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The C-Hf (carbon-hafnium) system

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Bulletin of Alloy Phase Diagrams

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Cited references

  1. C. Agte and H. Alterthum, “Systems of High-Melting Carbides; Contribution to the Problem of Carbon Fusion,”Z. Tech. Phys., 11, 182–191 (1930) in German. (Equi Diagram; Experimental)

    Google Scholar 

  2. C. Agte and K. Moers, “Methods for the Preparation of Pure High-Melting Carbides, Nitrides, and Borides and a Description of a Few of Their Properties. I. The Preparation of Pure High-Melting Carbides and Nitrides, as well as a FewBinary Mixtures of These, According to the Sinter Method and a Description of a Few of Their Properties,”Z. Anorg. Allg. Chem., 198, 233–243 (1931) in German. (Equi Diagram; Experimental)

    Article  Google Scholar 

  3. K. Moers, “Methods for the Preparation of Pure High-Melting Carbides, Nitrides, and Borides and a Description of a Few of Their Properties. II. The Preparation of Pure Carbides, Nitrides, and Borides by the Method of Growth and a Description of a Few of Their Properties,”Z. Anorg. Allg. Chem., 198, 243–261 (1931) in German. (Equi Diagram; Experimental)

    Google Scholar 

  4. K Moers, “Methods for the Preparation of Pure High-Melting Carbides, Nitrides, and Borides and a Description of a Few of Their Properties. III. Conductivity Measurements on High-Melting Carbides, Nitrides, and Borides at Room Temperature, Low and High Temperatures,”Z. Anorg. Allg. Chem., 198, 262–275 (1931) in German. (Equi Diagram; Experimental)

    Google Scholar 

  5. K. Becker, “Physical Characteristics of High-Melting Compounds,”Phys. Z., 34, 185–198 (1933) in German. (Crys Structure; Experimental)

    ADS  Google Scholar 

  6. P.M. McKenna, “Tantalum Carbide; Its Relation to Other Hard Refractory Compounds,”Ind. Eng. Chem., 28, 767–772 (1936). (Crys Structure; Experimental)

    Article  Google Scholar 

  7. H.J. Goldschmidt, “The Structure of Carbides in Alloy Steels. I. General Survey,”J. Iron Steel Inst., 160, 345–362 (1948). (Equi Diagram; Review; #)

    Google Scholar 

  8. F.W Glaser, D. Moskowitz, and B. Post, “AStudy of Some Binary Hafnium Compounds,”Trans. AIME, 197(9), 1119–1120 (1953). (Crys Structure; Experimental)

    Google Scholar 

  9. P.G. Cotter and J.A. Kohn, “Industrial Diamond Substitutes: I, Physical and X-Ray Study of Hafnium Carbide,”J. Am. Ceram. Soc., 37(9), 415–420 (1954). (Equi Diagram, Crys Structure; Experimental)

    Article  Google Scholar 

  10. C.E. Curtis, L.M. Doney, and J.R. Johnson, “Some Properties of Hafnium Oxide, Hafnium Silicate, Calcium Hafnate, and Hafnium Carbide,”J. Am. Ceram. Soc., 37(10), 458–465 (1954). (Crys Structure; Experimental)

    Article  Google Scholar 

  11. L.M. Doney,Ceram. Age, 63(3), 21 (1954); quoted in [Hansen]. (Crys Structure; Experimental)

    Google Scholar 

  12. F. Benesovsky and E. Rudy, “Contribution to the Systems Zirconium-Carbon and Hafnium-Carbon,”Planseeber. Pulvermetall., 8(2), 66–71 (1960) in German. (Equi Diagram, Crys Structure; Experimental)

    Google Scholar 

  13. S. J. Grisaffe, “Thermal Expansion of Hafnium Carbide,”J. Am. Ceram. Soc., 43(9), 494 (1960). (Crys Structure; Experimental)

    Article  Google Scholar 

  14. H. Nowotny, F. Benesovsky, and E. Rudy, “High-Melting Systems with Hafnium Carbide and Nitride,”Monatsh. Chem., 91(2), 348–356 (1960) in German. (Equi Diagram, Crys Structure; Review)

    Article  Google Scholar 

  15. H. Nowotny, H. Braun, and F. Benesovsky, “On Some Binary Systems of Hafnium,”Radex-Rundsch., (6), 367–372 (1960) in German (Equi Diagram; Review; #)

  16. H. Kato and M.I. Copeland, U.S. At. Energy Comm., USBM-U-887 (QPR13), 8pp (1961); quoted in [Elliott]. (Equi Diagram; Experimental)

  17. J.A. Koffman, G.M. Kibler, T.R. Reithoff, and A.A. Watts, Tech. Rept. WADD-TDR-60–646, pt. II (AD 297946), (1961). (Thermo; Experimental)

  18. K.I. Portnoi, Yu.V Levinskii, and V.I. Fadeeva, “Reaction with Carbon of Some Refractory Carbides and Their Solid Solutions,”Izu. Akad. Nauk SSSR, Otd. Tekh. Nauk, Met. Toplivo, (2), 147–149 (1961) in Russian. (Equi Diagram; Experimental)

  19. R.G. Avarde, AI. Avgustinik, Yu.N. Vil’k, Yu.D. Kondrashov, S.S. Nikol’skii, Yu.A. Omel’chenko, and S.S. Ordan’yan, “Phase Diagram of the Hf-HfC System,”Zh. Prikl. Khim., 35, 1976–1980 (1962) in Russian; TR:J. Appl. Chem., USSR, 35, 1899–1902 (1962). (Equi Diagram, Crys Structure; Experimental; #)

    Google Scholar 

  20. H. Bittner and H. Goretzki, “Magnetic Investigation of Carbides TiC, ZrC, HfC, VC, NbC, and TaC,”Monatsh. Chem., 93, 1000–1004 (1962) in German. (Equi Diagram, Crys Structure; Experimental)

    Article  Google Scholar 

  21. M.I. Copeland, BM-U-952, U.S. Bureau of Mines, (1962) quotedin[67Sto]. (Equi Diagram; Experimental; #)

  22. H. Kato and M. Copeland, U.S. At. Energy Comm., USBM-U-921, 12–13 (1962); U.S. At. Energy Comm., USBM-U-952, 14–16 (1962); U.S. At. Energy Comm., USBM-U-978,5-7 (1962); U.S. At. Energy Comm., USBM-U-1001,7-8 (1962); U.S. At. Energy Comm., USBM-U-1031, 19–21 (1963); U.S. At. Energy Comm., USBM-U-1057, 14–19 (1963); quoted in [Shunk]. (Equi Diagram; Experimental; #)

  23. J.I. Wittebort, Armed Services Technical Information Agency Rep. No. WADD-TR-60-924 (1962); quoted in [Hultgren, B]. (Thermo; Experimental)

  24. VI. Zhelankin, VS. Kutsev, and B.E Ormont, “Conditions of Formation of Hafnium Carbide During the Reduction of HfO2 by Carbon,”Zh. Neorg. Khim., 7(8), 1762–1764 (1962) in Russian; TR:Russ. J. Inorg. Chem., 7(8), 912–913 (1962). (Crys Structure; Experimental)

    Google Scholar 

  25. R.P. Adams and R.A. Beall, “Preparation and Evaluation of Fused Hafnium Carbide,” U.S. Bur. Mines, Rep. Invest. 6304, 17 pp (1963). (Equi Diagram, Crys Structure; Experimental)

  26. R.P Adams and A.G. Pike, U.S. At. Energy Comm., USBM-U-1091, 5–6 (1963); quoted in [Shunk]. (Equi Diagram; Experimental)

  27. J.A. Coffman, G.M. Kibler, T.F. Lyon, and B.D. Acchione, Wright-Patterson Air Force Base Tech. Rep. No. WADD-TR-646, Part II (1963) as quoted in [Hultgren, B]. (Thermo; Experimental)

  28. W.A. Frad, “Hafnium,”Carbides, U.S. At. Energy Comm., IS-722, 63–64 (1963). (Equi Diagram; Review)

    Google Scholar 

  29. N.H. Krikorian, T.C. Wallace, and J.L. Anderson, “Low-Temperature Thermal Expansion of the Group 4a Carbides,”J. Electrochem. Soc., 110(6), 587–589 (1963). (Crys Structure; Experimental)

    Article  Google Scholar 

  30. E. Rudy and F. Benesovsky, “Stability of Uranium Dicarbide and the Carbon Stability Range in the Partial Systems of UC with ZrC, HfC, NbC, and TaC,”Monatsh. Chem., 94(1), 204–224 (1963) in German. (Crys Structure; Experimental)

    Article  Google Scholar 

  31. V.I. Zhelankin and V.S. Kutsov, “The Structure and Composition of Hafnium Carbide,”Zh. Strukt. Khim., 4(6), 865–867 (1963) in Russian; TR:J. Struct. Chem. (USSR), 4(6), 796–798 (1963). (Crys Structure; Experimental)

    Google Scholar 

  32. H. Bernstein, Met. Soc. AIME, Inst. Metals Div., Spec. Rep. Ser., No. 13, 609–625 (1964). (Crys Structure; Experimental)

  33. D.L. Deadmore, NASA Tech. Memo, TMX-52104 (1964);quotedin[67Sto]. (Crys Structure; Experimental)

  34. L.S. Levinson, “Physical and Chemical Properties / Phase Diagrams,”Carbides in Nuclear Energy, Vol. 1, L.E. Russell, Ed., Macmillan, New York, 429 (1964). (Crys Structure; Experimental)

    Google Scholar 

  35. L.S. Levinson, “High Temperature Heat Content of Tungsten Carbide and Hafnium Carbide,”J. Chem. Phys., 40(5), 1437–1438 (1964). (Thermo; Experimental)

    Article  ADS  Google Scholar 

  36. C.R. Houska, “Thermal Expansion of Certain Group IV and Group V Carbides at High Temperatures,”J. Am. Ceram. Soc., 47(6), 310–311 (1964). (Crys Structure; Experimental)

    Article  Google Scholar 

  37. A.D. Mah, U.S. Bureau of Mines Rep. USBM-6518 (1964); quoted in [Hultgren, B]. (Thermo; Experimental)

  38. J.T. Norton and R.K. Lewis, Tech. Rep. NASA-CR-58046 (NASA Doc. N64-27289), 42 pp (1964). (Crys Structure; Experimental)

  39. J.H. Richardson, “Thermal Expansion of Titanium, Zirconium, and Hafnium Carbides to 2700 °C,” Tech. Rep. SSD-TDR-64-243 (AD 452174), 21 pp (1964). (Crys Structure; Experimental)

  40. R.V. Sara and C.E. Lowell, Tech. Rep. WADD-TDR-60-143, pt. V (AD 608301), 19–44 (1964); quoted in [Shunk]. (Equi Diagram; Experimental)

  41. E.K. Storms, “Some Observations Concerning the Maximum in the Lattice Parameter vs Composition Curve of the Group 4A Carbides,” U.S. At. Energy Comm., LA-DC-6529, 9 pp (1964). (Crys Structure; Experimental)

  42. E.K. Storms, “Critical Review of Refractories,” U.S. At. Energy Comm., LA-2942, 254 pp (1964). (Equi Diagram; Review; #)

  43. V.I. Zhelankin and V.S. Kutsev, “Variation of the Heat of Formation of Hafnium Carbides with Composition,”Zh. Fiz. Khim., 38(3), 562–563 (1964) in Russian; TR:Russ. J. Phys. Chem., 38(3), 302–303 (1964). (Thermo; Experimental)

    Google Scholar 

  44. E.G. Kendall, “The Development and Evaluation of Hypereutectic Carbides,”Modern Ceramics-Some Principles and Concepts, Wiley, New York, 261–289 (1965). (Equi Diagram; Review; #)

    Google Scholar 

  45. J.T. Norton and R.K Lewis, “Properties of Nonstoichiometric Metallic Carbides,” NASA Contract Rep. NASA-CR-67380, 41 pp (1965). (Crys Structure; Experimental)

  46. J.H. Richardson, “Thermal Expansion of Three Group IVACarbides to 2700 °C,”J.Am. Ceram. Soc., 48(10), 497–499 (1965). (Crys Structure; Experimental)

    Article  Google Scholar 

  47. E. Rudy, “Ternary Phase Equilibria in Transition Metal-Bismuth-Carbon-Silicon Systems. Part 1. Related Binary Systems. Vol. 4. Hf-C System,” Tech. Rep. AFML-TR-65-2, Part 1,4, (AD 472697), Air Force Materials Lab., Air Force Systems Command, Wright-Patterson Air Force Base, OH, 62 pp (1965). (Equi Diagram, Crys Structure; Experimental; #)

  48. R.V. Sara, “The Hafnium-Carbon System,”Trans. Metall. Soc. AIME, 233(9), 1683–1691 (1965). (Equi Diagram, Crys Structure; Experimental; #)

    Google Scholar 

  49. L.M. Adelsberg, L.H. Cadoff, and J.M. Tobin, “Group IV-B and V-B Metal Carbide-Carbon Eutectic Temperatures,”J. Am. Ceram. Soc., 49(10), 573–574 (1966). (Equi Diagram; Experimental)

    Article  Google Scholar 

  50. V.V. Fesenko, A.S. Bolgar, and S.P. Gordienko, “Vaporization Rate, Vapor Pressure, Composition Discontinuity, and Some Thermodynamic Properties of Refractory Compounds at Temperatures up to 3000°,”Colloq. Int. Cent. Nat. Rech. Sci., 153, 261–271 (1966);Rev. Int. Hautes Temp. Refract., 3(3), 261–271 (1966) in French. (Thermo; Experimental)

    Google Scholar 

  51. S.S. Ordanyan, A.A. Kraskovskaya, and A.I. Avgustinik, “Phase Diagram of the HfC-Mo System,”Izv. Akad. Nauk SSSR, Neorg. Mater., 2, 299–302 (1966) in Russian; TR:Inorg. Mater. USSR, 2,256–259 (1966). (Crys Structure; Experimental)

    Google Scholar 

  52. H.L. Schick, “Thermodynamics of Certain Refractory Compounds,” quoted in [78Mas]. (Thermo; Experimental)

  53. L.M. Adelsberg and L.H. Cadoff, “The Reactions of Liquid Titanium and Hafnium with Carbon,”Trans. Metall. Soc. AIME, 239(6), 933–935 (1967). (Equi Diagram; Experimental; #)

    Google Scholar 

  54. D.K. Deardorff, M.I. Copeland, and R.P. Adams, “The Hafnium-Carbon Phase Diagram,” U.S. Bur. Mines, Rep. Invest., No. 6983, 16pp (1967). (Equi Diagram, Crys Structure; Experimental; #)

  55. H.J. Kelly and G.Asai, “High Melting Point Carbides. B. Evaluation,” U.S. Bur. Mines, USBM-RC-1326, Met. Prog. Rep. 371,3–23 (1967). (Equi Diagram; Review)

  56. E.K. Storms, “The Hafnium-Hafnium Carbide System,”The Refractory Carbides, Academic Press, New York, 35–46 (1967). (Equi Diagram, Crys Structure; Review;#)

    Google Scholar 

  57. J.P Tosdale, “Refractory Metal-Carbide Systems,” U.S. At. Energy Comm., IS-T-219, 100 pp (1967). (Equi Diagram; Review)

  58. H.A. Wilhelm and J.P. Tosdale, “Carbide Systems,” U.S. At. Energy Comm., IS-1600, M29-M32 (1967). (Equi Diagram; Review)

  59. L. Ramqvist, “Variation of Lattice Parameter and Hardness with Carbon Content of Group 4b Metal Carbides,”Jern kontorets Ann., 152, 517–523 (1968). (Crys Structure; Experimental)

    Google Scholar 

  60. E. Rudy, “Ternary Phase Equilibria in Transition Metal-Boron-Carbon-Silicon Systems,” AFML-TR-65-2, Part V, Air Force Materials Lab., Air Force Systems Command, Wight-Patterson Air Force Base, OH, 689 pp (1969). (Equi Diagram, Crys Structure; Review; #)

  61. Yu.G. Zainulin, S.I. Alyamovskii, G.P. Shveikin, and P.V. Gel’d, “Coefficients of Thermal Expansion of Cubic (NaCl Type) Oxycarbides and Oxynitrides of Zirconium and Hafnium,”Teplofiz. Vys.Temp., 9(3), 546–549 (1971) in Russian; TR:High Temp., 9(3), 496–499 (1971). (Crys Structure; Experimental)

    Google Scholar 

  62. V.N. Eremenko, T.Ya. Velikanova, and S.V. Shabanova, “Phase Diagram of the Hafnium-Carbon Binary System,”Strukt. Faz. Fazovye Prevrashch., Diagr. Sostoyaniya, O.S. Ivanov and Z.M. Alekseeva, Ed., Nauka, Moscow, 129–132 (1974) in Russian. (Equi Diagram; Experimental; #)

    Google Scholar 

  63. M. Achour, J. Zaug, and A. Pialoux, “Progressive Carboreduction of Hafnium Dioxide. III. Determination of Lattice Parameters of Hafnium Carbide Phases by X-Ray Diffraction between 1000 and 2000°,”Rev. Int. Hautes Temp. Refract., 12(3), 289–294 (1975) in French. (Crys Structure; Experimental)

    Google Scholar 

  64. N.V. Chelovskaya, A.N. Kornilov, V.I. Zhelankin, and G.P. Shveikin, “Possibility of Determiningthe Heat of Formation of Transition Metal Carbides from Data on the Combustion Heat of Oxycarbides,” Vses. Konf. Kalorim., 7th, Vol. 1, 27–28 (1977) in Russian. (Thermo; Experimental)

    Google Scholar 

  65. V.M. Maslov, A.S. Neganov, I.P. Borovinskaya, and A.G. Merzhanov, “Self-Propagating High-Temperature Synthesis as a Method for Determination of the Heat of Formation of Refractory Compounds,”Fiz. Goreniya Vzryva, 14(6), 73–82 (1978) in Russian; TR:Combustion Explosion Shock Waves, 14(6), 759–767 (1979). (Crys Structure, Thermo; Experimental)

    Google Scholar 

  66. P.J. Spencer, O. von Goldbeck, R. Ferro, R. Marazza, K Girgis, and O. Kubaschewski,Hafnium: Physico-Chemical Properties of Its Compounds and Alloys, K.L. Komarek, Ed., Atomic Energy Review Special Issue No. 8, International Atomic Energy Agency, Vienna (1981). (Equi Diagram; Review,#)

    Google Scholar 

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This work was supported by ASM International. Literature searched through early 1987

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Okamoto, H. The C-Hf (carbon-hafnium) system. Bulletin of Alloy Phase Diagrams 11, 396–403 (1990). https://doi.org/10.1007/BF02843319

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