Abstract
The 2-0, 1-0 and 0-0 bands of the ultraviolet system of PS have been analysed for their rotational structure. It is shown that they involve the transitionC 2 Σ -X 2 Π r (a). TheC 2 Σ state shows a significant spin doubling.
Similar content being viewed by others
References
Dressler K 1955Helv. Phys. Acta 28 563
Dressler K and Miescher E 1955Proc. Phys. Soc. London A68 542
Earls L T 1935Phys. Rev. 48 423
Herzberg G 1950Molecular spectra and molecular structure (New York: Van Nostrand) Vol. 1
James T C 1964J. Chem. Phys. 41 631
Jenouvrier A and Pascat B 1978Can. J. Phys. 56 1088
Mulliken R S and Christy A 1931Phys. Rev. 38 87
Narasimham N A and Balasubramanian T K 1969J. Mol. Spectrosc. 29 294
Narasimham N A and Balasubramanian T K 1971J. Mol. Spectrosc. 37 371
van Vleck J H 1929Phys. Rev. 33 467
Zalubus R 1960 NBS Monograph 17
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Balasubramanian, T.K., Dixit, M.N. & Narasimham, N.A. Rotational analysis of the ultraviolet bands of PS. Pramana - J. Phys 12, 707–716 (1979). https://doi.org/10.1007/BF02846859
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF02846859