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The intrinsic acidity constants and specific surface area of marine solid particles I. A new method

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Abstract

This paper proposes a new method for determining the intrinsic acidity constantsK int a1 andK int aj . The new method is a great improvement over the modified Langmuir plot method generally adopted in that determination of these constants is not dependent on the specific surface area\(\bar S\) of the marine solid particles. The new method was used to determineK int a1 ,K int2a and\(\bar S\) for the main inorganic components of marine solid particles, including illite, montmorillonite, kaolinite, goethite, γ-AlOOH. amorphous ferric oxide, δ-MnO2, manganite, SiO2 and calcium carbonate, and can facilitate the study on the effect of solution constituents, solution temperature, ionic strength, etc. on the value of\(\bar S\).

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References

  • Adamson, A.W., 1982. Physical Chemistry of Surface, 4th ed., John Wiley & Sons, New York.

    Google Scholar 

  • Anderson, M.A. and J.A. Rubin, 1981. Adsorption of Inorganics at Solid-Liquid Interfaces. Ann. Arber Science. Michigan, 357 pp.

    Google Scholar 

  • Atkison, R.J., A.M. Posrer and J.P. Qiuck, 1976. Adsorption of potential-determining ions of the ferric oxide at aqueous electrolyte interface.J. Phys. Chem. 71: 550–558.

    Article  Google Scholar 

  • Davis, J.A., R.O. James and J.O. Leckie, 1978. Surface ionization and complexation at the oxide/water interface.J. Colloid Interface Sci. 63: 480–499.

    Article  Google Scholar 

  • Hohl, H. and W. Stumm, 1976. Interaction of Pb2+ with hydrous γ-AlOOH.J. Colloid Interface Sci. 55: 281–289.

    Article  Google Scholar 

  • Huang C.P. and W. Stumm, 1973. Specific Adsorption of cation on hydrous γ-AlOOH.J. Colloid Interface Sci. 43: 409–421.

    Article  Google Scholar 

  • Huang Jianxia and Zhang Shisan, 1983. Primary study on geochemistry of Si, Al, Fe and CaCO3 in the sediment of Pacific mid-region.Oceanog. Acta 5(5) 604–619 (in Chinese, with English Abstract).

    Google Scholar 

  • Johnston, C. T. and T. G. Sposito, 1984. Vibrational Spectroscopic study of the interlamellar kaolinite-dimethyl sulfoxide complex.J. Phys. Chem. 88: 5953–5964.

    Article  Google Scholar 

  • Lewis, D.G. and V.C. Former, 1986. Infrared absorption of surface hydroxyl groups and lattice vibration in lepidocrocite and boehmite.Clay Mineralls 25: 93–100.

    Article  Google Scholar 

  • Liu Binchong, 1981. Primary study on CaCO3 in Huanghai Sea sediment.Trans. Oceanog. Limnol. 2: 20–25 (in Chinese, with English abstract).

    Google Scholar 

  • Lowell, S. and J.E. Shields, 1984. Powder Surface Area and Porosity. Chapman & Hall, New York, 234 pp.

    Google Scholar 

  • Lyklema, J., 1971. The electric layer on oxide.Croat Chim. Acta 43: 249–260.

    Google Scholar 

  • Riley, J.P. and G.K. Skirrow ed., 1973. Chemical Oceanography, Vol. 2. Academic Press, London, 667 pp.

    Google Scholar 

  • Stumm, W., 1967. Equilibrium Concept in Natural Water System. American Chemical Society, New York, 432 pp.

    Google Scholar 

  • Zhang Zhengbin and Liu Liansheng, 1985. Theory of Interfacial Stepwise Ion/Coordination Particle Exchange and Its Application. Ocean Press, Beijing, 357 pp.

    Google Scholar 

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Authors and Affiliations

  1. Ocean University of Qingdao, 266003, Qingdao

    Wang Xiulin, Zhang Zhengbin, Liu Liansheng & Chen Shaohua

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  1. Wang Xiulin
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  2. Zhang Zhengbin
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  3. Liu Liansheng
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  4. Chen Shaohua
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Xiulin, W., Zhengbin, Z., Liansheng, L. et al. The intrinsic acidity constants and specific surface area of marine solid particles I. A new method. Chin. J. Ocean. Limnol. 9, 253–262 (1991). https://doi.org/10.1007/BF02850751

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  • DOI: https://doi.org/10.1007/BF02850751

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