Abstract
Recent progress which allows laser flash photolysis investigation of opaque materials by using diffuse reflectance from analysing sources for the detection of laser induced transient species is described. Experimental details of nanosecond and picosecond diffuse reflectance laser photolysis systems are presented and methods of analysis of data are discussed. The potential of the technique for studying elementary reactions at interfaces is demonstrated with particular reference to bimolecular reactions of (a) the triplet state of acridine adsorbed on various porous silica surfaces and (b) ion-electron recombination following multi-photon ionisation of diphenyl polyenes adsorbed on γ-alumina. The mechanisms of formation and decay of these transient adsorbed species are discussed.
Similar content being viewed by others
References
Ikeda N, Immagi K, Masuhara H, Nakashima N and Yoshihara K 1987Chem. Phys. Lett. 140 281
Kasche V and Lindqvist L 1965Photochem. Photobiol. 4 923
Kellmann A 1977J. Chem. Phys. 81 1195
Kessler R W and Wilkinson F 1981J. Chem. Soc., Faraday Trans. I 77 309
Kossanyi J, Kouyte D, Pouliquen J, Ronfard-Haret J C, Valat P, Oelkrug D, Mammel U, Kelly G P and Wilkinson F 1990J. Luminesc. 46 17
Kubelka P 1948J. Opt. Soc. Am. 38 448
De Mayo P 1982Pure Appl. Chem. 54 1623
Oelkrug D, Honnen W, Wilkinson F and Willsher C J 1987J. Chem. Soc. Faraday Trans. II 83 2081
Oelkrug D, Krabichler G, Honnen W, Wilkinson F and Willsher C J 1988J. Phys. Chem. 92 3589
Oelkrug D, Uhl S, Willsher C J and Wilkinson F 1989J. Phys. Chem. 93 4551
Pouliquen J, Fichou D, Valat P, Kossanyi J, Wilkinson F and Willsher C J 1986J. Photochem. 35 381
Porter G 1950Proc. R. Soc. A200 284
Wilkinson F 1986J. Chem. Soc. Faraday Trans. II 82 1073
Wilkinson F and Kelly G P 1990 inHandbook of organic photochemistry (ed.) J C Scaiano (Boca Raton, FL: CRC Press) vol. 1, ch. 12
Wilkinson F and Willsher C J 1984Chem. Phys. Lett. 104 272
Wilkinson F and Willsher C J 1985J. Chem. Soc., Chem. Commun. 142
Wilkinson F and Willsher C J 1988J. Luminesc. 33 187
Wilkinson F and Willsher C J 1990 inLasers in polymer science and technology: application (eds) Foussier and F Jan Rabek (Boca Raton, FL: CRC Press) vol. 2, ch. 9
Wilkinson F, Willsher C J, Bourdelande J L, Font J and Greuges J 1987J. Photochem. 38 381
Wilkinson F, Willsher C J, Casai M L, Johnston L J and Scaiano J C 1986aCan. J. Chem. 64 539
Wilkinson F, Willsher C J, Leicester P A, Barr J R M and Smith M J C 1986bJ. Chem. Soc., Chem. Commun. 1216
Wilkinson F, Willsher C J, Uhl S, Honnen W and Oelkrug D 1986cJ. Photochem. 33 273
Wilkinson F, Willsher C J, Warwick P, Land E J and Rushton F A P 1984Nature (London) 311 40
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Wilkinson, F. Diffuse reflectance laser flash photolysis of adsorbed molecules. Proc. Indian Acad. Sci. (Chem. Sci.) 103, 305–311 (1991). https://doi.org/10.1007/BF02842087
Issue Date:
DOI: https://doi.org/10.1007/BF02842087