Abstract
The reaction of 5-(4-hydroxyphenyl)-10,15,20-triphenyl porphyrin with 2,6-dibromomethylpyridine and 4,4′-dicarboxyl-2,2′-bipyridine respectively gave 2,6-bis-[5,10,15-triphenyl-20-(4-phenoxymethyl)-porphyrin-yl]-pyridine(3) and 4,4′-di-[5,10,15-triphenyl-20-(p-phenoxycarbonyl)-porphyrin-yl]-2,2′-bipyridine (4). 5-[4-(4′- Bromobutoxy) phenyl]-10,15,20-triphenyl porphyrin reacted with 2,6-dihydroxymethylpyridine to give 2,6-bis-[5,10,15-triphenyl-20-(4-(p-phenoxy)-butoxymethyl)-porphyrin-yl]-pyridine(5). Those new compounds have been identified by1H NMR, IR, MS and UV-visible spectra, and elemental analysis.
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Foundation item: Supported by the National Natural Science Foundation of China (29972035)
Biography: FU Shi-tao (1979-), male, Ph. D candidate, research direction: porphyrin chemistry.
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Shi-tao, F., Kai, W., Zheng, X. et al. Synthesis and characterization of novel bridged porphyrins. Wuhan Univ. J. Nat. Sci. 9, 949–951 (2004). https://doi.org/10.1007/BF02850806
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DOI: https://doi.org/10.1007/BF02850806