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Bis (η5-cyclopentadienyl/indenyl) N-aryl dithiocarbamato chloro oxotungsten(VI) complexes

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Abstract

Some bis(η5-cyclopentadienyl) N-aryl-ditbiocarbamato chloro oxotungsten (VI) complexes of the type (C5H5)2 WO (S2CNHR) Cl (R =o-, m-, p-tolyl and Ph) have been prepared by the reaction of stoichiometric amounts of bis (η5-cyclo-pentadienyl) oxotungsten(VI) dichloride with sodium salts of dithiocarbamic acids in refluxing tetrahydrofuran. The corresponding indenyl complexes of the type (C9H7)2WO (S2CNHR) Cl were similarly synthesised by refluxing equimolar quantities of bis (η5-indenyl) oxotungsten(VI) dichloride and sodium dithiocarbamate in tetrahydrofuran. Infrared spectral studies demonstrate that in these complexes dithiocarbamate ligands are bidentate. Electronic spectra, magnetic susceptibility and elemental analysis have also been carried out for the complexes.

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Authors and Affiliations

  1. Department of Chemistry, University of Delhi, 110007, Delhi, India

    G. S. Sodhi, H. S. Sangari & N. K. Kaushik

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  1. G. S. Sodhi
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  2. H. S. Sangari
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  3. N. K. Kaushik
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Sodhi, G.S., Sangari, H.S. & Kaushik, N.K. Bis (η5-cyclopentadienyl/indenyl) N-aryl dithiocarbamato chloro oxotungsten(VI) complexes. Proc. Indian Acad. Sci. (Chem. Sci.) 91, 289–294 (1982). https://doi.org/10.1007/BF02845029

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  • DOI: https://doi.org/10.1007/BF02845029

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