Abstract
Methyl iodide activated stereospecific α-mannosylations utilising 2-pyridyl-1-thiomannopyranoside derivatives (2,3,4) as donors and suitably protected myo-inositol derivatives (1,25,27,29) as acceptors to prepare 2-0-α-D-mannopyranosyl-6-[O-α-D-mannopyranosyl-(1–6)-O-α-D-mannopyranosyl-(l-6)-O-α-D-mannopyranosyl]-D-myo-inositol derivative (31) is described.
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IICT Commun. No. 3355
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Mereyala, H.B., Gaddam, B.R. Stereospecific mannosylations ofmyo-inasitol: Synthesis of manno-myo-inositol fragment ofMycobacterium tuberculosis . Proc. Indian Acad. Sci. (Chem. Sci.) 106, 1225–1230 (1994). https://doi.org/10.1007/BF02841929
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DOI: https://doi.org/10.1007/BF02841929