolites, 1995, 17: 416–423

    Article  Google Scholar 

  10. D Gournis, M A Karakassides, T Bakas,et al. Catalytic Synthesis of Carbon Nanotubes on Clay Minerals.Carbon, 2002, 40, 2641–2646

    Article  CAS  Google Scholar 

  11. J P Cheng, J P Tu, Y Ye,et al. Carbon Nanotubes Grown on Sepiolite as Catalyst Carrier.Chinese Chem. Lett., 2002, 13: 381–384

    CAS  Google Scholar 

  12. J P Cheng, X B Zhang, F Liu,et al. Synthesis of Carbon Nanotubes Filled with Fe3 C Nanowires by CVD with Titanate Modified Palygorskite as Catalyst.Carbon, 2003, 41: 1965–1970

    Article  CAS  Google Scholar 

  13. B Kitiyanan, W E Alvarez, J H Harwell,et al. Controlled Production of Single-wall Carbon Nanotubes by Catalytic Decomposition of CO on Bimetallic Co-Mo Catalysts.Chem. Phys. Lett., 2000, 317: 497–503

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Cheng Jipeng.

Additional information

Supported by China Ocean Mineral Resources R and D Association (Grant No. DY105-04-01-10)

Rights and permissions

Reprints and permissions

About this article

Cite this article

Jipeng, C., Xiaobin, Z., Ying, Y. et al. Natural mineral-marine manganese nodule as a novel catalyst for the synthesis of carbon nanotubes. J. Wuhan Univ. Technol.-Mat. Sci. Edit. 21, 29–31 (2006). https://doi.org/10.1007/BF02861464

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02861464

Key words

Navigation