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Abstract

The reactions of a range of acyclic, cyclic and bicyclic diphosphazanes with several transition metal organometallic derivatives have been investigated. The structures of the products have been deduced from IR and NMR spectroscopic data and confirmed by single crystal X-ray analysis of a few representative compounds.

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References

  • Baker P K and Quinlan A J 1989Inorg. Chim. Acta 162 179

    Article  CAS  Google Scholar 

  • Balakrishna M S 1989Synthetic, spectroscopic and structural studies on transition metal complexes of diphosphazane ligands, PhD thesis, Indian Institute of Science, Bangalore

    Google Scholar 

  • Balakrishna M S, Prakasha T K and Krishnamurthy S S 1989a,Proc. Indian Natl. Sci. Acad. A55 335

    Google Scholar 

  • Balakrishna M S, Prakasha T K, Krishnamurthy S S, Siriwardane U and Hosmane N S 1989bJ. Organomet. Chem. (in press)

  • Balakrishna M S, Prakasha T K and Krishnamurthy S S 1990Phosphorus, Sulfur and Silicon (in press)

  • Blagg A, Carr S W, Cooper G R, Dobson I D, Gill J B, Goodall D C, Shaw B L, Taylor N, Boddington T 1985J. Chem. Soc. Dalton Trans. 1213

  • Burckett St Laurent J C T R, Hitchcock P B and Nixon J F 1983J. Organomet. Chem. 249 243

    Article  Google Scholar 

  • Brown G M, Finholt J E, King R B, Bibber J W and Kim J H 1978J. Am. Chem. Soc. 100 1632

    Article  Google Scholar 

  • de Leeuw G, Field J S and Haines R J 1989J. Organomet. Chem. 359 245

    Article  Google Scholar 

  • Drew M G B 1977Prog. Inorg. Chem. 23 67

    Article  CAS  Google Scholar 

  • Ellermann J, Szucsanyi G Y and Wilhelm E 1985Chem. Ber. 118 1588

    Article  CAS  Google Scholar 

  • Foy R M, Kepert D L, Raston C L and White A H 1980J. Chem. Soc., Dalton Trans. 440

  • Haines R J, Laing M, Meintjies E and Sommerville P 1981J. Organomet. Chem. 215 C17

    Article  CAS  Google Scholar 

  • Haines R J, Meintjies E and Laing M 1979Inorg. Chim. Acta 36 403

    Article  Google Scholar 

  • Hill T G, Haltiwanger R C, Prout T R and Norman A D 1989Inorg. Chem. 28 3461

    Article  CAS  Google Scholar 

  • Keat R 1982Top. Curr. Chem. 102 89

    CAS  Google Scholar 

  • Keat R 1987 inChemistry of inorganic homo- and heterocycles (eds) D B Sowerby and I Haiduc (London: Academic Press) vol. 2, p. 407

    Google Scholar 

  • Keat R, Muir L M, Muir K W and Rycroft D S 1981J. Chem. Soc., Dalton Trans 2192

  • Keat R and Thompson D G 1977Angew. Chem., Int. Edn. Engl. 16 797

    Article  Google Scholar 

  • Kepert D L 1979Prog. Inorg. Chem. 25 41

    Article  CAS  Google Scholar 

  • King R B 1980Acc. Chem. Res. 13 243

    Article  CAS  Google Scholar 

  • Kirss R U and Eisenberg R 1989Inorg. Chem. 28 3372

    Article  CAS  Google Scholar 

  • Kumaravel S S, Krishnamurthy S S, Cameron T S and Linden A 1988Inorg. Chem. 27 4546

    Article  CAS  Google Scholar 

  • Mague J T, Johnson M P and Lloyd C L 1989J. Am. Chem. Soc. 111 5012

    Article  CAS  Google Scholar 

  • Muir L M, Muir K W, Grossel M C, Brown M P, Nelson C D, Yavari A, Kalles E, Moulding R P and Seddon K R 1986J. Chem. Soc., Dalton Trans. 1955

  • Pignolet L H (ed.) 1983Homogeneous catalysis with metal phosphine complexes (New York: Plenum)

    Google Scholar 

  • Prakasha T K and Krishnamurthy S S 1989 (to be published)

  • Puddephatt R J 1982Chem. Soc. Rev. 99

  • Scherer O J, Anselmann R and Sheldrick W S 1984J. Organomet. Chem. 263 C26

    Article  CAS  Google Scholar 

  • Sreenivasa Reddy V and Krishnamurthy S S 1989 (to be published)

  • Stricklen P M, Volcko E J and Verkade J G 1983J. Am. Chem. Soc. 105 2494

    Article  CAS  Google Scholar 

  • Uson R, Fornies J, Navarro R, Thomas M, Fortuno C and Cebollada J I 1989Polyhedron 8 1045

    Article  CAS  Google Scholar 

  • Wilkinson G, Stone F G A and Abel E W (eds) 1982Comprehensive organometallic chemistry (Oxford: Pergamon)

    Google Scholar 

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Krishnamurthy, S.S. Organometallic chemistry of diphosphazane ligands. Proc. Indian Acad. Sci. (Chem. Sci.) 102, 283–290 (1990). https://doi.org/10.1007/BF02841942

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