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IR multiphoton dissociation of CF3I. Pressure effect with inert and reactive gases

  • Special Issue on Lasers in Chemistry, Proceedings of the Conference of the International Centre for Pure and Applied Chemistry, Trieste, June 1990
  • Published:
Proceedings of the Indian Academy of Sciences - Chemical Sciences Aims and scope Submit manuscript

Abstract

The IR multiphoton dissociation of CF3I has been studied in the presence of isobutane and with isobutane and Ar and CO2 as inert gases. The dependence of the reaction probability P(Φ) with fluence (ϕ) is confirmed. Modeling of the experimental results shows that for the energy transfer processes the average energy transferred per collision 〈†E〉d varies with (ϕ).

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Authors and Affiliations

  1. INFIQE, Dpto. de Fisico Quimica, Fac. de Ciencias Quimicas, U.N.C. SUC 16, C.C. 61, 5016, Cordoba, Argentina

    C. A. Rinaldi, J. C. Ferrero, S. I. Lane & E. V. Oexler

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  1. C. A. Rinaldi
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  2. J. C. Ferrero
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  3. S. I. Lane
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  4. E. V. Oexler
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Rinaldi, C.A., Ferrero, J.C., Lane, S.I. et al. IR multiphoton dissociation of CF3I. Pressure effect with inert and reactive gases. Proc. Indian Acad. Sci. (Chem. Sci.) 103, 465–469 (1991). https://doi.org/10.1007/BF02842108

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  • DOI: https://doi.org/10.1007/BF02842108

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