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The kinetics of hydroxyl radical reactions with cyclopropane and cyclobutane

  • Special Issue on Lasers in Chemistry, Proceedings of the Conference of the International Centre for Pure and Applied Chemistry, Trieste, June 1990
  • Published:
Proceedings of the Indian Academy of Sciences - Chemical Sciences Aims and scope Submit manuscript

Abstract

A laser flash photolysis/resonance fluorescence investigation has been carried out to study the kinetics of the overall reactions OH + cyclopropane (1) and OH + cyclobutane (2) in the temperature range 298–490 K and at 298 K, respectively. The following kinetic parameters have been determined: k1 =(3.9 ±0.6) 10−12exp- (2.2 ± 0.1)kcal mol−1/RT molecule−1cm3s−1, k2(298 K) = (17.5 ± 1.5)10−13molecule−1 cm3s−1.

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Authors and Affiliations

  1. Central Research Institute for Chemistry, Hungarian Academy of Science, P.O. Box 17, H-1525, Budapest, Hungary

    S. Dóbé, T. Turányi, T. Bérces & F. Márta

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  1. S. Dóbé
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  2. T. Turányi
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  3. T. Bérces
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  4. F. Márta
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Dóbé, S., Turányi, T., Bérces, T. et al. The kinetics of hydroxyl radical reactions with cyclopropane and cyclobutane. Proc. Indian Acad. Sci. (Chem. Sci.) 103, 499–503 (1991). https://doi.org/10.1007/BF02842112

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  • DOI: https://doi.org/10.1007/BF02842112

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