Abstract
The melting points in the KCl-KBr, RbCl-RbBr and KBr-RbBr mixed crystal systems have been measured using the microscopic method. In all the three systems, melting points vary nonlinearly with composition, with negative deviations from linearity and maximum deviation at about the equimolar concentration. The observed composition dependence of the melting points is explained qualitatively in terms of the enhanced concentration of point defects and dislocations in mixed crystals.
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Akella J, Ganguly J, Grover R and Kennedy G 1973J. Phys. Chem. Solids 34 631
Arends J, Den Hartog, H W and Decker A J 1965Phys. Status Solidi 10 105
Barr L W and Lidiard A B 1970Physical Chemistry — An advanced treatise (New York: Academic Press)10
Barsch R and Shull H W 1971Phys. Status Solidi B43 637
Born M 1939J. Chem. Phys. 7 591
Bruton T M 1974J. Solid State Chem. 9 173
Cahn R W 1978Nature (London) 273 491
Cholokov K S, Novikov E N, Grishukov V A and Botaki A A 1970Izv. Vyssh. Uchebn. Zaved., Fiz. 12 157
Clark Jr S P 1959J. Chem. Phys. 31 1526
Gupta O P 1983J. Phys. Soc. Jpn. 52 4237
Hari Babu V and Subba Rao U V 1984Prog. Cryst. Growth Charac. 8 189
Hussian K A, Subhadra K G and Kishan Rao K 1988Cryst. Res. Techn. 23 171
Jackson J N S and Liebermann R C 1974J. Phys. Chem. Solids 35 1115
Kruger O L and Moser J B 1967J. Phys. Chem. Solids 28 2321
Lifshitz G M 1955Z. Obschchei Khim 25 2417
Lindemann F A 1910Z. Phys. 11 609
Pistorius C W F T 1965J. Chem. Phys. 43 1557
Pistorius C W F T 1966J. Chem. Phys. 45 3513
Singh I 1970J. Technol. 8 52
Shapiro J N 1970Phys. Rev B1 3982
Sirdeshmukh D B and Srinivas K 1986J. Mater. Sci. 21 4117
Slagle O D and McKinstry H A 1967J. Appl. Phys. 38 437, 446
Srinivas K 1984 Ph.D. Thesis, Kakatiya University, India
Srinivas K and Sirdeshmukh D B 1985Pramana — J. Phys. 25 71
Subba Rao U V and Hari Babu V 1978Pramana — J. Phys. 11 149
Thyagarajan R 1966J. Phys. Chem. Solids 27 218
Ubblehode A R 1978The molten state of matter (New York: Wiley Interscience)
Wallace W E and Flinn R A 1953Nature (London) 172 681
Weyl W A 1961 Advances in Chemistry series (New York: American Chemical Society)33 72
Wollam J S and Wallace W E 1956J. Phys. Chem. 60 1654
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Sirdeshmukh, D.B., Subhadra, K.G. & Hussain, K.A. Melting temperatures of some alkali halide mixed crystal systems. Pramana - J Phys 34, 235–241 (1990). https://doi.org/10.1007/BF02845767
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DOI: https://doi.org/10.1007/BF02845767