Skip to main content
Log in

Rare earth element geochemistry and Rb-Sr geochronology of Archaean stromatolitic cherts of the Dharwar craton, south India

  • Published:
Proceedings of the Indian Academy of Sciences - Earth and Planetary Sciences Aims and scope Submit manuscript

Abstract

Stromatolites associated with cherty dolomites of the Vanivilaspura Formation of the Archaean Dharwar Supergroup show a morphology indicative of the deposition of the latter in a intertidal to subtidal environment. The cherts are moderately high in their Al/Al + Fe ratios but depleted in Fe2C3 and also most trace elements. Unlike most other Archaean cherts, the Vanivilaspur cherts exhibit significant negative Ce anomaly, which is interpreted to have resulted from contemporary manganese deposition. The Rb/Sr ratios in the cherts show a sufficient spread to define a linear correlation line in the Rb-Sr evolution diagram corresponding to an age of 2512 ± 159 Ma and initial Sr ratio of 0.7128 ± 0.0012 (2σ). While this age is strikingly close to that of regional metamorphism in the Dharwar craton, the initial ratio is distinctly higher than that of the associated volcanics. Acid leaching experiments on the cherts suggest that they may have been isotopically equilibrated on a mm to cm scale about 500 Ma later than the time of regional metamorphism.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  • Aitchison J C and Flood P G 1990 Geochemical constraints on the depositional setting of Palaeozoic cherts from the New England orogen, NSW, Eastern Australia;Marine Geol. 94 79–95

    Article  Google Scholar 

  • Anil Kumar, Bhaskar Rao Y J, Sivaraman T V and Gopalan K 1996 Sm-Nd ages of Archean metavolcanics of the Dharwar craton, south India;Precambrian Res. 80 206–216

    Google Scholar 

  • Balaram V, Manikyamba C, Ramesh S L and Anjiah K V 1992 Rare earth and trace element determination in iron formation reference samples by ICP-MS;Atomic Spectroscopy 13 19–25

    Google Scholar 

  • Bhaskar Rao Y J, Sivararaman T V, Pantulu G V C, Gopalan K and Naqvi S M 1992 Rb-Sr ages of late Archaean metavolcanics and granites of Dharwar craton, south India and evidence for early Proterozoic thermotectonic events;Precambrian Res. 59 145–170

    Article  Google Scholar 

  • Blatt H, Middleton G and Murray R 1980 Origin of sedimentary rocks; 2nd ed; Prentice Hall pp 782

  • Hesse R 1988 Origin of chert: Diagenesis of biogenic siliceous sediments;Geoscience Canada 15 171–192

    Google Scholar 

  • Hesse R 1989 Silica Diagenesis: Origin of Inorganic and Replacement Cherts;Earth-Science Reviews 26 253–284

    Article  Google Scholar 

  • Hurley P M, Pinson W H Jr., Nagy B, Teska T M 1972 Ancient age for the Middle Marker Horizon, Onverwacht Group, Swaziland Sequence, South Africa;Earth Planet. Sci. Lett. 14 360–366

    Article  Google Scholar 

  • Jones D L and Murchy B 1986 Geological significance of Palaeozoic and Mesozoic radiolarian chert;Ann. Rev. Earth and Planet. Sci. 14 455–492

    Article  Google Scholar 

  • Knauth L P 1992 Origin and diagenesis of chert: An isotopic perspective, InIsotopic signatures and sedimentary rocks (eds.) N Clauer and Chaudhuri (Berlin: Springer Verlag) 23–152

    Google Scholar 

  • Knauth L P and Lowe D R 1978 Oxygen isotopic geochemistry of cherts from the Onverwacht Group (3.4 billion years), Transvaal, South Africa with implications for secular variations in the isotopic compositions of cherts;J. Geol. 41 209–272

    Google Scholar 

  • Moffet J W1990 Microbially mediated cerium oxidation in sea water;Nature 345 421–423

    Article  Google Scholar 

  • Murray R W, Marilyn R, Buchholtz Ten Brink M R, Jones D L, Gerlach D C and Russ G P III 1990 Rare earth elements as indicators of different marine depositional environments in chert and shale;Geology 18 268–271

    Article  Google Scholar 

  • Murray R W, Buchholtz Ten Brink M R, Gerlach D C, Russ G P III and Jones D L 1991 Rare earth, major and trace elements in chert from the Fransiscan Complex and Monterey Group, California: Assessing REE sources for fine grained marine sediments;Geochim. Cosmochim. Acta. 55 1875–1895

    Article  Google Scholar 

  • Murray R W, Buccholtz Ten Brink M R, Gerlach D C and Russ G P III 1992 Rare earth, major and trace element composition of Monterey and DSDP chert and associated host sediments: Assessing the influence of chemical fractionation during diagenesis;Geochim. Cosmochim. Acta. 56 2657–2671

    Article  Google Scholar 

  • Naqvi S M, Govil P K and Rogers J J W 1981 Chemical sedimentation in the Archaean-Early Proterozoic greenschist belts of the Dharwar craton, India; InArchaean Geology, (eds) J E Glover and D I Groves Spl. Publ. 7 Geological Soc. Australia. Inc pp. 245–254

  • Nutmann A P, Chadwick B, Krishna Rao B and Vasudev V N 1996 SHRIMP U/Pb zircon ages of acid volcanic rocks in the Chitradurga and Sandur Groups and granites adjacent to the Sandur schist belt, Kanataka;J. Geol. Soc. India 47 153–164

    Google Scholar 

  • Shibata and Mizutani 1982 Isotopic ages of Jurassic siliceous shale and Triassic bedded chert in Unuma, Central Japan;Geochem. J. 16 213–223

    Google Scholar 

  • Shimizu H and Masuda A 1977 Cerium in chert as an indicator of marine environment of its formation;Nature 266 346–348

    Article  Google Scholar 

  • Sreenivas B, Balaram V and Srinivasan R 1994 Trace and rare earth element contamination during routine preparation of sample powders for geochemical studies;Indian J. Geol. 66 296–304

    Google Scholar 

  • Srinivasan R and Ojakangas R W 1986 Sedimentology of the quartz pebble conglomerates and quartzites of the Bababudan Group, Dharwar craton, South India: Evidence for early crustal stability;J. Geol. 94 199–214

    Article  Google Scholar 

  • Srinivasan R, Shukla M, Naqvi S M, Yadav V K, Venkatachala B S, Uday Raj B and Subba Rao D V 1989 Archaean stromatolites from the Chitradurga schist belt, Dharwar craton, south India;Precambrian Res. 43 239–250

    Article  Google Scholar 

  • Srinivasan R, Naqvi S M and Vasantha Kumar 1990 Archaean shelf facies and stromatolite proliferation in the Dharwar Supergroup, North Kanara District, Karnataka;J. Geol. Soc. India 35 203–212

    Google Scholar 

  • Steinberg M, Bonnot-Courtois C and Tlig S 1983 Geochemical contribution to the understanding of the bedded chert: InSiliceous deposits of the Pacific region, (eds) A Ijima, J R Hein and Siever R Developments in Sedimentology 36 (Amsterdam: Elsevier) pp 193–210

    Google Scholar 

  • Swami Nath J and Ramakrishna M 1981 Early Precambrian Supracrustals of southern Karnataka;Geol. Surv. India Mem. 112 pp 350

    Google Scholar 

  • Taylor H P, Chadwick B and Friend C R L 1988 New age data on the geological evolution of southern India;J. Geol. Soc. India 31 155–157

    Google Scholar 

  • Venkatachala B S, Shukla M, Sharma M, Naqvi S M, Srinivasan R and Uday Raj B 1990 Archaean microbiota from the Donimalai Formation, Dharwar Supergroup, India;Precambrian Res. 47 27–34

    Article  Google Scholar 

  • Weis D and Wasserburg G J 1987a Rb-Sr and Sm-Nd systematics of cherts and other siliceous deposits;Geochim. Cosmochim. Acta 51 959–972

    Article  Google Scholar 

  • Weis D and Wasserburg G J 1987b Rb-Sr and Sm-Nd isotope geochemistry and chronology of cherts from the Onverwacht Group (3.5 AE), South Africa;Geochim. Cosmochim. Acta. 51 973–984

    Article  Google Scholar 

  • Wildeman T R and Haskin L A 1973 Rare earths in Precambrian sediments;Geochim. Cosmochim. Acta. 37 413–439

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Srinivasan, R., Pantulu, G.V.C. & Gopalan, K. Rare earth element geochemistry and Rb-Sr geochronology of Archaean stromatolitic cherts of the Dharwar craton, south India. Proc. Indian Acad. Sci. (Earth Planet Sci.) 106, 369–377 (1997). https://doi.org/10.1007/BF02843461

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02843461

Keywords

Navigation